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Technical Paper

Catalytic Activity of Nanostructured Ceria-Based Materials Prepared by Different Synthesis Conditions

2017-09-04
2017-24-0145
In this work, several nanostructured ceria-based catalysts were prepared by the hydrothermal technique varying two synthesis parameters (namely, temperature and pH). Then, cerias with different shapes (i.e., cubes, rods, combination of them, other polyhedra) and structural properties were obtained. The prepared materials were tested for the CO oxidation and soot oxidation efficiency. The results have shown that, for the CO oxidation, activities depend on the surface properties of the catalysts. Conversely, for the soot oxidation, the most effective catalysts exhibit better soot-catalyst contact conditions.
Technical Paper

Catalytic Oxidation of Soot and Volatile Organic Compounds over Cu and Fe Doped Manganese Oxides Prepared via Sol-Gel Synthesis

2021-09-05
2021-24-0088
A set of manganese oxide catalysts was synthesized and doped with Cu and/or Fe by means of the citric acid sol-gel preparation method. The samples were studied by means of several characterization techniques: field-emission scanning electron microscopy (FESEM), X-ray powder diffraction (XRD), N2-physisorption at -196 °C, H2 and soot temperature-programmed reduction (H2-TPR, soot-TPR) and X-ray photoelectron spectroscopy (XPS). The catalytic performance of the prepared catalysts was investigated in the oxidation of a probe VOC molecule (propylene) and carbon soot singularly and simultaneously. The catalytic performances were studied as well assuring a content of 5 vol.% of water in the gaseous reactive mix. The investigations evidenced that the best soot catalytic oxidation rates occurred over the Mn2O3 sample, while the copper-doped manganese oxide (i.e. the MnCu15) showed the best performance in the decomposition of propylene.
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