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An overview is given on the state of the art of a new catalytic exhaust gas aftertreatment device for diesel engines. The function of a precious metal based, flow-through type diesel oxidation catalyst is explained. Much attention is paid to the durability of the diesel oxidation catalyst and especially to the influence of poisoning elements on the catalytic activity. Detailed data on the interaction of poisoning elements such as sulfur, zinc and phosphorus with the catalytic active sites are given. Finally it is demonstrated that it is possible to meet the stringent emission standards for diesel passenger cars in Europe with a new catalyst generation over 80.000 km AMA aging.

The California LEV1 II program will be introduced in the year 2003 and requires a further reduction of the exhaust emissions of passenger cars. The cold start emissions represent the main part of the total emissions of the FTP2-Cycle. Cold start emissions can be efficiently reduced by injecting secondary air (SA) in the exhaust port making compliance with the most stringent standards possible. The thermochemical conditions (mixing rate and temperature of secondary air and exhaust gas, exhaust gas composition, etc) prevailing in the exhaust system are described in this paper. This provides knowledge of the conditions for auto ignition of the mixture within the exhaust manifold. The thus established exothermal reaction (exhaust gas post-combustion) results in a shorter time to light-off temperature of the catalyst. The mechanisms of this combustion are studied at different engine idle conditions.

The European Commission has released strict emission regulations for passenger cars in the past decade in order to improve air quality in cities and limit harmful emission exposure to humans. In the near future, even stricter regulations containing more realistic/demanding driving scenarios and covering more exhaust gas components are expected to be released. Passenger cars fueled with gasoline are one contributor to unhealthy air conditions, due to the fact that gasoline engines emit harmful air pollutants. One option to minimize harmful emissions would be to utilize specifically tailored, low emission synthetic fuels or fuel blends in internal combustion engines. Methyl formate and dimethyl carbonate are two promising candidates to replace or substitute gasoline, which in previous studies have proven to significantly decrease harmful pollutants.

Future emission regulations require further development for internal combustion engines operating on gasoline. To comply with such regulations and simultaneously improve fuel efficiency, major development trends are found in reduced displacements, increased compression ratios and turbocharging. To counteract such engines’ increased tendencies to knocking combustion, direct fuel injection systems are necessarily applied. Compared to standard port fuel injection, direct injection systems cause increased particle emissions. State-of-the-art magnet-driven gasoline direct injectors are capable of realizing various injection events of small injected mass per event and short dwell time between one another. Thereby, they facilitate multiple injection strategies, able to overcome the drawbacks of direct injection systems in relation to exhaust emissions. However, the full potential of multiple injection strategies is not yet taken advantage of.

Since the mechanisms leading to cyclic combustion variabilities in direct injection gasoline engines are still poorly understood, advanced computational studies are necessary to be able to predict, analyze and optimize the complete engine process from aerodynamics to mixing, ignition, combustion and heat transfer. In this work the Scale-Adaptive Simulation (SAS) turbulence model is used in combination with a parameterized lagrangian spray model for the purpose of predicting transient in-cylinder cold flow, injection and mixture formation in a gasoline engine. An existing CFD model based on FLUENT v15.0 [1] has been extended with a spray description using the FLUENT Discrete Phase Model (DPM). This article will first discuss the validation of the in-cylinder cold flow model using experimental data measured within an optically accessible engine by High Speed Particle Image Velocimetry (HS-PIV).

Synthetic fuels for internal combustion engines offer CO2-neutral mobility if produced in a closed carbon cycle using renewable energies. C1-based synthetic fuels can offer high knock resistance as well as soot free combustion due to their molecular structure containing oxygen and no direct C-C bonds. Such fuels as, for example, dimethyl carbonate (DMC) and methyl formate (MeFo) have great potential to replace gasoline in spark-ignition (SI) engines. In this study, a mixture of 65% DMC and 35% MeFo (C65F35) was used in a single-cylinder research engine to determine friction losses in the piston group using the floating-liner method. The results were benchmarked against gasoline (G100). Compared to gasoline, the density of C65F35 is almost 40% higher, but its mass-based lower heating value (LHV) is 2.8 times lower. Hence, more fuel must be injected to reach the same engine load as in a conventional gasoline engine, leading to an increased cooling effect.

A novel algorithm-based approach is employed in this publication to calculate multiple direct injection patterns for spark ignition engines. The algorithm is verified by investigating the combustion and emission behavior of a single-cylinder research engine. State-of-the-art standard exhaust gas analyzers, a particle counter and an additional FTIR analyzer enable in-depth investigation of engine exhaust gas composition. With the upcoming worldwide pollutant emission targets, the emission limits will be reduced while the test procedures’ requirements to the engine increase. Special attention to the engine-out emissions must be paid during cold-start, during which the aftertreatment system lacks sufficient pollutant emission conversion efficiency. With advanced injection control, the engine-out emissions can be reduced and exhaust aftertreatment heat-up can be accelerated.

