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An innovative approach to the study of combustion and emission formation in modern diesel engines has been applied to a EURO V diesel engine equipped with an indirect-acting piezo injection system. The model is based on the joint use of a predictive non-stationary 1D spray model, which has recently been presented by Musculus and Kattke, and a diagnostic multizone thermodynamic model developed by the authors. The combustion chamber content has been split into homogeneous zones, to which mass and energy conservation laws have been applied: an unburned gas zone, made up of air, EGR and residual gas, several fuel/unburned gas mixture zones, premixed combustion burned gas zones and diffusive combustion burned gas zones. The 1D spray model enables the mixing process dynamics of the different fuel parcels with the unburned gas to be estimated for each injection pulse; therefore, the equivalent ratio time-history of each mixture zone can be estimated.