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Battery packs used in automotive application experience high-power demands, fast charging, and varied operating conditions, resulting in temperature imbalances that hasten degradation, reduce cycle life, and pose safety risks. The development of proper simulation tools capable of capturing both the cell electrical and thermal response including, predicting the cell’s temperature rise and distribution, is critical to design efficient and reliable battery packs. This paper presents a co-simulation model framework capable of predicting voltage, 2-D heat generation and temperature distribution throughout a cell. To capture the terminal voltage and 2-D heat generation across the cell, the simulation framework employs a high-fidelity electrical model paired with a charge balance model based on the Poisson equation. The 2-D volumetric heat generation provided by the charge balance model is used to predict the temperature distribution across the cell surface using CFD software.