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Technical Paper

1D Model of a Copper Exchanged Small Pore Zeolite Catalyst Based on Transient SCR Protocol

2013-04-08
2013-01-1578
Urea-selective catalytic reduction (SCR) catalysts are the leading aftertreatment technology for diesel engines, but there are major challenges associated with meeting future NOx emission standards, especially under transient drive cycle conditions that include large swings in exhaust temperatures. Here we present a simplified, transient, one-dimensional integral model of NOx reduction by NH₃ on a commercial small-pore Cu-zeolite urea-SCR catalyst for which detailed kinetic parameters have not been published. The model was developed and validated using data acquired from bench reactor experiments on a monolith core, following a transient SCR reactor protocol. The protocol incorporates NH₃ storage, NH₃ oxidation, NO oxidation and three global SCR reactions under isothermal conditions, at three space velocities and at three NH₃/NOx ratios.
Technical Paper

3D-Semi 1D Coupling for a Complete Simulation of an SCR System

2013-04-08
2013-01-1575
The presented work describes how numerical modeling techniques were extended to simulate a full Selective Catalytic Reduction (SCR) NOx aftertreatement system. Besides predicting ammonia-to-NOX ratio (ANR) and uniformity index (UI) at the SCR inlet, the developed numerical model was able to predict NOx reduction and ammonia slip. To reduce the calculation time due to the complexity of the chemical process and flow field within the SCR, a semi-1D approach was developed and applied to model the SCR catalyst, which was subsequently coupled with a 3D model of the rest of the exhaust system. Droplet depletion of urea water solution (UWS) was modeled by vaporization and thermolysis techniques while ammonia generation was modeled by the thermolysis and hydrolysis method. Test data of two different SCR systems were used to calibrate the simulation results. Results obtained using the thermolysis method showed better agreement with test data compared to the vaporization method.
Technical Paper

42 Catalytic Reduction of Marine Sterndrive Engine Emissions

2002-10-29
2002-32-1811
A 2001 General Motors 4.3 liter V-6 marine engine was baseline emissions tested and then equipped with catalysts. Emission reduction effects of exhaust gas recirculation (EGR) were also explored. Because of a U.S. Coast Guard requirement that inboard engine surface temperatures be kept below 200°F, the engine's exhaust system, including the catalysts, was water-cooled. Engine emissions were measured using the ISO-8178-E4 5-mode steady-state test for recreational marine engines. In baseline configuration, the engine produced 16.6 g HC+NOx/kW-hr, and 111 g CO/kW-hr. In closed-loop control with catalysts, HC+NOx emissions were reduced by 75 percent to 4.1 g/kW-hr, and CO emissions were reduced by 36 percent to 70 g/kW-hr of CO. The catalyzed engine was then installed in a Sea Ray 190 boat, and tested for water reversion on both fresh and salt water using National Marine Manufacturers Association procedures.
Technical Paper

A Bench Test Facility for Engine Muffler Evaluation

1963-01-01
630283
The problem associated with laboratory evaluation of muffler acoustical characteristics are complicated both by the acoustical considerations involved in obtaining an adequate noise source and by the ambiguities involved in defining what constitutes quality in a muffler built for general application. In order to quantitatively define the characteristics of quality mufflers, an extensive series of field tests were conducted on a variety of sizes and types of mufflers in conjunction with four engine configurations. Work then turned to the development of a wide band siren noise source and acoustical test system which would simulate the high impedance character of an engine exhaust noise source, and in addition generate the necessary intensity and spectral characteristics required to obtain test data over the range of noise conditions encountered in the field.
Technical Paper

A Comparative Life Cycle Assessment of Magnesium Front End Autoparts: A Revision to 2010-01-0275

2012-12-31
2012-01-2325
The Magnesium Front End Research and Development (MFERD) project under the sponsorship of Canada, China, and USA aims to develop key technologies and a knowledge base for increased use of magnesium in automobiles. The primary goal of this life cycle assessment (LCA) study is to compare the energy and potential environmental impacts of advanced magnesium based front end parts of a North American-built 2007 GM-Cadillac CTS using the current steel structure as a baseline. An aluminium front end is also considered as an alternate light structure scenario. A “cradle-to-grave” LCA is conducted by including primary material production, semi-fabrication production, autoparts manufacturing and assembly, transportation, use phase, and end-of-life processing of autoparts. This LCA study was done in compliance with international standards ISO 14040:2006 [1] and ISO 14044:2006 [2].
Technical Paper

