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Journal Article

A Comparative Study of Lithium-Ion Cathode Chemistry Correlations with Emissions Initiated by Nail Penetration Abuse in the Presence of an Immersive Coolant

2022-03-29
2022-01-0707
Internal short-circuit in cells/batteries is a phenomenon where there is direct electrical contact between the positive and negative electrodes leading to thermal runaway. The nail penetration tests were used to simulate an internal short circuit within the battery, where a conductive nail was used to pierce the battery cell separator membrane which provided direct electrical contact between the positive and negative electrodes. The batteries tested during this work were common batteries used in existing automotive applications, and they included a nickel manganese cobalt (NMC) battery from a Chevrolet Bolt, a lithium manganese oxide (LMO) battery from a Chevrolet Volt, and a lithium iron phosphate (LFP) battery in a hybrid transit bus. The battery abuse and emissions tests were designed to intentionally drive the three different battery chemistries into thermal runaway while measuring battery temperatures, battery voltages and gaseous emissions.
Journal Article

A Comparative Study of Lithium-Ion Cathode Chemistry Correlations with Emissions Initiated by Nail Penetration Abuse in the Presence of an Immersive Coolant

2022-03-29
2022-01-0715
Internal short-circuit in cells/batteries is a phenomenon where there is direct electrical contact between the positive and negative electrodes leading to thermal runaway. The nail penetration tests were used to simulate an internal short circuit within the battery, where a conductive nail was used to pierce the battery cell separator membrane which provided direct electrical contact between the positive and negative electrodes. The batteries tested during this work were common batteries used in existing automotive applications, and they included a nickel manganese cobalt (NMC) battery from a Chevrolet Bolt, a lithium manganese oxide (LMO) battery from a Chevrolet Volt, and a lithium iron phosphate (LFP) battery in a hybrid transit bus. The battery abuse and emissions tests were designed to intentionally drive the three different battery chemistries into thermal runaway while measuring battery temperatures, battery voltages and gaseous emissions.
Technical Paper

A Comprehensive Numerical Approach to Predict Thermal Runaway in Li-Ion Battery Packs

2021-04-06
2021-01-0748
With the increasing level of electrification of on-road, off-road and stationary applications, use of larger lithium-ion battery packs has become essential. These packs require large capital investments on the order of millions of dollars and pose a significant risk of self-annihilation without rigorous safety evaluation and management. Testing these larger battery packs to validate design changes can be cost prohibitive. A reliable numerical simulation tool to predict battery thermal runaway under various abuse scenarios is essential to engineer safety into the battery pack design stage. A comprehensive testing & simulation workflow has been established to calibrate and validate the numerical modeling approach with the test data for each of the individual sub model - electrochemical, internal short circuit and thermal abuse model. A four-equation thermal abuse model was built and validated for lithium-ion 21700 form factor cylindrical cells using NCA cathodes.
Journal Article

A One-Way Coupled Modeling Method to Simulate Battery Pack Thermal Runaway Initiated by an External Impact

2023-04-11
2023-01-0593
There is an ongoing proliferation of electric and electrified vehicles as manufacturers seek to reduce their carbon footprint and meet the carbon reduction targets mandated by governments around the world. An ongoing challenge in electric vehicle design is the efficient and safe design of battery packs. There are significant safety challenges for lithium battery packs relating to thermal runaway, which can be initiated through overheating and internal short from defects or external damage. This work proposes a robust method to couple the mechanical damage in a battery module calculated from a dynamic model with a thermal model of the battery that includes heating from electro-chemical sources as well as Arrhenius reactions from the battery cells. The authors identify the main sources of thermal runaway initiation and propagation in an impact scenario simulating a vehicle collision. The modeling approach was developed and validated using test data.
Technical Paper

A Second Generation Expert System for Diagnosis and Repair of Mechanical and Electrical Devices

1986-03-01
860337
Existing expert systems have a high percentage agreement with human experts in a particular field in many situations. However, in many ways their overall behavior is not like that of a human expert. These areas include the inability to give flexible, functional explanations of their reasoning processes and the failure to degrade gracefully when dealing with problems at the periphery of their knowledge. These two important shortcomings can be improved when the right knowledge is available to the system. This paper presents an expert system design, called the Integrated Diagnostic Model (IDM), that integrates two sources of knowledge: a shallow, empirically-oriented, experiential knowledge base and a deep, functionally-oriented, physical knowledge base. To demonstrate the IDM's usefulness in the problem area of diagnosis and repair of electrical and mechanical devices, two implementations and our experience with them is described.
Technical Paper

Accessory Electrification in Class 8 Tractors

2006-04-03
2006-01-0215
Fuel costs to operate large trucks have risen substantially in the last few years and, based on petroleum supply/demand curves, that trend is expected to continue for the foreseeable future. Non-propulsion or parasitic loads in a large truck account for a significant percentage of overall engine load, leading to reductions in overall vehicle fuel economy. Electrification of parasitic loads offers a way of minimizing non-propulsion engine loads, using the full motive force of the engine for propulsion and maximizing vehicle fuel economy. This paper covers the integration and testing of electrified accessories, powered by a fuel cell auxiliary power unit (APU) in a Class 8 tractor. It is a continuation of the efforts initially published in SAE paper 2005-01-0016.
Technical Paper

