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After several decades of human spaceflight, the community of space-faring nations has accumulated a diverse and sometimes harrowing history of toxicological events that have plagued human space endeavors almost from the very beginning. Some lessons have been learned in ground-based test beds and others were discovered the hard way - when human lives were at stake in space. From such lessons one can build a risk-management framework for toxicological events to minimize the probability of a harmful exposure, while recognizing that we cannot predict all possible events. Space toxicologists have learned that relatively harmless compounds can be converted by air revitalization systems into compounds that cause serious harm to the crew.

A Total Organic Carbon (TOC) Analyzer has been developed for a Life Sciences Risk Mitigation Flight Experiment to be conducted on Spacehab and the Russian space station, Mir. Initial launch is scheduled for December 1996 (flight STS-81). The analyzer will be tested on the Orbiter in the Spacehab module, including when the Orbiter is docked at the Mir space station. The analyzer is scheduled to be launched again in May 1997 (STS-84) when it will be transferred to Mir. During both flights the analyzer will measure the quality of recycled and ground-supplied potable water on the space station. Samples will be archived for later return to the ground, where they will be analyzed for comparison to in-flight results. Water test samples of known composition, brought up with the analyzer, also will be used to test its performance in microgravity. Ground-based analyses of duplicates of those test samples will be conducted concurrently with the in-flight analyses.

Absorption cooling using a lithium chloride/water heat pump can enable lightweight and effective thermal control for Extravehicular Activity (EVA) suits without venting water to the environment. The key components in the system are an absorber/radiator that rejects heat to space and a flexible evaporation cooling garment that absorbs heat from the crew member, This paper describes progress in the design, development, and testing of the absorber/radiator and evaporation cooling garment. New design concepts and fabrication approaches will significantly reduce the mass of the absorber/radiator. We have also identified materials and demonstrated fabrication approaches for production of a flexible evaporation cooling garment, Data from tests of the system's modular components have validated the design models and allowed predictions of the size and weight of a complete system.

The development of an optimum regenerative Advanced Life Support (ALS) system for future Mars missions has been a crucial issue in the space industry. Considering the numerous potential technologies for subsystems with the complexity of the Air Revitalization System (ARS), Water Reclamation System (WRS), and Waste Management System of the Environmental Control and Life Support System (ECLSS), it will be time-consuming and costly to determine the best combination of these technologies without a powerful sizing analysis tool. Johnson Space Center (JSC), therefore, initiated the development of ALSSAT using Microsoft® Excel for this purpose. ALSSAT has been developed based upon the ALS Requirement and Design Definition Document (Ref. 18). In 1999, a paper describing the development of ALSSAT with its built-in ARS mass balance model (Ref. 21) was published in ICES.

Future spacesuits will require thermal insulation protection in low-earth orbit (LEO), in the near-earth neighborhood and in planetary environments. In order to satisfy all future exploration needs and lower production and maintenance costs, a common thermal insulation is desirable that will perform well in all these environments. A highly promising material is a fiber-reinforced aerogel composite insulation currently being developed at the Johnson Space Center. This paper presents an overview of aerogels and their manufacture, a summary of the development of a flexible fiber-based aerogel for NASA by Aspen Aerogels, Inc., and performance data of aerogels relative to flexible commercial insulation. Finally, future plans are presented of how an aerogel-based insulation may be integrated into a spacesuit for ground testing as well as for a flight configuration.

When technologies are traded for incorporation into vehicle systems to support a specific mission scenario, they are often assessed in terms of “Technology Readiness Level” (TRL). TRL is based on three major categories of Core Technology Components, Ancillary Hardware and System Maturity, and Control and Control Integration. This paper describes the Technology Readiness Level assessment of the Carbon Dioxide Reduction Assembly (CRA) for use on the International Space Station. A team comprising of the NASA Johnson Space Center, Marshall Space Flight Center, Southwest Research Institute and Hamilton Sundstrand Space Systems International have been working on various aspects of the CRA to bring its TRL from 4/5 up to 6. This paper describes the work currently being done in the three major categories. Specific details are given on technology development of the Core Technology Components including the reactor, phase separator and CO2 compressor.

This paper reviews the evolution and current state of atmospheric monitoring on the International Space Station to provide context from which we can imagine a more advanced and integrated system. The unique environmental hazards of human space flight are identified and categorized into groups, taking into consideration the time required for the hazard to become a threat to human health or performance. The key functions of a comprehensive monitoring strategy for a closed ecological life support system are derived from past experience and a survey of currently available technologies for monitoring air quality. Finally, a system architecture is developed incorporating the lessons learned from ISS and other analogous closed life support systems. The paper concludes by presenting recommendations on how to proceed with requirements definition and conceptual design of an air monitoring system for exploration missions.

