Search Results

Urea-selective catalytic reduction (SCR) catalysts are the leading aftertreatment technology for diesel engines, but there are major challenges associated with meeting future NOx emission standards, especially under transient drive cycle conditions that include large swings in exhaust temperatures. Here we present a simplified, transient, one-dimensional integral model of NOx reduction by NH₃ on a commercial small-pore Cu-zeolite urea-SCR catalyst for which detailed kinetic parameters have not been published. The model was developed and validated using data acquired from bench reactor experiments on a monolith core, following a transient SCR reactor protocol. The protocol incorporates NH₃ storage, NH₃ oxidation, NO oxidation and three global SCR reactions under isothermal conditions, at three space velocities and at three NH₃/NOx ratios.

The Magnesium Front End Research and Development (MFERD) project under the sponsorship of Canada, China, and USA aims to develop key technologies and a knowledge base for increased use of magnesium in automobiles. The primary goal of this life cycle assessment (LCA) study is to compare the energy and potential environmental impacts of advanced magnesium based front end parts of a North American-built 2007 GM-Cadillac CTS using the current steel structure as a baseline. An aluminium front end is also considered as an alternate light structure scenario. A “cradle-to-grave” LCA is conducted by including primary material production, semi-fabrication production, autoparts manufacturing and assembly, transportation, use phase, and end-of-life processing of autoparts. This LCA study was done in compliance with international standards ISO 14040:2006 [1] and ISO 14044:2006 [2].

While gasoline surrogate development has progressed in the areas of more complex surrogate mixtures and in kinetic modeling tools and mechanism development, it is generally recognized that further development is still needed. This paper represents a small step in supporting this development by providing comparisons between experimental engine data and surrogate-based kinetic models. In our case, the HCCI engine data comes from a port-injected, single-cylinder research engine with intake-air heating for combustion phasing control. Timing sweeps were run at constant fuel rate for three market gasolines and five surrogate mixtures. Modeling was done using the CHEMKIN software with a gasoline mechanism set containing 1440 species and 6572 reactions. Five pure compounds were selected for the surrogate blends and include iso-octane, n-heptane, toluene, methylcyclohexane, and 1-hexene.

One scenario for reducing engine out NOx in a spark ignition engine is to introduce small amounts of supplemental hydrogen to the combustion process. The supplemental hydrogen enables a gasoline engine to run lean where NOx emissions are significantly reduced and engine efficiency is increased relative to stoichiometric operation. This paper reports on a mass and energy balance model that has been developed to evaluate the overall system efficiencies of a thermal reformer-heat exchanger system capable of delivering hydrogen to the air intake of a gasoline engine. The mass and energy balance model is utilized to evaluate the conditions where energy losses associated with fuel reformation may be offset by increases in engine efficiencies.

Internal combustion engines are operated under conditions of high exhaust gas recirculation (EGR) to reduce NOx emissions and promote enhanced combustion modes such as HCCI. However, high EGR under certain conditions also promotes nonlinear feedback between cycles, leading to the development of combustion instabilities and cyclic variability. We employ a two-zone phenomenological combustion model to simulate the onset of combustion instabilities under highly dilute conditions and to illustrate the impact of these instabilities on emissions and fuel efficiency. The two-zone in-cylinder combustion model is coupled to a WAVE engine-simulation code through a Simulink interface, allowing rapid simulation of several hundred successive engine cycles with many external engine parametric effects included.

This project team conducted a life-cycle-based environmental evaluation of new, lightweight materials (e.g., titanium, magnesium) used in two concept 3XVs -- i.e., automobiles that are three times more fuel efficient than today's automobiles -- that are being designed and developed in support of the Partnership for a New Generation of Vehicles (PNGV) program. The two concept vehicles studied were the DaimlerChrysler ESX2 and the Ford P2000. Data for this research were drawn from a wide range of sources, including: the two automobile manufacturers; automobile industry reports; government and proprietary databases; past life-cycle assessments; interviews with industry experts; and models.

