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In modern compression ignition engines, the dense liquid fuel is directly injected into high pressure and temperature atmosphere, so the spray transitions from subcritical to supercritical conditions. To gain better control of the spray-combustion heat release process, it is important to have a physically accurate description of the spray development process. This work explored the effect of real-fluid thermodynamics in the computational prediction of multiphase flow for two non-ideal situations: the cryogenic nitrogen and non-cryogenic n-dodecane and ammonia sprays. Three real-fluid equations of state (EoS) such as the Soave-Redlich-Kwong (SRK), Peng-Robinson (PR), and Redlich-Kwong-Peng-Robinson (RKPR) coupled with the real-fluid Chung transport model were implemented in OpenFoam to predict the real-fluid thermodynamic properties. Validations against the CoolProp database were conducted.