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Journal Article

Evaluation of the Oxidation Stability of Diesel/Biodiesel Blends using the Modified Rancimat Method

2009-06-15
2009-01-1828
This study describes the effect of different types of biodiesel (fatty acid methyl esters, FAME) on the oxidative stability of low and ultra low sulfur automotive diesel fuels. Eight different samples of FAME were employed to create blends of 2, 3, 4, 5, 7, and 10% v/v with four different types of diesel fuels. The samples were analyzed using the modified Rancimat method (EN 15751). The aim of this paper was to evaluate the impact of biodiesel source material and biodiesel concentration in diesel fuel, on the oxidation stability of the final blend. Moreover, the effect of sulfur content and the presence of cracked stocks in the base diesel fuel, on the oxidation stability of the final blends were also investigated.
Journal Article

Impact of Simultaneous ETBE and Ethanol Addition on Motor Gasoline Properties

2008-10-06
2008-01-2503
This study examines the impact of ETBE and ethanol addition on the main properties of motor gasoline. European Union mandates the use of biofuels in all transport fuels, according to the 2003/30/EC Directive. The addition of ethanol, a known octane enhancing component, in small proportions significantly increases the vapor pressure of the final gasoline, exceeding the maximum specification limits. ETBE (ethyl tert-butyl ether) is on the other hand an excellent but expensive octane enhancing component with beneficial impact on vapor pressure of the final gasoline. This paper examines the ability of ETBE to act as a stabilizer in gasoline - ethanol blends. Two gasoline samples with different chemical compositions and characteristics were prepared by blending basic refinery components. In each sample, ETBE was added in concentrations of 2, 4, and 6 % V/V respectively. In each of these ETBE - gasoline blends, ethanol was added in concentrations from 1 to 6 % V/V in 1% steps.
Journal Article

Regulated and Unregulated Emissions of a Euro 4 SUV Operated with Diesel and Soy-based Biodiesel Blends

2009-11-02
2009-01-2690
In this study, regulated, unregulated exhaust emissions and fuel consumption with ultra low sulphur diesel and soy-based biodiesel blends at proportions of 10 and 30% v/v have been investigated. A Euro 4 compliant SUV, equipped with a 2.2 litre common-rail diesel engine and an oxidation catalyst was tested on a chassis dynamometer with constant volume sampling (CVS) technique. Emission and fuel consumption measurements were performed over the New European Driving Cycle (NEDC) and the non-legislated Artemis driving cycles which simulate urban, rural, and highway driving conditions in Europe. The regulated pollutants were characterized by determined NOx, PM, CO, and HC. CO2 was also quantified in the exhaust. Overall, 16 PAHs, 4 nitro-PAHs, 6 oxy-PAHs, 13 carbonyl compounds and particulate alkanes ranged from C13 to C35 were determined in the exhaust.
Technical Paper

The Effect of Biodiesel on PAHs, Nitro-PAHs and Oxy-PAHs Emissions from a Light Vehicle Operated Over the European and the Artemis Driving Cycles

2009-06-15
2009-01-1895
This study examines the effects of neat soy-based biodiesel (B100) and its 50% v/v blend (B50) with low sulphur automotive diesel on vehicle PAH emissions. The measurements were conducted on a chassis dynamometer with constant volume sampling (CVS) according to the European regulated technique. The vehicle was a Euro 2 compliant diesel passenger car, equipped with a 1.9 litre common-rail turbocharged direct injection engine and an oxidation catalyst. Emissions of PAHs, nitro-PAHs and oxy-PAHs were measured over the urban phase (UDC) and the extra-urban phase (EUDC) of the type approval cycle (NEDC). In addition, for evaluating realistic driving performance the non-legislated Artemis driving cycles (Urban, Road and Motorway) were used. Overall, 12 PAHs, 4 nitro-PAHs, and 6 oxy-PAHs were determined. The results indicated that PAH emissions exhibited a reduction with biodiesel during all driving modes.
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