Hamilton Sundstrand Space Systems International (HSSSI) is currently under contract with NASA MSFC to design, fabricate and deliver the Water Processor Assembly (WPA) for the International Space Station (ISS). As part of this effort HSSSI has developed an oxidation catalyst for the catalytic reactor assembly in the WPA. This paper discusses full-scale development reactor testing and the status of the life testing of the oxidation catalyst used in the reactor.

Twenty-nine recycled water, eight stored (ground-supplied) water, and twenty-eight humidity condensate samples were collected on board the Mir Space Station during the Phase One Program (1995-1998). These samples were analyzed to determine potability of the recycled and ground-supplied water, to support the development of water quality monitoring procedures and standards, and to assist in the development of water reclamation hardware. This paper describes and summarizes the results of these analyses and lists the lessons learned from this project. Results show that the recycled water and stored water on board Mir, in general, met NASA, Russian Space Agency (RSA), and U.S. Environmental Protection Agency (EPA) standards.

Potable- and hygiene-quality water will be supplied to crews on the International Space Station through the recovery and purification of spacecraft wastewaters, including humidity condensate, urine, and wash water. Contaminants released into the cabin air from human metabolism, hardware offgassing, flight experiments, and routine operations will be present in spacecraft humidity condensate; normal constituents of urine and bathing water will be present in urine and untreated wash water. This report describes results from detailed analyses of Mir reclaimed potable water, ground-supplied water, and humidity condensate. These results are being used to develop and test water recycling and monitoring systems for the International Space Station (ISS); to evaluate the efficiency of the Mir water processors; and to determine the potability of the recycled water on board.

Supply of oxygen (O2) and hydrogen (H2) by electrolyzing water in space will play an important role in meeting the National Aeronautics and Space Administration's (NASA's) needs and goals for future space missions. Both O2 and H2 are envisioned to be used in a variety of processes including crew life support, spacecraft propulsion, extravehicular activity, electrical power generation/storage as well as in scientific experiment and manufacturing processes. Life Systems, Inc., in conjunction with NASA, has been developing an alkaline-based Static Feed Electrolyzer (SFE). During the development of the water electrolysis technology over the past 23 years, an extensive engineering and scientific data base has been assembled.

Hamilton Sundstrand Space Systems International, Inc. (HSSSI) is under contract to NASA Marshall Space Flight Center (MSFC) to develop a Water Processor Assembly (WPA) and Oxygen Generation Assembly (OGA) for the International Space Station (ISS). The WPA produces potable quality water from humidity condensate, carbon dioxide reduction water, water obtained from fuel cells, reclaimed urine distillate, shower, handwash and oral hygiene waste waters. The Oxygen Generation Assembly (OGA) electrolyzes potable water from the Water Recovery System (WRS) to provide gaseous oxygen to the Space Station module atmosphere. The OGA produces oxygen for metabolic consumption by crew and biological specimens. The OGA also replenishes oxygen lost by experiment ingestion, airlock depressurization, CO2 venting, and leakage. As a byproduct, gaseous hydrogen is generated. The hydrogen will be supplied at a specified pressure range to support future utilization.

Hamilton Sundstrand Space Systems International, Inc. HSSSI) is under contract to NASA Marshall Space Flight Center (MSFC) to develop a Water Processor Assembly (WPA) and Oxygen Generation Assembly (OGA) for the International Space Station (ISS). The WPA produces potable quality water from humidity condensate, carbon dioxide reduction water, water obtained from fuel cells, reclaimed urine distillate, shower, handwash and oral hygiene waste waters. The Oxygen Generation Assembly (OGA) electrolyzes potable water from the Water Recover System (WRS) to provide gaseous oxygen to the Space Station module atmosphere. The OGA produces oxygen for metabolic consumption by crew and biological specimens. The OGA also replenishes oxygen lost by experiment ingestion, airlock depressurization, CO2 venting, and leakage. As a byproduct, gaseous hydrogen is generated. The hydrogen will be supplied at a specified pressure range to support future utilization.

Hamilton Sundstrand Space Systems International, Inc. (HSSSI) is under contract to NASA Marshall Space Flight Center (MSFC) to develop a Water Processor Assembly (WPA) for the International Space Station (ISS). The WPA produces potable quality water from humidity condensate, carbon dioxide reduction water, water obtained from fuel cells, reclaimed urine distillate, shower, handwash and oral hygiene wastewaters. All planned development testing has been completed and this paper provides the status of the development activities and results for the WPA.