Asymmetric particulate filters (PF), where the inlet channel is wider than the outlet channel, are commonly used because of their greater capacity for ash. Somewhat surprisingly, very few models for asymmetric PFs have been published and none of these gives a correct/detailed description of the geometry. For example, octahedral channels may be treated as if they were square or the tapering walls between the inlet and outlet channels treated as if they were rectangular in cross section. Alternatively, the equations may be presented in generic form in terms of channel cross-sectional areas and perimeters, but without giving any indication of how to calculate these. This paper aims to address these deficiencies with a model that correctly describes the geometry of square and octo-square asymmetric PFs. Expressions for the solid fraction of the PF (which affects thermal mass) and channel cross section and perimeter (both when clean and soot/ash loaded) are presented.

This paper presents a new 0D phenomenological approach to predict the combustion process in diesel engines operated under various running conditions. The aim of this work is to develop a physical approach in order to improve the prediction of in-cylinder pressure and heat release. The main contribution of this study is the modeling of the premixed part of the diesel combustion with a further extension of the model for multi-injection strategies. In phenomenological diesel combustion models, the premixed combustion phase is usually modeled by the propagation of a turbulent flame front. However, experimental studies have shown that this phase of diesel combustion is actually a rapid combustion of part of the fuel injected and mixed with the surrounding gas. This mixture burns quasi instantaneously when favorable thermodynamic conditions are locally reached. A chemical process then controls this combustion.

Reduction of nitrogen oxides in Diesel exhaust gas is a challenging task. This paper reports results from an extensive study using Pt-based catalysts involving synthetic gas activity testing (SCAT), engine bench testing and tests on passenger cars. Preliminary SCAT work highlighted the importance of Pt-dispersion, and both SCAT and bench engine testing yielded comparable NOx conversions under steady state conditions at high HC:NOx ratios. On passenger cars in the European cycle without secondary fuel injection NOx conversion was lower than obtained in the steady state tests. Better conversion was obtained in the FTP cycle, where secondary injection was employed. Higher HC:NOx, ratios and more favourable temperature conditions which were present in the exhaust contributed to this higher conversion.

Biofuels are a renewable energy source. When used as extenders for transportation fuels, biofuels contribute to the global reduction of Green House Gas and CO2 emissions from the transport sector and to security and independence of energy supply. On a “Well to Wheel” basis they are much more CO2 efficient than conventional fossil fuels. All vehicles currently in circulation in Europe are capable of using 5 % biodiesel. The introduction of higher percentages biodiesel needs new specific standards and vehicle tests validation. The development of vehicles compatible with 30% biodiesel blends in diesel fuel includes the validation of each part of both engine and fuel vehicle systems to guarantee normal operation for the entire life of the vehicle.

A systems-level modeling framework developed to estimate the life cycle cost of medium- and heavy-duty trucks is discussed in this paper. Costs are estimated at a resolution of five major subsystems and 30+ subsystems, each representing a specific manufacturing technology. Interrelationships among various subsystems affecting cost are accounted for. Results of a specific Class 8 truck are finally discussed to demonstrate the modeling framework's capability, including the analysis of cost-effectiveness of some of the competing alternative system design options being considered by the industry today.

Thermal conductivity detection has long been used in gas chromatography to detect hydrogen and other diatomic gases in a gas sample. Thermal conductivity instruments that are not coupled to gas chromatographs are useful for detecting hydrogen in binary gas mixtures, but suffer from significant cross-interference from other gas species that are separated when the detector is used with a gas chromatograph. This study reports a method for using a commercially-available thermal conductivity instrument to detect and quantify hydrogen in a diesel exhaust stream. The instrument time response of approximately 40 seconds is sufficient for steady-state applications. Cross-interference from relevant gas species are quantified and discussed. Measurement uncertainty associated with the corrections for the various species is estimated and practical implications for use of the instrument and method are discussed.

Progress in Diesel spray modelling highly depends on a better knowledge of the instantaneous injection velocity and of the hydraulic section at the exit of each injection hole. Additionally a better identification of the mechanisms which cause fragmentation is needed. This necessitates to begin with a precise computation of the two-phase flow which arises due to the presence of cavitation within the injectors. For that aim, a VOF type interface tracking method has been developed and improved (Segment Lagrangian VOF method) which allows to describe numerically the onset and development of cavitation within Diesel injectors. Furthermore, experiments have been performed for validation purpose, on transparent one-hole injectors for high pressure injection conditions. Two different entrance geometries (straight and rounded) and various upstream and downstream pressure levels have been considered.