Advanced Nondestructive Testing Methods for Bearing Inspection

1972-02-01
720172
The principles of the magnetic-perturbation method of flaw detection and the Barkhausen noise residual stress measurement method are briefly reviewed. It is suggested that they provide very powerful tools for assuring improved ball bearing performance. The methods are applied for the evaluation of ball bearing races. Typical experimental results are presented along with metallurgical sectioning correlation.
Technical Paper

An Engine Start/Stop System for Improved Fuel Economy

2007-04-16
2007-01-1777
During city traffic or heavily congested roads, a vehicle can consume a substantial amount of fuel idling when the vehicle is stopped. Due to regulation enforcement, auto manufacturers are developing systems to increase the mileage and reduce emissions. Turning off the engine at traffic lights and regenerative braking systems are simple ways to reduce emissions and fuel consumption. In order to develop strong manufacturer and consumer interest, this type of operation needs to be automated such that the stop/start functionality requires no driver interaction and takes place without the intervention of the vehicle operator. Valeo Electrical Systems has developed such a system that replaces the OEM engine alternator with a starter/alternator driven by a standard multi-ribbed V belt. To avoid a break and dual voltage network, this system is based on a 12V electrical system using an Enhanced Power Supply.
Technical Paper

An Investigation of Sample Bag Hydrocarbon Emissions and Carbon Dioxide Permeation Properties

2004-03-08
2004-01-0593
The equipment for collecting dilute exhaust samples involves the use of bag materials (i.e., Tedlar®) that emit hydrocarbons that contaminate samples. This study identifies a list of materials and treatments to produce bags that reduce contamination. Based on the average emission rates, baked Tedlar®, Capran® treated with alumina deposition, supercritical CO2 extracted Kynar® and supercritical CO2 extracted Teflon NXT are capable of achieving the target hydrocarbon emission rate of less than 15 ppbC per 30 minutes. CO2 permeation tests were also performed. Tedlar, Capran, Kynar and Teflon NXT showed comparable average permeation rates. Based on the criteria of HC emission performance, changes in measured CO2 concentration, ease of sealing, and ease of surface treatment, none of the four materials could be distinguished from one another.
Technical Paper

Analyses of the Integration of Carbon Dioxide Removal Assembly, Compressor, Accumulator and Sabatier Carbon Dioxide Reduction Assembly

2004-07-19
2004-01-2496
An analysis model has been developed for analyzing/optimizing the integration of a carbon dioxide removal assembly (CDRA), CO2 compressor, accumulator, and Sabatier CO2 reduction assembly. The integrated model can be used in optimizing compressor sizes, compressor operation logic, water generation from Sabatier, utilization of CO2 from crew metabolic output, and utilization of H2 from oxygen generation assembly. Tests to validate CO2 desorption, recovery, and compression had been conducted in 2002-2003 using CDRA/Simulation compressor set-up at NASA Marshall Space Flight Center (MSFC). An analysis of test data has validated CO2 desorption rate profile, CO2 compressor performance, CO2 recovery and CO2 vacuum vent in the CDRA model. Analysis / optimization of the compressor size and the compressor operation logic for an integrated closed air revitalization system is currently being conducted
Technical Paper

Analysis For A Parallel Four-Wheel Propane Electric Hybrid Vehicle

1999-08-17
1999-01-2907
This paper analyzes the hybridization of a conventionally powered light duty front wheel drive pick up truck by adding an electric motor driven rear axle. Also studied are the effects of using propane fuel instead of gasoline. This hybrid powertrain configuration can be described as a parallel hybrid electric vehicle. Supervisory power management control has been developed to best determine the proportion of load to be provided by the engine and/or electric motor. To perform these analyses, a simulation tool (computer model of the powertrain components) was developed using MATLAB/SIMULINK'. The models account for the thermal and mechanical efficiencies of the components and are designed to develop control strategies for meeting road loads with improved fuel economy and reduced emissions. Results of this study have shown that fuel economy can be improved and emissions reduced using commercially available components (motor, rear axle, and lead acid batteries).
Technical Paper

Analysis of a Hybrid Multi-Mode Hydromechanical Transmission

2007-04-16
2007-01-1455
A multi-mode hybrid hydromechanical transmission (HMT) with infinite variability is designed to meet the power transmission needs of medium duty on- and off-road vehicles. A hydraulic pump-motor assembly provides output speed and torque variability in an input coupled split power configuration. Dual planetary arrangements with two multiplate clutches allow multi-mode ratio change and combination of power from the mechanical and variable branches of the power path. Hydraulic accumulators offer hydraulic power assist during launch conditions and storage of reclaimed energy during braking events. Transmission kinematic, force and power flow analyses will be developed for the HMT and analyzed for suitability in a bus application. The resulting benefits and areas for improvement will be discussed.
Technical Paper

