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Urea-selective catalytic reduction (SCR) catalysts are the leading aftertreatment technology for diesel engines, but there are major challenges associated with meeting future NOx emission standards, especially under transient drive cycle conditions that include large swings in exhaust temperatures. Here we present a simplified, transient, one-dimensional integral model of NOx reduction by NH₃ on a commercial small-pore Cu-zeolite urea-SCR catalyst for which detailed kinetic parameters have not been published. The model was developed and validated using data acquired from bench reactor experiments on a monolith core, following a transient SCR reactor protocol. The protocol incorporates NH₃ storage, NH₃ oxidation, NO oxidation and three global SCR reactions under isothermal conditions, at three space velocities and at three NH₃/NOx ratios.

The affordability of today's and future advanced technology vehicles (i.e., diesel, hybrid, and fuel cell) developed for improved fuel economy remains a concern with respect to final consumer acceptance. The automotive system cost model (ASCM) developed for the production cost estimates at a level of five major subsystems and 35+ components, has been used here to address the affordability issue of advanced technology vehicles. Scenarios encompassing five alternative powertrain and three body options for a mid-size vehicle under two different timeframes (i.e., 2002 and 2010) were considered to determine the cost-effectiveness of among the competing technology options within the same timeframe and between the two timeframes.

The Magnesium Front End Research and Development (MFERD) project under the sponsorship of Canada, China, and USA aims to develop key technologies and a knowledge base for increased use of magnesium in automobiles. The primary goal of this life cycle assessment (LCA) study is to compare the energy and potential environmental impacts of advanced magnesium based front end parts of a North American-built 2007 GM-Cadillac CTS using the current steel structure as a baseline. An aluminium front end is also considered as an alternate light structure scenario. A “cradle-to-grave” LCA is conducted by including primary material production, semi-fabrication production, autoparts manufacturing and assembly, transportation, use phase, and end-of-life processing of autoparts. This LCA study was done in compliance with international standards ISO 14040:2006 [1] and ISO 14044:2006 [2].

While gasoline surrogate development has progressed in the areas of more complex surrogate mixtures and in kinetic modeling tools and mechanism development, it is generally recognized that further development is still needed. This paper represents a small step in supporting this development by providing comparisons between experimental engine data and surrogate-based kinetic models. In our case, the HCCI engine data comes from a port-injected, single-cylinder research engine with intake-air heating for combustion phasing control. Timing sweeps were run at constant fuel rate for three market gasolines and five surrogate mixtures. Modeling was done using the CHEMKIN software with a gasoline mechanism set containing 1440 species and 6572 reactions. Five pure compounds were selected for the surrogate blends and include iso-octane, n-heptane, toluene, methylcyclohexane, and 1-hexene.

One scenario for reducing engine out NOx in a spark ignition engine is to introduce small amounts of supplemental hydrogen to the combustion process. The supplemental hydrogen enables a gasoline engine to run lean where NOx emissions are significantly reduced and engine efficiency is increased relative to stoichiometric operation. This paper reports on a mass and energy balance model that has been developed to evaluate the overall system efficiencies of a thermal reformer-heat exchanger system capable of delivering hydrogen to the air intake of a gasoline engine. The mass and energy balance model is utilized to evaluate the conditions where energy losses associated with fuel reformation may be offset by increases in engine efficiencies.

Internal combustion engines are operated under conditions of high exhaust gas recirculation (EGR) to reduce NOx emissions and promote enhanced combustion modes such as HCCI. However, high EGR under certain conditions also promotes nonlinear feedback between cycles, leading to the development of combustion instabilities and cyclic variability. We employ a two-zone phenomenological combustion model to simulate the onset of combustion instabilities under highly dilute conditions and to illustrate the impact of these instabilities on emissions and fuel efficiency. The two-zone in-cylinder combustion model is coupled to a WAVE engine-simulation code through a Simulink interface, allowing rapid simulation of several hundred successive engine cycles with many external engine parametric effects included.

This project team conducted a life-cycle-based environmental evaluation of new, lightweight materials (e.g., titanium, magnesium) used in two concept 3XVs -- i.e., automobiles that are three times more fuel efficient than today's automobiles -- that are being designed and developed in support of the Partnership for a New Generation of Vehicles (PNGV) program. The two concept vehicles studied were the DaimlerChrysler ESX2 and the Ford P2000. Data for this research were drawn from a wide range of sources, including: the two automobile manufacturers; automobile industry reports; government and proprietary databases; past life-cycle assessments; interviews with industry experts; and models.