Existing electronic combustion engine control systems only guarantee a desired air-to-fuel-ratio λ in stationary operation. In order to achieve the desired λ also in in-stationary use of the engine, it is necessary to use new-technology-based control systems. Artificial Intelligence provides methods to cope with difficulties like wide operation range, unknown nonlinearities and time delay. We will propose a strategy for control of a Spark Ignition Engine to determine the mass of air inside the combustion chambers with the highest accuracy. Since Neural Networks are universal approximators for multidimensional nonlinear static functions they can be used effectively for identification and compensation purposes of unknown nonlinearities in closed control loops.

Several different possibilities will be described and discussed on the processes of reducing NOx in lean-burn gasoline and diesel engines. In-company studies were conducted on zeolitic catalysts. With lean-burn spark-ignition engines, hydrocarbons in the exhaust gas act as a reducing agent. In stationary conditions at λ = 1.2, NOx conversion rates of approx. 45 % were achieved. With diesel engines, the only promising variant is SCR technology using urea as a reducing agent. The remaining problems are still the low space velocity and the narrow temperature window of the catalyst. The production of reaction products and secondary reactions of urea with other components in the diesel exhaust gas are still unclarified.

A new method for the analysis of the gas flow in an internal combustion engine has been developed. It is based on the interactive coupling between commercially available three (STAR-CD) and one dimensional (PROMO) fluid dynamics codes. With this method the detailed transient flow distribution for any engine component of interest can be calculated taking into account the overall gas dynamic interaction with other engine components. The underlying physics and numerics are outlined. A description of the coupling procedure ensuring proper communication between the two computer codes is given. Also addressed is the averaging procedure adopted at the 3D boundaries, including the influence of the 1D/3D interface placement. A first application of this new method is presented, in which the gas flow in a turbo-charged DI-diesel-engine is simulated.

The objective of this study was to reduce pollutant emissions during cold start conditions in a spark-ignited direct injection engine, by exploring the potential of oxygenated fuels. With their high oxygen content and lack of direct C-C bonds, they effectively reduce particle number (PN) and NOx emissions under normal conditions. Methanol was chosen due to its wide availability. As methanol is toxic to humans and associated with cold-start issues, a second promising synthetic fuel was selected to be benchmarked against gasoline, comprising 65 vol% of dimethyl carbonate and 35 vol% of methyl formate (C65F5). Currently, there is a lack of detailed investigations on the cold start performance for both oxygenated fuels utilizing today’s injector capabilities. Spray measurements were caried out in a constant volume chamber to assess the spray of C65F35. Reduced fuel temperature increased spray-penetration length and compromised fast vaporization.

This paper compares 4 different EGR systems by means of simulation in GT-Power. The demands of optimum massive EGR and fresh air rates were based on experimental results. The experimental data were used to calibrate the model and ROHR, in particular. The main aim was to investigate the influence of pumping work on engine and vehicle fuel consumption (thus CO2 production) in different EGR layouts using optimum VG turbine control. These EGR systems differ in the source of pressure drop between the exhaust and intake pipes. Firstly, the engine settings were optimized under steady operation - BSFC was minimized while taking into account both the required EGR rate and fresh air mass flow. Secondly, transient simulations (NEDC cycle) were carried out - a full engine model was used to obtain detailed information on important parameters. The study shows the necessity to use natural pressure differences or renewable pressure losses if reasonable fuel consumption is to be achieved.

Crank-angle resolved, gas temperatures are determined in the combustion chamber of a Volkswagen (VW) standard-production, port-injected SI engine. During idle, two different methods are applied: (1) a direct spectroscopic emission-absorption technique at a resonance line of potassium, seeded to the air stream to generate sufficient spectral absorptance (‘colouring’ technique), and (2) a more standard, indirect method in which temperatures are derived from pressure recordings using a two-zone thermodynamic model. Combustion temperatures obtained during idle with both the spectroscopic (1) and ‘two-zone’ (2) methods are in good agreement. In addition, the spectroscopic technique is extended to transient operating conditions where the ‘two-zone’ method is not applicable. Combustion temperatures measured during cold-start and abrupt load alteration are in good agreement with former investigations.

