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As SI engines strive for higher efficiency they are more likely to encounter knock and fuel anti-knock quality, which is currently measured by RON and MON, becomes more important. However, the RON and MON scales are based on primary reference fuels (PRF) - mixtures of iso-octane and n-heptane - whose autoignition chemistry is significantly different from that of practical fuels. Hence RON or MON alone can truly characterize a gasoline for its knock behavior only at their respective test conditions. The same gasoline will match different PRF fuels at different operating conditions. The true anti-knock quality of a fuel is given by the octane index, OI = RON −KS where S = RON − MON, is the sensitivity. K depends on the pressure and temperature evolution in the unburned gas during the engine cycle and hence is different at different operating conditions and is negative in modern engines.

More stringent emissions standards along with higher fuel economy demands have obliged auto makers to develop technical solutions that exploit synergistic features from gasoline and diesel engines. To minimize NOx and soot trade-off, diesel powertrain has been developed to adopt increasingly complex and expensive technology such as extremely high pressure fuel injection systems, low pressure EGR, and variable valve timing. These attempts are associated with promoting Partially Premixed Charge Compression Ignition (PPC-CI) combustion via increasing mixing time and ignition delay. Alternatively, PPC-CI combustion can be achieved easier by using fuels with higher resistance to auto-ignition than conventional diesel fuel. Previous work has demonstrated the possibility of reducing the cost of future diesel after-treatment systems by using gasoline-like fuels.

Recent research [21] has shown that the compression ignition concept where very low cetane fuels (RON between 70 and 85) are run in compression ignition (CI) mode has several advantages. The engine will be at least as efficient and clean as the current diesel engines but will have a less complicated after-treatment system. The optimum fuel will be less processed and therefore simpler to make compared to current gasoline or diesel fuels. Naphtha, which is a product of the initial distillation of petroleum, is one such fuel. It provides a path to mitigate the global demand imbalance between heavier and lighter fuels that is otherwise projected. Since naphtha requires much less processing in the refinery than either gasoline or diesel [23], there is an additional benefit in terms of well-to-wheel CO2 emissions and overall energy consumed. Partially premixed charge compression ignition combustion with such a low cetane fuel has usually been investigated with a diesel engine base.

Extensive tests have been carried out in a single-cylinder Direct Injection Spark Ignition (DISI) engine using up to fifteen different fuels at inlet pressure of up to 3.4 bar abs. to study fuel effects as well as inlet pressure effects on knock. In addition fuel effects on particulate emissions at part-throttle were measured. Fuel anti-knock quality does not correlate with MON and is best described by the Octane Index, OI = RON-KS where S = RON -MON is the sensitivity of the fuel and K is a constant depending on the engine pressure/temperature regime. The RON of the fuels considered was in the range between 95 and 105 and the sensitivity between 8 and 13. K is negative at all the conditions tested, i.e., for a given RON, a higher sensitivity fuel has better anti-knock quality. K decreases with increasing intake pressure and more generally, decreases as Tcomp₁₅, the temperature of the unburned gas at a pressure of 15 bar decreases.