A Comparison of Emissions and Flow Restriction of Thinwall Ceramic Substrates for Low Emission Vehicles

1999-03-01
1999-01-0271
The emission and flow restriction characteristics of three different ceramic substrates with varying wall thickness and cell density (400 cpsi/6.5 mil, 600/4.3, and 600/3.5) are compared. These 106mm diameter substrates were catalyzed with similar amounts of washcoat and fabricated into catalytic converters having a total volume of 2.0 liters. A Pd/Rh catalyst technology was applied at a concentration of 6.65 g/l and a ratio of 20/1. Three sets of converters (two of each type) were aged for 100 hours on an engine dynamometer stand. After aging, the FTP performance of these converters were evaluated on an auto-driver FTP stand using a 2.4L, four-cylinder prototype engine and on a 2.4L, four-cylinder prototype vehicle. A third set of unaged converters was used for cold flow restriction measurements and vehicle acceleration tests.
Technical Paper

A Controls Overview on Achieving Ultra-Low NOx

2020-04-14
2020-01-1404
The California Air Resources Board (CARB)-funded Stage 3 Heavy-Duty Low NOX program focusses on evaluating different engine and after-treatment technologies to achieve 0.02g/bhp-hr of NOX emission over certification cycles. This paper highlights the controls architecture of the engine and after-treatment systems and discusses the effects of various strategies implemented and tested in an engine test cell over various heavy-duty drive cycles. A Cylinder De-Activation (CDA) system enabled engine was integrated with an advanced after-treatment controller and system package. Southwest Research Institute (SwRI) had implemented a model-based controller for the Selective Catalytic Reduction (SCR) system in the CARB Stage 1 Low-NOX program. The chemical kinetics for the model-based controller were further tuned and implemented in order to accurately represent the reactions for the catalysts used in this program.
Technical Paper

A Critical Analysis of Traffic Accident Data

1975-02-01
750916
General agreement exists that the ultimate goals of traffic accident research are to reduce fatality, mitigate injury and decrease economic loss to society. Although massive quantities of data have been collected in local, national and international programs, attempts by analysts to use these data to explore ideas or support hypotheses have been met by a variety of problems. Specifically, the coded variables in the different files are not consistent and little information on accident etiology is collected. Examples of the inadequacies of present data in terms of the collected and coded variables are shown. The vehicular, environmental and human (consisting of human factors and injury factors) variables are disproportionately represented in most existing data files in terms of recognized statistical evidence of accident causation. A systems approach is needed to identify critical, currently neglected variables and develop units of measurement and data collection procedures.
Technical Paper

A Fundamental Consideration on NOx Adsorber Technology for DI Diesel Application

2002-10-21
2002-01-2889
Diesel engines are far more efficient than gasoline engines of comparable size, and emit less greenhouse gases that have been implicated in global warming. In 2000, the US EPA proposed very stringent emissions standards to be introduced in 2007 along with low sulfur (< 15 ppm) diesel fuel. The California Air Resource Board (CARB) has also established the principle that future diesel fueled vehicles should meet the same low emissions standards as gasoline fueled vehicles and the EPA followed suit with its Tier II emissions regulation. Achieving such low emissions cannot be done through engine development and fuel reformulation alone, and requires application of NOx and particulate matter (PM) aftertreatment control devices. There is a widespread consensus that NOx adsorbers and particulate filter are required in order for diesel engines to meet the 2007 emissions regulations for NOx and PM. In this paper, the key exhaust characteristics from an advanced diesel engine are reviewed.
Technical Paper

A History of Mack Engine Lubricant Tests from 1985-2005: Mack T-7 through Mack T-12

2005-10-24
2005-01-3713
As on-highway, heavy-duty diesel engine designs have evolved to meet tighter emissions specifications and greater customer requirements, the crankcase environment for heavy-duty engine lubricants has changed. Engine lubricant quality is very important to help ensure engine durability, engine performance, and reduce maintenance downtime. Beginning in the late 1980's, a new Mack genuine oil specification and a new American Petroleum Institute (API) heavy-duty engine lubricant category have been introduced with each new U.S. heavy-duty, on-highway emissions specification. This paper documents the history and development of the Mack T-7, T-8, T-8A, T-8E, T-9, T-10, T-11, and T-12 engine lubricant tests.
Technical Paper