The optimization of fuel efficiency and the minimization of the residual gas fraction require individual cylinder control of the amounts of inducted air mass and injected fuel mass. Determination of an individual cylinder air/fuel ratio (AFR) regulator is based on the measured AFR for each cylinder, using 4 proportional UEGO sensors. The innovative character of this study describes a unified and robust individual cylinder AFR estimator, using a single measuring point: a proportional oxygen sensor located in the exhaust manifold. The model used for the estimator is a state model such that the dimension of the state and measurement matrices are unique, whatever the manifold configuration and the sensor position (confluence point or exhaust manifold: unified model), the engine speed (robust model).

The regulations for mobile applications will become stricter in Euro 6 and further emission levels and require the use of active aftertreatment methods for NOX and particulate matter. SCR and LNT have been both used commercially for mobile NOX removal. An alternative system is based on the combination of these two technologies. Developments of catalysts and whole systems as well as final vehicle demonstrations are discussed in this study. The small and full-size catalyst development experiments resulted in PtRh/LNT with optimized noble metal loadings and Cu-SCR catalyst having a high durability and ammonia adsorption capacity. For this study, an aftertreatment system consisting of LNT plus exhaust bypass, passive SCR and engine independent reductant supply by on-board exhaust fuel reforming was developed and investigated. The concept definition considers NOX conversion, CO2 drawback and system complexity.

The spray development, combustion and emissions in a 1.9L optical, four-cylinder, direct-injection diesel engine were investigated by means of pressure analysis, high-speed cinematography, the two-colour method and exhaust gas analysis for various levels of exhaust gas recirculation (EGR), three EGR temperatures (uncontrolled, hot and cold) and three fuels (diesel, n-heptane and a two-component fuel 7D3N). Engine operating conditions included 1000 rpm/idle and 2000 rpm/2bar with EGR-rates ranging from 0 to 70%. Independent of rate, EGR was found to have a very small effect on spray angle and spray tip penetration but the auto-ignition sites seemed to increase in size and number at higher EGR-rates with associated reduction in the flame luminosity and flame temperature, by, say, 100K at 50% EGR.

Beside the main trend technologies such as downsizing, down speeding, external exhaust gas recirculation, and turbocharging in combination with Miller cycles, the optimization of the mechanical efficiency of gasoline engines is an important task in meeting future CO2 emission targets. Friction in the piston assembly is responsible for up to 45% of the total mechanical loss in a gasoline engine. Therefore, optimizing piston assembly friction is a valuable approach in improving the total efficiency of an internal combustion engine. The form honing process enables new specific shapes of the cylinder liner surface. These shapes, such as a conus or bottle neck, help enlarge the operating clearance between the piston assembly and the cylinder liner, which is one of the main factors influencing piston assembly friction.

Meeting current exhaust emission standards requires rapid catalyst light-off. Closed-coupled catalysts are commonly used to reduce light-off time by minimizing exhaust heat loss between the engine and catalyst. However, this exhaust gas system design leads to a coupling of catalyst heating and engine operation. An engine-independent exhaust gas aftertreatment can be realized by combining a burner heated catalyst system (BHC) with an underfloor catalyst located far away from the engine. This paper describes some basic characteristics of such a BHC system and the results of fitting this system into a Volkswagen Touareg where a single catalyst was located about 1.8 m downstream of the engine. Nevertheless, it was possible to reach about 50% of the current European emission standard EU 4 without additional fuel consumption caused by the BHC system.

For substantial reduction of fuel consumption of their vehicle fleet, Volkswagen AG has decided to develop spark-ignition engines with direct fuel injection. To launch this new engine concept with stratified lean operation mode while at the same time meeting the stringent EU IV emission standards, it was necessary to develop a suitable exhaust gas aftertreatment system. This was achieved as part of an intensive co-operation between Volkswagen AG and OMG, formerly dmc2 Degussa Metals Catalysts Cerdec AG. The paper describes the demands for exhaust gas aftertreatment due to lean burn operation. In addition the main development steps of the exhaust gas aftertreatment system for Volkswagen FSI engines and catalyst durability over vehicle lifetime are discussed. Focus is laid on the catalyst system design and coating variations. Volkswagen developed a new closed-loop emission control management system which uses NOx-sensor signals for the first time worldwide.

A uniform flow distribution at converter inlet is one of the fundamental requirements to meet high catalytic efficiency. Commonly used tools for optimization of the inlet flow distribution are flow measurements as well as CFD analysis. This paper puts emphasis on the experimental procedures and results. The interaction of flow measurements and CFD is outlined. The exhaust gas flow is transient, compressible and hot, making in-situ flow measurements very complex. On the other hand, to utilize the advantages of flow testing at steady-state and cold conditions the significance of these results has to be verified first. CFD analysis under different boundary conditions prove that - in a first approach - the flow situation can be regarded as a sequence of successive, steady-state situations. Using the Reynolds analogy a formula for the steady-state, cold test mass flow is derived, taking into account the cylinder displacement and the rated speed.