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This paper reports on DaimlerChrysler's participation in the Ad Hoc Diesel Fuels Test Program. This program was initiated by the U.S. Department of Energy and included major U.S. auto makers, major U.S. oil companies, and the Department of Energy. The purpose of this program was to identify diesel fuels and fuel properties that could facilitate the successful use of compression ignition engines in passenger cars and light-duty trucks in the United States at Tier 2 and LEV II tailpipe emissions standards. This portion of the program focused on minimizing engine-out particulates and NOx by using selected fuels, (not a matrix of fuel properties,) in steady state dynamometer tests on a modern, direct injection, common rail diesel engine.

The Fischer-Tropsch (FT) process can be used to synthesize diesel fuels from a variety of energy sources, including coal, natural gas and biomass. Diesel fuels produced from the FT process are essentially sulfur-free, have very low aromatic content, and have excellent ignition characteristics. Because of these favorable attributes, FT diesel fuels may offer environmental benefits over transportation fuels derived from crude oil. Previous tests have shown that FT diesel fuel can be used in unmodified engines and have been shown to lower regulated emissions. Whereas exhaust emissions reductions from these previous studies have been impressive, this paper demonstrates that far greater exhaust emissions reductions are possible if the diesel engine is optimized to exploit the properties of the FT fuels. A Power Stroke 7.3 liter turbocharged diesel engine has been modified for use with FT diesel.

With the adoption of the California Low-Emission Vehicle Regulations and the associated lower emission standards such as LEV (Low-Emission Vehicle in 1990), ULEV (Ultra-Low-Emission Vehicle), and LEV II (1998 with SULEV-Super Ultra Low Emission Vehicle), concerns were raised by emissions researchers over the accuracy and reliability of collecting and analyzing emissions measurements at such low levels. The primary concerns were water condensation, optimizing dilution ratios, and elimination of background contamination. These concerns prompted a multi-year research program looking at several new sampling techniques. This paper will describe the cooperative research conducted into one of these new technologies, namely the Bag Mini-Diluter (BMD) and Direct Vehicle Exhaust (DVE) Volume system.

Vehicle evaluations and model calculations were conducted on a vacuum-insulated catalytic converter (VICC). This converter uses vacuum and a eutectic PCM (phase-change material) to prolong the temperature cool-down time and hence, may keep the converter above catalyst light-off between starts. Tailpipe emissions from a 1992 Tier 0 5.2L van were evaluated after 3hr, 12hr, and 24hr soak periods. After a 12hr soak the HC emissions were reduced by about 55% over the baseline HC emissions; after a 24hr soak the device did not exhibit any benefit in light-off compared to a conventional converter. Cool-down characteristics of this VICC indicated that the catalyst mid-bed temperature was about 180°C after 24hrs. Model calculations of the temperature warm-up were conducted on a VICC converter. Different warm-up profiles within the converter were predicted depending on the initial temperature of the device.

In 2007 emissions regulations for on-road light to heavy duty Diesel trucks will require the use of Diesel Particulate Filters (DPFs). The uniform distribution of soot on the DPF is critical for adequate long term performance of these DPFs. This is especially true when cordierite is used instead of silicon carbide for the DPF substrate, due to the reduced thermal conductivity and reduced peak temperature capability of cordierite. In addition to flow uniformity, an inverted flow pattern where more of the flow is forced radially outward on the substrate face could be beneficial to counteract thermal losses in the converter. This paper describes a dispersion device that can improve flow geometry with a low backpressure penalty. Computational fluid dynamics (CFD) results and experimental data are presented for this device. Additionally, cone design options are explored, and CFD analysis results of the cone design are presented.

As SULEV emission regulations approach, the bag mini-diluter (BMD) technology is gaining acceptance as a replacement for the existing constant volume sampler (CVS) for SULEV exhaust emission measurement and certification. The heart of the BMD system is the direct vehicle exhaust (DVE) flow measurement system. Due to the transient nature of vehicle exhaust during a standard FTP emission test cycle, the DVE must be capable of rapid and accurate response in order to track these varying exhaust flow rates. The DVE must also be robust enough to accurately measure flow rate despite variations in exhaust gas composition, pulsation effects, and rapid changes in both exhaust temperature and pressure. One of the primary DVE systems used on BMDs is the E-Flow, an ultrasonic flow meter manufactured by Flow Technologies, Inc.

It is becoming increasingly difficult to obtain good repeatability from running lab vehicle correlation testing, since vehicle variability is so significant at the Low ULEV and SULEV emissions levels. These new emission standards are becoming so stringent that it makes it very difficult to distinguish whether a problem is a result of vehicle variability, test cell sampling or the analytical system. A vehicle exhaust emission simulator (VEES) developed by Horiba, can simulate emissions from low emitting gasoline vehicles by producing tailpipe flow rates containing emissions constituents ( HC, CH4, CO, NOx, CO2 ) injected at the tailpipe flow stream via mass flow controllers.