A Modeling Study of SCR Reaction Kinetics from Reactor Experiments

2013-04-08
2013-01-1576
In order to further characterize and optimize the performance of Selective Catalytic Reduction (SCR) aftertreatment systems used on heavy-duty diesel engines, an accurately calibrated high-fidelity multi-step global kinetic SCR model and a reduced order estimator for on-board diagnostic (OBD) and control are desirable. In this study, a Cu-zeolite SCR catalyst from a 2010 Cummins ISB engine was experimentally studied in a flow reactor using carefully designed protocols. A 2-site SCR model describing mass transfer and the SCR chemical reaction mechanisms is described in the paper. The model was calibrated to the reactor test data sets collected under temperatures from 200 to 425 °C and SCR space velocities of 60000, 90000, and 120000 hr-1. The model parameters were calibrated using an optimization code to minimize the error between measured and simulated NO, NO₂, N₂O, and NH₃ gas concentration time histories.
Technical Paper

A Next-Generation Emission Test Procedure for Small Utility Engines - Part 1, Background and Approach

1990-09-01
901595
Measurement of emissions from small utility engines has usually been accomplished using steady-state raw emissions procedures such as SAE Recommended Practice J1088. While raw exhaust measurements have the advantage of producing modal exhaust gas concentration data for design feedback; they are laborious, may influence both engine performance and the emissions themselves, and have no provision for concurrent particulate measurements. It is time to consider a full-dilution procedure similar in principle to automotive and heavy-duty on-highway emission measurement practice, leading to improvements in many of the areas noted above, and generally to much higher confidence in data obtained. When certification and audit of small engine emissions become a reality, a brief dilute exhaust procedure generating only the necessary data will be a tremendous advantage to both manufacturers and regulatory agencies.
Technical Paper

A Novel Capability for Crush Testing Crash Energy Management Structures at Intermediate Rates

2002-06-03
2002-01-1954
The crush performance of lightweight composite automotive structures varies significantly between static and dynamic test conditions. This paper discusses the development of a new dynamic testing facility that can be used to characterize crash performance at high loads and constant speed. Previous research results from the Energy Management Working Group (EMWG) of the Automotive Composites Consortium (ACC) showed that the static crush resistance of composite tubes can be significantly greater than dynamic crush results at speeds greater than 2 m/s. The new testing facility will provide the unique capability to crush structures at high loads in the intermediate velocity range. A novel machine control system was designed and projections of the machine performance indicate its compliance with the desired test tolerances. The test machine will be part of a national user facility at the Oak Ridge National Laboratory (ORNL) and will be available for use in the summer of 2002.
Technical Paper

A Performance Comparison of Various Automatic Transmission Pumping Systems

1996-02-01
960424
The pumping system used in a step ratio automatic transmission can consume up to 20% of the total power required to operate a typical automotive transmission through the EPA city cycle. As such, it represents an area manufacturers have focused their efforts towards in their quest to obtain improved transmission efficiency. This paper will discuss the history of automatic transmission pumps that develop up to 300 psi along with a description of the factors used to size pumps and establish pump flow requirements. The various types of pumps used in current automatic transmissions will be described with a discussion of their characteristics including a comparison based upon observations of their performance. Specific attention will be focused on comparing the volumetric efficiency, mechanical efficiency, overall efficiency, pumping torque and discharge flow.
Technical Paper

A Review of Diesel Particulate Filter Technologies

2003-06-23
2003-01-2303
Diesel particulate filters (DPF), known as traps in the mid-to late 1970s, were being developed for on-highway diesel applications. However, advanced engine design and in-cylinder engineering enabled diesel engines and vehicles to meet extremely low emission limits, including those of particulate matter (PM) without the need for DPF's or other auxiliary emission control devices. Late in 2000, the US EPA finalized its on-highway heavy-duty diesel emission standards, thus ending speculations regarding its stringency and establishing the lowest limits ever. The new nitric oxides (NOX) and PM limits are seen as technology-forcing. For NOX emissions, the debate rages on among the technical community about the merits of NOX adsorbers and urea selective catalytic reduction. On the other hand, there seems to be little doubt about DPF's as the technical solution for PM.
Technical Paper

