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The greenhouse gas emission reduction targets agreed at Kyoto represent a first step to reduce emissions in the long term in order to stabilize the earth's climate. The European Union has made an important contribution to the Kyoto agreement and the European Commission intends to develop a strategy to reach the Union's Kyoto target. This will require action in all sectors of the economy including the transport sector. Of the six gases covered by the Kyoto protocol, carbon dioxide (CO2) is the most important as it accounts for about 80% of the total global warming potential of all six greenhouse gases. In the European Union, the share of transport CO2 emissions in total increased from 19% in 1985 to 26% in 1995. Road traffic is the most important source, and largely determines the trend in the transport sector; and road freight accounts for about 35% of transport CO2 emissions. As well as CO2, road freight transport causes considerable amounts of other pollutant emissions.

Society is moving towards climate neutrality where hydrogen fuelled combustion engines (H2 ICE) could be considered a main technology. These engines run on hydrogen (H2) so carbon-based emission are only present at a very low level from the lube oil. The most important pollutants NO and NO2 are caused by the exhaust aftertreatment system as well as CO2 coming from the ambient air. For standard measurement technologies these low levels of CO2 are hard to detect due to the high water content. Normal levels of CO2 are between 400-500 ppm which is very close or even below the detection limit of commonly used non-dispersive-infrared-detectors (NDIR). As well the high water content is very challenging for NOx measuring devices, like chemiluminescence detectors (CLD), where it results in higher noise and therefore a worse detection limit. Even for Fourier-transformed-infrared-spectroscopy-analysers (FT-IR) it is challenging to deal with water content over 15% without increased noise.

In this paper, we will show the potentials of reducing NOx emissions of an H2-ICE to an ultra-low level by hybridizing the H2-ICE in an NRMM powertrain. Real-world measurement data of NRMM together with a simulated hybrid powertrain and operating strategy form the input data for the H2-ICE on the test bench. We have modified a turbocharged four-cylinder in-line gasoline engine for use with directly injected hydrogen. Within several iteration loops, we obtained measurement data that shows that, depending on the operating strategy, ultra-low NOx emissions are reachable. The combination of hybridization, which implies the possibility of recuperation, and the CO2 emission-free H2-ICE leads to a highly efficient, robust, and economic drivetrain with the lowest emissions, perfectly suitable for Non-Road Machinery. Additionally, we will discuss the overall coupled measurement and simulation setup and the reachable NOx emission levels in our tested setup.

To minimize nitrogen oxide (NOx) as well as carbon monoxide (CO) and hydrocarbon (HC) emissions to fulfil the new European real driving emissions (RDE) legislation, the LNT operation strategy - especially for DeNOx events (rich mode) - has to be optimized. On one hand the DeNOx purges should be long enough to fully regenerate the lean NOx trap, on the other hand the purges should be as short as possible to reduce the fuel consumption penalty from rich mode. Fundamental experiments have been conducted on a synthetic-gas-test-bench, purposely designed to test LNT catalysts. This methodology allowed to remove NOx from the gasfeed after the lean storage phase. The actually reduced amount of NOx could be easily calculated from the NOx storage before a regeneration event minus the NOx that was desorbed during the DeNOx event and afterwards thermally desorbed NOx.

Currently, emission regulations for the LVs using standard spark ignited ICEs considering only gaseous pollutants, just as CO, HC and NOx. Following the upcoming legislation for personal vehicles sector, the LVs might also include limits of PN and PM. Regarding fuel injection strategies, the MPFI which was previously excluded from particulate control will be incorporated into the new regulation [1]. In terms of social harm, there will be a necessity to reduce engine particulate emissions, as they are known for being carcinogenic substances [2, 3, 4]. Generally, the smaller the particulate diameter, the more critical are the damages for human health therefore, the correct determination of PN and particulate diameter is essential. Beside future challenges for reducing and controlling particulates, the reduction of fossil fuel usage is also an imminent target, being the replacement by eFuels one of the most promising alternatives.

This paper describes the development of a 0-D-sulfur poisoning model for a NOx storage catalyst (NSC). The model was developed and calibrated using findings and data obtained from a passenger car diesel engine used on testbed. Based on an empirical approach, the developed model is able to predict not only the lower sulfur adsorption with increasing temperature and therefore the higher SOx (SO2 and SO3) slip after NSC, but also the sulfur saturation with increasing sulfur loading, resulting in a decrease of the sulfur adsorption rate with ongoing sulfation. Furthermore, the 0-D sulfur poisoning model was integrated into an existing 1-D NOx storage catalyst kinetic model. The combination of the two models results in an “EAS Model” (exhaust aftertreatment system) able to predict the deterioration of NOx-storage in a NSC with increasing sulfation level, exhibiting higher NOx-emissions after the NSC once it is poisoned.