Plug-in hybrid electric vehicle (PHEV) technologies have the potential for considerable petroleum consumption reductions, possibly at the expense of increased tailpipe emissions due to multiple “cold” start events and improper use of the engine for PHEV specific operation. PHEVs operate predominantly as electric vehicles (EVs) with intermittent assist from the engine during high power demands. As a consequence, the engine can be subjected to multiple cold start events. These cold start events may have a significant impact on the tailpipe emissions due to degraded catalyst performance and starting the engine under less than ideal conditions. On current hybrid electric vehicles (HEVs), the first cold start of the engine dictates whether or not the vehicle will pass federal emissions tests. PHEV operation compounds this problem due to infrequent, multiple engine cold starts.

Fuel cell-powered electric vehicles (FCPEV) require an energy storage device to start up the fuel cells and to store the energy captured during regenerative braking. Low-voltage (12 V) batteries are preferred as the storage device to maintain compatibility with the majority of today's automobile loads. A dc/dc converter is therefore needed to interface the low-voltage batteries with the fuel cell-powered higher-voltage dc bus system (255 V ∼ 425 V), transferring energy in either direction as required. This paper presents a soft-switched, isolated bi-directional dc/dc converter developed at Oak Ridge National Laboratory for FCPEV applications. The converter employs dual half-bridges interconnected with an isolation transformer to minimize the number of switching devices and their associated gate drive requirements. Snubber capacitors including the parasitic capacitance of the switching devices and the transformer leakage inductance are utilized to achieve zero-voltage switching (ZVS).

Of the fuel cells being studied, the proton exchange membrane fuel cell (PEMFC) is viewed as the most promising for transportation. Yet until today, the commercialization of the PEMFC has not been widespread in spite of its large expectation. Poor long term performances or durability, and high production and maintenance costs account for the main reasons. For the final commercialization of fuel cell in transportation field, the durability issue must be addressed, while the costs should be further brought down. In the meantime, health-monitoring and prognosis techniques are of great significance in ensuring the normal operation of the fuel cell and preventing or predicting its likely abrupt and catastrophic failure. In this paper, an analytical formulation of a damage accumulation law for fuel cell is presented.

Thermal conductivity detection has long been used in gas chromatography to detect hydrogen and other diatomic gases in a gas sample. Thermal conductivity instruments that are not coupled to gas chromatographs are useful for detecting hydrogen in binary gas mixtures, but suffer from significant cross-interference from other gas species that are separated when the detector is used with a gas chromatograph. This study reports a method for using a commercially-available thermal conductivity instrument to detect and quantify hydrogen in a diesel exhaust stream. The instrument time response of approximately 40 seconds is sufficient for steady-state applications. Cross-interference from relevant gas species are quantified and discussed. Measurement uncertainty associated with the corrections for the various species is estimated and practical implications for use of the instrument and method are discussed.

An alternative approach is presented for the regression of response data on predictor variables that are not logically or physically separable. The methodology is demonstrated by its application to a data set of heavy-duty diesel emissions. Because of the covariance of fuel properties, it is found advantageous to redefine the predictor variables as vectors, in which the original fuel properties are components, rather than as scalars each involving only a single fuel property. The fuel property vectors are defined in such a way that they are mathematically independent and statistically uncorrelated. The available data set is not considered adequate for the development of a full-fledged emission model. Nevertheless, the data clearly show that only a few basic patterns of fuel-property variation affect emissions and that the number of these patterns is considerably less than the number of variables initially thought to be involved.

In order to achieve proposed fuel economy requirements, engines must make better use of the available fuel energy. Regardless of how efficient the engine is, there will still be a significant fraction of the fuel energy that is rejected in the exhaust and coolant streams. One viable technology for recovering this waste heat is an Organic Rankine Cycle. This cycle heats a working fluid using these heat streams and expands the fluid through a turbine to produce shaft power. The present work was the development of such a system applied to a light duty diesel engine. This lab demonstration was designed to maximize the peak brake thermal efficiency of the engine, and the combined system achieved an efficiency of 45%. The design of the system is discussed, as are the experimental performance results. The system potential at typical operating conditions was evaluated to determine the practicality of installing such a system in a vehicle.

Battery electric vehicles (BEV) in heavy duty (HD) commercial freight transport face challenging technoeconomic barriers to adoption. Specifically, beyond safety and compliance, fleet and operational logistics require both high up-time and parity with diesel system productivity/Total Cost of Ownership (TCO) to enable strong adoption of electrified powertrains. At present, relatively high energy storage prices coupled with the increased weight of BEV systems limit the practicality of HD commercial freight transport to shorter range applications, where smaller batteries will suffice for the mission energy requirements (single operational shift). This paper presents an approach to extend the feasibility of BEV HD trucking for a broad range of applications.