A Test Method for Evaluating Feasibility of Lean Nitrous Oxide Traps

2011-01-19
2011-26-0030
The Lean NOx Trap (LNT) is a technology that could be used to reduce oxides of nitrogen from heavy-duty diesel engines to meet emissions standards (US 2010 and EURO 4/5/6). This paper describes a case-study for evaluating the feasibility of an LNT. LNTs suffer from sulfur poisoning and thermal aging limitations. Catalyst formulations allow reversal of sulfur poisoning through desulfation procedures. A case study was performed using a 7-liter diesel engine equipped with VGT, common rail fuel injection system, cooled EGR, oxidation catalyst and DPF. The LNT was positioned after the particulate filter. Gaseous raw emissions were measured from engine and various stages of aftertreatment. A Fourier Transform Infrared (FTIR) analyzer was used to characterize Ammonia and SO₂. Temperatures were measured in the substrate. Fast response NOx sensor allowed for continuous monitoring of the NOx in the LNT. A wide-range O₂ sensor was also utilized to measure equivalence ratio.
Technical Paper

A Zero Trust Architecture for Automotive Networks

2024-04-09
2024-01-2793
Since the early 1990’s, commercial vehicles have suffered from repeated vulnerability exploitations that resulted in a need for improved automotive cybersecurity. This paper outlines the strategies and challenges of implementing an automotive Zero Trust Architecture (ZTA) to secure intra-vehicle networks. Zero Trust (ZT) originated as an Information Technology (IT) principle of “never trust, always verify”; it is the concept that a network must never assume assets can be trusted regardless of their ownership or network location. This research focused on drastically improving security of the cyber-physical vehicle network, with minimal performance impact measured as timing, bandwidth, and processing power. The automotive ZTA was tested using a software-in-the-loop vehicle simulation paired with resource constrained hardware that closely emulated a production vehicle network.
Technical Paper

AN AIRFLOW-DOMINANT CONTROL SYSTEM FOR FUTURE DIESEL ENGINES

2007-07-23
2007-01-2070
An airflow-dominant control system was developed to provide precise engine and exhaust treatment control with low air fuel ratio alternative combustion. The main elements of the control logic include a real-time state observer for in-cylinder oxygen mass estimation, a simplified packaging scheme for all air-handling and fueling parameters, a finite state machine for control mode switching, combustion control models to maintain robust alternative combustion during transients, and smooth rich/lean switching during lean NOx trap (LNT) regeneration without post injection. The control logic was evaluated on a passenger car equipped with a 4-way catalyst system with LNT and was instrumental in achieving US Tier II Bin 5 emission targets with good drivability and low NVH.
Technical Paper

Achieving Heavy-Duty Diesel NOx/PM Levels Below the EPA 2002 Standards--An Integrated Solution

2000-03-06
2000-01-0187
The diesel engine has long been the most energy efficient powerplant for transportation. Moreover, diesels emit extremely low levels of hydrocarbon and carbon monoxide that do not require post-combustion treatment to comply with current and projected standards. It is admittedly, however, difficult for diesel engines to simultaneously meet projected nitrogen oxides and particulate matter standards. Traditionally, measures aimed at reducing one of these two exhaust species have led to increasing the other. This physical characteristic, which is known as NOx/PM tradeoff, remains the subject of an intense research effort. Despite this challenge, there is significant evidence that heavy-duty highway engine manufacturers can achieve substantial emission reductions. Many development programs carried out over the last five years have yielded remarkable results in laboratory demonstrations.
Technical Paper

Achieving Tier 2 Bin 5 Emission Levels with a Medium Duty Diesel Pick-Up and a NOX Adsorber, Diesel Particulate Filter Emissions System-Exhaust Gas Temperature Management

2004-03-08
2004-01-0584
Increasing fuel costs and the desire for reduced dependence on foreign oil has brought the diesel engine to the forefront of future medium-duty vehicle applications in the United States due to its higher thermal efficiency and superior durability. The main obstacle to the increased use of diesel engines in this platform is the upcoming extremely stringent, Tier 2 emission standard. In order to succeed, diesel vehicles must comply with emissions standards while maintaining their excellent fuel economy. The availability of technologies such as common rail fuel injection systems, low sulfur diesel fuel, NOX adsorber catalysts (NAC), and diesel particle filters (DPFs) allow the development of powertrain systems that have the potential to comply with these future requirements. In meeting the Tier 2 emissions standards, the heavy light-duty trucks (HLDTs) and medium-duty passenger vehicles (MDPVs) will face the greatest technological challenges. In support of this, the U.S.
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