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Studies using a bi-fuelled (autogas/gasoline) Renault Laguna vehicle meeting °the 1996 European exhaust emission legislation has demonstrated that over the European test cycle at 25°C the LPG operated vehicle provides substantial benefits of reduced emissions compared to unleaded reference gasoline. At lower test temperatures (i.e. 5°C) even larger reduction in emissions have been observed. Lower CO (up to 95% at -5°C and 65% at 25°C), HC (90% at -5°C and 40% at 25°C) emissions and lower ozone HC reactivity have been observed and could all offer significant environmental air-quality benefits for LPG. Various autogas mixtures have been tested including 70/30, 30/70 and 49/30/21 (% mass propane / butane / propene). Results show that NOx emissions for this vehicle appear dependent on autogas composition. The two gas mixtures containing only 30% butane gave about 50% more NOx at +25°C than the 70% butane autogas mixture.

The emissions performance of catalytic converters under different conditions of flow distribution was investigated. Computational Fluid Dynamics methods were utilised to model the maldistribution effects of different inlet cones. The effects of maldistribution on ageing, light-off and conversion were investigated using steady state tests on an engine bench. Emission testing was also conducted on a vehicle throughout ECE and EUDC test cycles. Maldistribution was found to have a significant effect on the efficiency of the catalyst during the early stages of the ECE cycle for both fresh and aged catalysts. The effects were less significant over later stages of the ECE cycle and throughout the EUDC except NOx where maldistribution did have an effect on the conversion at higher flow rates during the later stages of the test.

This presented paper deals with NOx trap sulphur poisoning and its regeneration. Sulphur poisoning has been studied with different SO2 gas concentrations under laboratory and engine test bench conditions. The sulphur poisoning studies have shown that the different NOx-traps available in the market have different behaviours toward SO2 poisoning and are all very sensitive to it. The results outline a non linear relationship of the NOx trap sulphur poisoning as a function of SO2 concentration. For instance, engine bench tests show that with a 50 and a 110ppm sulphur containing gasoline, a decrease of 50% in the NOx-trap storage capacity is respectively observed after 20 and 15 hours. With a gasoline containing 20ppm of sulphur, the same deactivation level is observed after 90 hours.

NOx adsorbers are very sensitive to sulfur poisoning and future fuel standards are unlikely to be sufficient to prevent the system from requiring periodic desulfation procedures. The purpose of this paper is to present the effects of low fuel sulfur content such as 50 ppm and 10 ppm on the NOx adsorber efficiency for a diesel application. Through this study, the influence of the substrate cell geometry has also been assessed. The use of a 10 ppm sulfur fuel is not enough to maintain, at a high level, the NOx adsorber performance during a 40,000 km aging test. The desulfation criterion (efficiency loss of 30%) is reached after the first 16,000 km. However, the desulfation operation is not enough to recover the initial catalyst performance and the poisoning velocity increases as the catalyst ages. The hexagonal cell substrate catalyst is less sensitive to sulfur poisoning than a square cell substrate catalyst so that its desulfation frequency is much lower.

No efficient catalyst presently exists for deNOx in lean burn conditions. Furthermore, actual catalysts generally deactivate during reaction. A cylindrical DBD non-thermal plasma reactor was coupled with a stable three-function catalyst in order to verify the nature of the effect of the plasma on the catalytic process. A mixture of NO/O2/C3H6 in N2 was used as a lean model exhaust. The plasma was found to perform two of the three functions: NO oxidation to NO2 and propene activation through the partial oxidation of the hydrocarbon to aldehyde or alcohol. A complete catalyst containing the first two previous functions and the associative chemisorption of NO (third function) was used, as well as a simplified catalyst containing only the third function. Results suggest an advantageous plasma-catalyst coupling effect on NOx remediation in accordance with the proposed catalytic model.

Among the existing concepts that help to improve the efficiency of spark-ignition engines at part load, Controlled Auto-Ignition™ (CAI™) is an effective way to lower both fuel consumption and pollutant emissions. This combustion concept is based on the auto-ignition of an air-fuel-mixture highly diluted with hot burnt gases to achieve high indicated efficiency and low pollutant emissions through low temperature combustion. To minimize the costs of conversion of a standard spark-ignition engine into a CAI engine, the present study is restricted to a Port Fuel Injection engine with a cam-profile switching system and a cam phaser on both intake and exhaust sides. In a 4-stroke engine, a large amount of burnt gases can be trapped in the cylinder via early closure of the exhaust valves. This so-called Negative Valve Overlap (NVO) strategy has a key parameter to control the amount of trapped burnt gases and consequently the combustion: the exhaust valve-lift profile.

This paper presents an after-treatment architecture combining a close coupled NOx trap and an under floor NOx trap. Instead of simply increasing the volume of the catalyst, we propose to broaden the active temperature window by splitting the LNT along the exhaust line. In order to design this architecture, a complete 1D model of NOx trap has been developed. Validated with respect to experimental data, this model has been useful to define the two volumes of LNT, making significant savings on the test bench exploitation. However, one of the main difficulties to operate the proposed architecture is the NOx purge and sulfur poisoning management. In order to optimize the NOx and sulfur purge launches, we have developed a control strategy based on an embedded reduced LNT model. These strategies have been validated on different driving cycles, by the means of simulation and of vehicle tests using rapid prototyping tools.