This work explores pathways to achieve diesel-like, high-efficiency combustion with stoichiometric 3-way catalyst compatible spark ignition (SI). A high stroke-to-bore engine design (1.5:1) with cooled exhaust gas recirculation (EGR) and high compression ratio (rc) was used to improve engine efficiency by up to 30% compared with a production turbocharged gasoline direct injection spark ignition engine. To achieve efficiency improvements, engine experiments were coupled with computational fluid dynamics simulations to guide and explain experimental trends between the original engine and the high stroke-to-bore ratio design (1.5:1). The effects of EGR and late intake valve closing (IVC) and fuel characteristics are investigated through their effects on knock mitigation. Direct injection of 91 RON E10 gasoline, 99 RON E0 gasoline, and liquified petroleum gas (i.e., propane/autogas) were evaluated with geometric rc ranging from 13.3:1 to 16.8:1.

The widespread adoption of boosted, downsized SI engines has brought pre-ignition phenomena into greater focus, as the knock events resulting from pre-ignitions can cause significant hardware damage. Much attention has been given to understanding the causes of pre-ignition and identify lubricant or fuel properties and engine design and calibration considerations that impact its frequency. This helps to shift the pre-ignition limit to higher specific loads and allow further downsizing but does not fundamentally eliminate the problem. Real-time detection and mitigation of pre-ignition would thus be desirable to allow safe engine operation in pre-ignition-prone conditions. This study focuses on advancing the time of detection of pre-ignition in an engine cycle where it occurs.

Lean gasoline engines offer greater fuel economy than the common stoichiometric gasoline engine, but the current three way catalyst (TWC) on stoichiometric engines is unable to control nitrogen oxide (NOX) emissions in oxidizing exhaust. For these lean gasoline engines, lean NOX emission control is required to meet existing Tier 2 and upcoming Tier 3 emission regulations set by the U.S. Environmental Protection Agency (EPA). While urea-based selective catalytic reduction (SCR) has proven effective in controlling NOX from diesel engines, the urea storage and delivery components can add significant size and cost. As such, onboard NH3 production via a passive SCR approach is of interest. In a passive SCR system, NH3 is generated over a close-coupled TWC during periodic slightly rich engine operation and subsequently stored on an underfloor SCR catalyst. Upon switching to lean operation, NOX passes through the TWC and is reduced by the stored NH3 on the SCR catalyst.

A commercial three-way catalyst (TWC) was evaluated for ammonia (NH3) generation on a 2.0-liter BMW lean burn gasoline direct injection engine as a component in a passive ammonia selective catalytic reduction (SCR) system. The passive NH3 SCR system is a potential low cost approach for controlling nitrogen oxides (NOX) emissions from lean burn gasoline engines. In this system, NH3 is generated over a close-coupled TWC during periodic slightly rich engine operation and subsequently stored on an underfloor SCR catalyst. Upon switching to lean, NOX passes through the TWC and is reduced by the stored NH3 on the SCR catalyst. NH3 generation was evaluated at different air-fuel equivalence ratios at multiple engine speed and load conditions. Near complete conversion of NOX to NH3 was achieved at λ=0.96 for nearly all conditions studied. At the λ=0.96 condition, HC emissions were relatively minimal, but CO emissions were significant.

A hybrid LNT+SCR system is used to control NOx from a light-duty diesel engine with in-cylinder regeneration controls. A diesel oxidation catalyst and diesel particulate filter are upstream of the LNT and SCR catalysts. Ultraviolet (UV) adsorption spectroscopy performed directly in the exhaust path downstream of the LNT and SCR catalysts is used to characterize NH3 production and utilization in the system. Extractive exhaust samples are analyzed with FTIR and magnetic sector mass spectrometry (H2) as well. Furthermore, standard gas analyzers are used to complete the characterization of exhaust chemistry. NH3 formation increases strongly with extended regeneration (or “over regeneration”) of the LNT, but the portion of NOx reduction occurring over the SCR catalyst is limited by the amount of NH3 produced as well as the amount of NOx available downstream of the LNT. Control of lean-rich cycling parameters enables control of the ratio of NOx reduction between the LNT and SCR catalysts.

A modified Mercedes 1.7-liter, direct-injection diesel engine was operated in both normal and high-efficiency clean combustion (HECC) combustion modes. Four steady-state engine operating points that were previously identified by the Ad-hoc fuels working group were used as test points to allow estimation of the hot-start FTP-75 emissions levels in both normal and HECC combustion modes. The results indicate that operation in HECC modes generally produce reductions in NOX and PM emissions at the expense of CO, NMHC, and H2CO emissions. The FTP emissions estimates indicate that aftertreatment requirements for NOX are reduced, while those for PM may not be impacted. Cycle-average aftertreatment requirements for CO, NMHC, and H2CO may be challenging, especially at the lowest temperature conditions.