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Isopentanol is an advanced biofuel that can be produced by micro-organisms through genetically engineered metabolic pathways. Compared to the more frequently studied ethanol, isopentanol's molecular structure has a longer carbon chain and includes a methyl branch. Its volumetric energy density is over 30% higher than ethanol, and it is less hygroscopic. Some fundamental combustion properties of isopentanol in an HCCI engine have been characterized in a recent study by Yang and Dec (SAE 2010-01-2164). They found that for typical HCCI operating conditions, isopentanol lacks two-stage ignition properties, yet it has a higher HCCI reactivity than gasoline. The amount of intermediate temperature heat release (ITHR) is an important fuel property, and having sufficient ITHR is critical for HCCI operation without knock at high loads using intake-pressure boosting. Isopentanol shows considerable ITHR, and the amount of ITHR increases with boost, similar to gasoline.

A 1998 Toyota Corona passenger car with a direct injection spark ignition (DISI) engine was tested at constant engine speed (2000 rpm) over a range of loads. Engine-out and tailpipe emissions of gas phase species were measured each second. This allowed examination of the engine-out emissions for late and early injection. Seven fuels were used for these tests: five blended fuels and two pure hydrocarbon fuels. These seven fuels can be divided into groups for examination of the effects of volatility, MTBE, and structure (an aromatic versus an i-alkane). Correlations between the fuel properties and their effects on emissions are presented. Use of steady state tests rather than driving cycles to examine fuel effects on emissions eliminates the complications resulting from accelerations, decelerations, and changes of injection timing but care had to be taken to account for the periodic regenerations of the lean NOx trap/catalyst.

The performance of Gasoline Direct Injection (GDI) engines is governed by multiple physical processes such as the internal nozzle flow and the mixing of the liquid stream with the gaseous ambient environment. A detailed knowledge of these processes even for complex injectors is very important for improving the design and performance of combustion engines all the way to pollutant formation and emissions. However, many processes are still not completely understood, which is partly caused by their restricted experimental accessibility. Thus, high-fidelity simulations can be helpful to obtain further understanding of GDI injectors. In this work, advanced simulation and experimental methods are combined in order to study the spray characteristics of two different 3-hole GDI injectors.

A 1998 Toyota Corona passenger car with a direct injection spark ignition (DISI) engine was tested at constant engine speed (2000 rpm) over a range of loads. Engine-out and tailpipe emissions of gas phase species were measured each second. This allowed examination of the engine-out emissions for late and early injection. Regeneration of the lean NOx trap/catalyst was also examined, as was the efficiency of NOx reduction. NOx stored in the trap/catalyst is released at the leading edge of regenerations, such that the tailpipe NOx is higher than the engine-out NOx for a brief period. The efficiency of NOx reduction was <50% for the lowest loads examined. As the load increased, the efficiency of NOx reduction decreased to near 0% due to excessive catalyst temperatures. Loads sufficiently high to require a rich mixture produce high NOx reduction efficiencies, but in this case the NOx reduction occurs via the three-way catalysts on this vehicle.

Improvement of thermal efficiency is an important problem for internal combustion engines. Fuel reforming with dehydrogenation reaction by exhaust heat is one of the measures to increase thermal efficiency using hydrogen mixed SI combustion. For this kind engine system, hydrous ethanol has a good potential. Furthermore, when the hydrous ethanol inject to combustion chamber directory, high compression combustion can be achieved by its large amount of latent heat. Therefore, fuel lubricity is an important check point for the hydrous ethanol reforming engine systems. In this study, effect of water concentrations within ethanol on the hydrous ethanol fuel lubricity has been evaluated using HFRR (High-Frequency Reciprocating Rig) test method. Wear scar diameter on 100 % of ethanol was around 700 μm which was a little better than gasoline lubricity. When the water concentration within ethanol was increased, the wear scar diameters were decreasing around 330 μm.

Exhaust gas recirculation (EGR) is widely used in diesel engines to reduce nitrogen oxide (NOx) emissions. However, a lacquer is formed on the EGR valve or EGR cooler due to particulate matter and other components present in diesel exhaust, causing serious problems. In this study, the mechanism of lacquer deposition is investigated using attenuated total reflection Fourier transform infrared spectrometry (ATR-FTIR) and scanning electron microscopy (SEM). Deposition of temperature-dependent lacquers was evaluated by varying the temperature of a diamond prism between 80 and 120 °C in an ATR-FTIR spectrometer integrated into a custom-built sample line, which branched off from the exhaust pipe of a diesel engine. Lacquers were deposited on the diamond prism at 100 °C or less, while no lacquer was deposited at 120 °C. Time-dependent ATR-FTIR spectra were obtained for approximately 2 h from the beginning of the experiment.