Hamilton Sundstrand Space Systems International, Inc. (HSSSI) is under contract to NASA Marshall Space Flight Center (MSFC) to develop, an Oxygen Generation Assembly (OGA) for the International Space Station (ISS). The Oxygen Generation Assembly (OGA) electrolyzes potable water from the Water Recovery System (WRS) to provide gaseous oxygen to the Space Station module atmosphere. The OGA produces oxygen for metabolic consumption by crew and biological specimens. The OGA also replenishes oxygen lost by experiment ingestion, airlock depressurization, CO2 venting, and leakage. As a byproduct, gaseous hydrogen is generated. The hydrogen will be supplied at a specified pressure range to support future utilization. Initially, the hydrogen will be vented overboard to space vacuum. The OGA has been under development at HSSSI for 3 years. This paper will update last year's ICES paper on the design/development of the OGA.

The purification of waste water is a critical element of any long-duration space mission. The Vapor Phase Catalytic Ammonia Removal (VPCAR) system offers the promise of a technology requiring low quantities of expendable material that is suitable for exploration missions. NASA has funded an effort to produce an engineering development unit specifically targeted for integration into the NASA Johnson Space Center's Integrated Human Exploration Mission Simulation Facility (INTEGRITY) formally known in part as the Bioregenerative Planetary Life Support Test Complex (Bio-Plex) and the Advanced Water Recovery System Development Facility. The system includes a Wiped-Film Rotating-Disk (WFRD) evaporator redesigned with micro-gravity operation enhancements, which evaporates wastewater and produces water vapor with only volatile components as contaminants. Volatile contaminants, including organics and ammonia, are oxidized in a catalytic reactor while they are in the vapor phase.

Sublimators have been used for heat rejection for a variety of space applications including the Apollo Lunar Module and the Extravehicular Mobility Unit (EMU). Sublimators are excellent candidates for heat rejection devices on future vehicles like the Crew Exploration Vehicle (CEV), the Lunar Surface Access Module (LSAM), and future spacesuits. One of the drawbacks of previous designs was sensitivity to contamination in the feedwater. Undissolved contaminants can be removed with filters, but dissolved contaminants would be left in the pores of the porous plates in which the feedwater freezes and sublimates. These contaminants build up and clog the relatively small pores (~3–6 μm), thereby blocking the flow of the feedwater, reducing the available area for freezing and sublimation, and degrading the performance of the sublimator. For the X-38 program, a new sublimator design was developed by NASA-JSC that is less sensitive to contaminants.

Biological water processors are currently being developed for application in microgravity environments. Work has been performed to develop a single-phase, gravity independent anoxic denitrification reactor for organic carbon removal [1]. As a follow on to this work it was necessary to develop a gravity independent nitrification reactor in order to provide sufficient nitrite and nitrate to the organic carbon oxidation reactor for the complete removal of organic carbon. One approach for providing the significant amounts of dissolved oxygen required for nitrification is to require the biological reactor design to process two-phase gas and liquid in micro-gravity. This paper addresses the design and test results overview for development of a tubular, two-phase, gravity independent nitrification biological water processor.

A Rotary Separator/Accumulator (RSA) has been developed to function as a phase separator and accumulator in the Oxygen Generator Assembly (OGA) in the microgravity environment of the International Space Station. The RSA design utilizes a fixed housing with rotating disks to create a centrifugal force field to separate hydrogen gas from water. The volume within the assembly is utilized to act as an accumulator for the OGA. During the development of the RSA, design refinements were made to meet the changing system operating requirements. Two proof of concept (POC) units and a “flight-like” development unit were fabricated and tested as system requirements evolved. Testing of the first POC unit demonstrated that a combined rotary separator and accumulator was feasible and showed areas where improvements could be made. The second POC unit incorporated a fifty percent volume increase to accommodate changing system requirements and geometry changes to help reduce power consumption.

Enhancements to the Regenerable Carbon Dioxide Removal System (RCRS) have undergone full-scale, pre-prototype development and testing to demonstrate a redundant system within the volume allotted for the RCRS on the Space Shuttle Orbiter. The concept for a Redundant Regenerable Carbon Dioxide Removal System (RRCRS) utilizes the existing canister of the RCRS, but partitions it into two, independent, two-bed systems. This partitioning allows for two, fully capable RCRS units to be packaged within the original volume, thus reducing stowage volume and launch weight when compared to the flight RCRS plus the backup LiOH system. This paper presents the results of development and testing of a full-scale, pre-prototype RRCRS and includes an overview of the design concept for a redundant system that can be packaged within the existing envelope.