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The monolithic DPF made of cordierite ceramic has unsatisfactory on his fatigue or long-term strength. A new design of configuration of plugs combined with the hexagonal channels shows a transversally isotropic property, and can remove the anisotropy of monoliths with square channels. This anisotropy is assumed to be one of main reasons for the failure of monoliths with square channels regarding the experimental results. Considering the honeycomb structure as a homogeneous material based on the Boltzmann continuum can't give the correct behaviour of this structure in a FEM simulation. Another homogenization procedure using the Cosserat theory has been discussed. The FEM stress analyses with structural detail-models show that the maximal tensile stresses in the monolith with square channels exist in the diagonal (i.e. 45°-) direction, or on the edges of channels. This feature is identical with what the theory has predicted and the experimental results have shown.

To achieve low emission levels, the handicap of the TWC is its light-off characteristic. It achieves a maximum hot efficiency of nearly 100 %, but this requires a temperature in the range of 300 to 450 °C. To improve this time lag after cold start, the TWC needs additional help to reach the targets of future low (LEV) or ultra low emission (ULEV) levels. This paper describes the work on additional devices to reach the ULEV-levels such as: Electrical Heated Catalyst (EHC). Burner Heated Catalyst (BHC) Hydrocarbon Trap (HCT) as external device. Adsorber Coated Substrate (ACS) in the usual converter box. The comparison of these systems was done with a concept car. The low mileage exhaust results demonstrated the principal suitability of all these devices, but there is still much work to be done to meet the ULEV levels with the guaranted durability. The advantages and disadvantages of the systems are discussed, including estimated weight and cost.

The California Air Resources Board (CARB) has proposed procedures for the analysis of non-methane organic gases (NMOG) to determine the ozone forming potential (OFP) of automotive exhaust. For realization of these methods two differently configured GC systems are necessary. In order to reduce the efforts concerning costs, maintenance and quality control of two analytical instruments, a single run method is developed for routine analysis. This method allows identification and quantification of individual hydrocarbons (IHC) in the range of carbon numbers C2 to C12. Analytical problems arising from high contents of water and carbon dioxide in exhaust samples are discussed. Water reduction is obtained by a Nafion® Dryer by means of membrane diffusion of polar compounds. Contamination as well as memory effects due to this sample work up are described. Sample pre-concentration of 50-200 mL diluted automotive exhaust is performed using a triple phase “mixed bed” adsorption tube at O°C.

Engine and laboratory tests were carried out to examine the performance of NOx adsorption catalysts for gasoline lean burn engines in fresh and aged condition. The results show that fresh NOx adsorption catalysts have the potential to meet EURO III emission standards. However, to accomplish these the fuel must contain a low sulfur concentration and the engine must be tuned to optimize the efficiency of the catalyst. After engine or furnace aging upto 750°C the catalyst shows some loss of NOx adsorption efficiency. This deterioration can be offset somewhat by increasing the frequency of lean/rich switching of the engine. Temperatures higher than 750°C may cause an irreversible destruction of the NOx, storage features while the three-way activity of the catalyst remains intact or even may improve. With reference to several physicochemical investigations it is believed that the detrimental effect of catalyst aging is attributed to two different deactivation modes.

This paper deals with a passenger-car direct-injection-diesel-engine with electronically controlled unit-injector. It is being investigated how far emissions and fuel-consumption can be influenced by exhaust-gas-recirculation (EGR) and pilot-injection especially when they are in combination with each other. The results reveal that the NOx-emission can be decreased much more by EGR than by pilot-injection. The lowest NOx-emissions however can only be reached by combination of EGR and pilot injection.. In the investigated area of the engine map a decrease in soot-emission can be obtained with rising EGR-rates by pilot-injection. On the other hand pilot-injection results in an increase of soot emission at high EGR-rates at the engine operating point N=2000 rpm, bmep=2 bar. Pilot-injection in combination with EGR effects no deterioration of fuel-consumption and HC-emission.

The influence of different port designs on the generation of a swirl flow is described on the basis of stationary and non-stationary flow analyses. Subsequently, engine test bench analyses with a 3-valve one-cylinder engine were performed to assess the aforementioned port configurations with respect to their influence on the lean-burn behaviour. The most favourable port design was then used to analyse various combustion chamber shapes in order to further improve the engine behaviour during lean-burn operation and to select the most promising combustion chamber variant. Finally, the port and combustion chamber configurations thus identified were applied in vehicle simulation tests with lean-burn and EGR-burn operation to check the emission behaviour for compliance with the future European level 3 emission limits.

The real-time concentrations of benzene, toluene, xylene, trimethyl-benzene and naphthalene in vehicle exhaust have been monitored during the FTP-cycle with a time-resolution of 20 ms and a sensitivity of 50 ppb. Using a laser mass spectrometer, the aromatic hydrocarbons in unconditioned exhaust gas at sampling positions behind the exhaust valve, before and behind the catalytic converter have been analyzed. The comparison of the emissions sampled before and behind the catalytic converter reveals the effect of dealkylation of the aromatic hydrocarbons in the catalytic converter. Whereas most of the aromatic hydrocarbons are burned in the hot catalytic converter, however, bursts of aromatic hydrocarbons are released at transient motor operation. In these moments, which can be attributed to phases of closed throttle valve and very low engine load at gear changes, a significant part of the C1-, C2- and C3- benzenes has been converted into benzene.

Secondary air injection after cold start gives two effects for reduced exhaust emissions: An exothermic reaction at the hot exhaust valves occurs, which increases the temperature of the exhaust gas. It gives sufficient air to the catalyst during the cold start fuel enrichment that is necessary to prevent driveability problems. Handicaps for the wide use of air injection include space constraints, weight and price. An electrical air blower was choosen to best satisfy all these requirements. The development steps are described. The result is a three stage radialblower with extremly high revolutions of about 18000 rpm. The system configuration and the outcome are demonstrated on the new C-Class of Mercedes-Benz. The results show emission reductions higher than 50 %, while also satisfying the development goals of noise, volume, weight and cost requirements.

After the introduction of four-valve technology for gasoline powered passenger cars, Mercedes-Benz consistently developed this technology also for Diesel engines. Based on the proven success of the prechamber combustion system, this new Diesel engine generation, which includes 4, 5 and 6-cylinder naturally-aspirated engines, will be the first four-valve Diesel engines to be installed in passenger cars. The naturally aspirated 3.0 liter 6-cylinder in-line engine which represents the high end of this generation will be offered for sale in all 50 states of the USA in the Executive Class models starting on January 1, 1994. Four-valve technology allows the prechamber to be located centrally between the intake and exhaust valves which results in a major improvement of the combustion process. In addition, this 6-cylinder engine has a resonance intake system controlled by two butterfly valves to maximize the volumetric efficiency of the engine.

A new multicomponent exhaust gas analyzer has been applied to investigate the time-resolved concentrations of the aromatic hydrocarbon exhaust components benzene, toluene, xylene, trimethyl benzene under dynamic engine operation, such as sudden change of speed and load, misfiring and switching off the fuel mixture control. The analyzer consisting of a compact laser mass spectrometer is capable of measuring the concentrations of the individual aromatic hydrocarbon compounds simultaneously with 1 ppm sensitivity at a sampling rate of 50 Hz corresponding to a sampling period of 20 ms. High concentration peaks are observed for these substances at instationary motor operation. However, whereas the real-time concentrations of toluene, xylene, and trimethyl benzene show equal dependence on motor speed and load a different behavior has been observed for benzene even during the emission phase of single combustion cycles.