Diesel engines have better fuel economy over comparable gasoline engines and are useful for the reduction of CO2 emissions. However, to meet stringent emission standards, the technology for reducing NOx and particulate matter (PM) in diesel engine exhaust needs to be improved. A conventional selective catalytic reduction (SCR) system consists of a diesel oxidation catalyst (DOC), diesel particulate filter (DPF), and urea-SCR catalyst. Recently, more stringent regulations have led to the development of SCR systems with a larger volume and increased the cost of such systems. In order to solve these problems, an SCR catalyst-coated DPF (SCR/DPF) is proposed. An SCR/DPF system has lower volume and cost compared to the conventional SCR system. The SCR/DPF catalyst has two functions: combustion of PM and reduction of NOx emissions.

Numerical calculations were performed to investigate the mixture formation, ignition, and combustion processes in a diesel spray. The spray was formed by injecting n-heptane into a constant volume vessel under high-temperature and high-pressure conditions. The fuel droplets were described by a discrete droplet model (DDM). Numerical calculations for the flow and turbulent diffusion processes were performed on the basis of large eddy simulation (LES) to describe the processes of local non-homogeneous mixture formation and heat release. The oxidation processes in the mixture were calculated by Schreiber's five-step mechanism for n-heptane. Calculations were performed for sprays formed by single-stage injection and pilot/main two-stage injection. The flame structure in a diesel spray and its temporal change were discussed using a flame index proposed by Yamashita et al.

The tasks to improve diesel emissions and fuel consumption must be accomplished with urgency. However, due to the trade-off relationship between NOx emissions, soot emissions and fuel consumption, clean diesel combustion should be achieved by both innovative combustion and fuel technologies. The objective of this study is to extend the clean diesel combustion operating range (Engine-out emission: NOx ≺ 0.2 g/kWh, Soot ≺ 0.02 g/kWh). In this study, performance of a single-cylinder test engine equipped with a hydraulic valve actuation system and an ultra-high pressure fuel injection system was investigated. Also evaluated, were the effects of fuel properties such as auto-ignitability, volatility and aromatic hydrocarbon components, on combustion performance. The results show that applying a high EGR (Exhaust gas recirculation) rate can significantly reduce NOx emission with an increase in soot emission.

In order to meet the reinforcement of worldwide environmental regulations, latest diesel engines for industrial machinery are required to reduce the emission of harmful gases such as carbon monoxide (CO), hydrocarbon (HC) and nitrogen oxide (NOx), and particulate matter (PM). For this reason, some of the diesel engines are equipped with exhaust gas treatment devices such as diesel particulate filter (DPF), diesel oxidation catalyst (DOC) and selective catalytic reduction (SCR) catalyst. However, applications of such industrial diesel engines bring about excessive back pressure increase and deterioration in the performance of the catalysts when continuous operation is performed at low load conditions: soot accumulates on the inlet faces of DOC and DPF, causing face plugging issues. To resolve this issue, it is necessary for the system to be equipped with certain additional devices to raise an exhaust gas temperature to a high level enough to burn out the soot [1].

Hydrogen can be produced by electrolyzation with renewable electricity and the combustion products of hydrogen mixture include no CO, CO2 and hydrocarbons. In this study, engine performance with hydrogen / diesel dual fuel (hydrogen DDF) operation in a multi-cylinder diesel engine is investigated due to clarify advantages and disadvantages of hydrogen DDF operation. Hydrogen DDF operation under several brake power conditions are evaluated by changing a rate of hydrogen to total input energy (H2 rate). As H2 rate is increased, an amount of diesel fuel is decreased to keep a given torque constant. When the hydrogen DDF engine is operated with EGR, Exhaust gas components including carbon are improved or suppressed to same level as conventional diesel combustion. In addition, brake thermal efficiency is improved to 40% by increase in H2 rate that advances combustion phasing under higher power condition. On the other hand, NOx emission is much higher than one of conventional diesel engine.