An alternative approach is presented for the regression of response data on predictor variables that are not logically or physically separable. The methodology is demonstrated by its application to a data set of heavy-duty diesel emissions. Because of the covariance of fuel properties, it is found advantageous to redefine the predictor variables as vectors, in which the original fuel properties are components, rather than as scalars each involving only a single fuel property. The fuel property vectors are defined in such a way that they are mathematically independent and statistically uncorrelated. The available data set is not considered adequate for the development of a full-fledged emission model. Nevertheless, the data clearly show that only a few basic patterns of fuel-property variation affect emissions and that the number of these patterns is considerably less than the number of variables initially thought to be involved.

This work explores pathways to achieve diesel-like, high-efficiency combustion with stoichiometric 3-way catalyst compatible spark ignition (SI). A high stroke-to-bore engine design (1.5:1) with cooled exhaust gas recirculation (EGR) and high compression ratio (rc) was used to improve engine efficiency by up to 30% compared with a production turbocharged gasoline direct injection spark ignition engine. To achieve efficiency improvements, engine experiments were coupled with computational fluid dynamics simulations to guide and explain experimental trends between the original engine and the high stroke-to-bore ratio design (1.5:1). The effects of EGR and late intake valve closing (IVC) and fuel characteristics are investigated through their effects on knock mitigation. Direct injection of 91 RON E10 gasoline, 99 RON E0 gasoline, and liquified petroleum gas (i.e., propane/autogas) were evaluated with geometric rc ranging from 13.3:1 to 16.8:1.

To reduce greenhouse gas emissions such as CO2, automakers are actively pursuing alternative propulsion systems. Improvements to current engine technology are being investigated along with new power plant technologies. Fuel Cell Vehicles offer an exciting option by producing electric power through a reaction that combines hydrogen and oxygen to make water. However, hydrogen storage onboard vehicles and construction of an expensive hydrogen distribution and fueling infrastructure remain as challenges today. In addition, greenhouse gas emissions from the production of hydrogen must be considered since most hydrogen is currently produced from non-renewable sources. While these issues are being worked on, Renault has chosen to pursue a fuel cell vehicle with a fuel processor that converts gasoline and other liquid fuels to hydrogen onboard the vehicle.

Enhancements in the thermal stability of three-way catalysts have been achieved by: 1) developing improved methods for the incorporation of ceria into catalyst formulations and 2) identifying a proprietary stabilizer which reduces the rate of ceria sintering at high temperature. Improvements in thermal stability are demonstrated by comparing the FTP and engine dynamometer performance of new formulations with a standard formulation after aging on several high temperature engine dynamometer cycles.

The paper presents the VALEO and RENAULT approach to study odor problems for passengers compartment. The first part describes the method chosen to form a panel, and the second part presents a vehicle application.

It has long been recognized that the key to achieving stringent emission standards such as ULEV is the control of cold-start hydrocarbons. This paper describes a new approach for achieving excellent cold-start hydrocarbon control. The most important component in the system is a catalyst that is highly active at ambient temperature for the exothermic CO oxidation reaction in an exhaust stream under net lean conditions. This catalyst has positive order kinetics with respect to CO for CO oxidation. Thus, as the concentration of CO in the exhaust is increased, the rate of this reaction is increased, resulting in a faster temperature rise over the catalyst.

Lean gasoline engines offer greater fuel economy than the common stoichiometric gasoline engine, but the current three way catalyst (TWC) on stoichiometric engines is unable to control nitrogen oxide (NOX) emissions in oxidizing exhaust. For these lean gasoline engines, lean NOX emission control is required to meet existing Tier 2 and upcoming Tier 3 emission regulations set by the U.S. Environmental Protection Agency (EPA). While urea-based selective catalytic reduction (SCR) has proven effective in controlling NOX from diesel engines, the urea storage and delivery components can add significant size and cost. As such, onboard NH3 production via a passive SCR approach is of interest. In a passive SCR system, NH3 is generated over a close-coupled TWC during periodic slightly rich engine operation and subsequently stored on an underfloor SCR catalyst. Upon switching to lean operation, NOX passes through the TWC and is reduced by the stored NH3 on the SCR catalyst.