Analysis of overcharge tolerance of aged LMO cells with Examples

2023-09-29
2023-32-0108
The capacity of a lithium-ion battery decreases during cycling. This capacity loss or fade occurs due to several different mechanisms associated with unwanted side reactions that occur in these batteries. The same reactions occur during overcharge and cause electrolyte decomposition, passive film formation, active material dissolution, and other phenomena. As the battery ages the accuracy of state of charge prediction decreases and vulnerability to persistent overcharge increases. Moreover, as the battery ages, its tolerance to such unintended overcharge changes. This tolerance depends on the nature of the history of cycle and calendar aging. A map of this tolerance in the BMS can provide awareness of the factor of safety due to overcharge as battery ages. Signatures of early warning signs of incipient thermal runaway due to overcharge can also be very useful features in a BMS.
Technical Paper

Analysis of the Ignition Behaviour of the ASTM D-613 Primary Reference Fuels and Full Boiling Range Diesel Fuels in the Ignition Quality Tester (IQT™) - Part III

1999-10-25
1999-01-3591
This paper reports on the third part of a continued study (SAE Papers 961182, 971636) to develop the Ignition Quality Tester (IQT™). Past research has shown that this automated laboratory/refinery apparatus can be used to accurately predict the cetane number of middle distillates and alternative fuels using small sample volumes (< 50 mL). The paper reports on the main objective of a study performed by Advanced Engine Technology Ltd. (AET), in co-operation with its research partners. The primary research objective of this work is to further the understanding of fuel preparation (fuel air mixing) and start of combustion processes in the IQT™. Key to this understanding is the manner in which single molecule compounds and full boiling-range diesel fuels behave during these processes. Insights are provided into the manner in which the American Society for Testing and Materials (ASTM) D-613 primary reference fuels (PRFs) undergo fuel preparation and start of combustion in the IQT™.
Technical Paper

Assessment of Technology Readiness Level of a Carbon Dioxide Reduction Assembly (CRA) for Use on International Space Station

2004-07-19
2004-01-2446
When technologies are traded for incorporation into vehicle systems to support a specific mission scenario, they are often assessed in terms of “Technology Readiness Level” (TRL). TRL is based on three major categories of Core Technology Components, Ancillary Hardware and System Maturity, and Control and Control Integration. This paper describes the Technology Readiness Level assessment of the Carbon Dioxide Reduction Assembly (CRA) for use on the International Space Station. A team comprising of the NASA Johnson Space Center, Marshall Space Flight Center, Southwest Research Institute and Hamilton Sundstrand Space Systems International have been working on various aspects of the CRA to bring its TRL from 4/5 up to 6. This paper describes the work currently being done in the three major categories. Specific details are given on technology development of the Core Technology Components including the reactor, phase separator and CO2 compressor.
Technical Paper

CO2 Pump for the Space Station Advanced Atmosphere Revitalization Subsystem

2001-07-09
2001-01-2418
The current operation of the International Space Station (ISS) calls for the oxygen used by the occupants to be vented overboard in the form of CO2, after the CO2 is scrubbed from the cabin air. Likewise, H2 produced via electrolysis in the oxygen generator is also vented. NASA is investigating the use of the Sabatier process to combine these two product streams to form water and methane. The water is then used in the oxygen generator, thereby conserving this valuable resource. One of the technical challenges to developing the Sabatier reactor is transferring CO2 from the Carbon Dioxide Removal Assembly (CDRA) to the Sabatier reactor at the required rate, even though the CDRA and the Sabatier reactor operate on different schedules. One possible way to transfer and store CO2 is to use a mechanical compressor and a storage tank.
Technical Paper

Comparative Abuse Testing of 36 V and 12 V Battery Designs

2006-04-03
2006-01-1272
Comparative abuse tests were performed on commercially available 12 V and 36 V battery designs. Four methods were chosen from SAE J2464 standard, Electrical Vehicle Battery Abuse Testing, March 1999, and modified to apply them to typical-sized automotive batteries. The four tests included a Penetration Test, Crush Test, Radiant Heat Test, and Short Circuit Test. Both the 12 V and 36 V batteries showed minimal reactions to the tests, and there was no significant difference between results of the two designs with respect to the abuse tests performed. It should be stressed however, that this project was limited in scope and was not intended to be a thorough investigation in the batteries safety hazards.
Technical Paper

Comparison of Representative Wet and Dry Fire Suppressants to Retard Fire Propagation in Lithium-Ion Modules Initiated by Overcharge Abuse

2023-04-11
2023-01-0520
Overcharging lithium-ion batteries is a failure mode that is observed if the battery management system (BMS) or battery charger fails to stop the charging process as intended. Overcharging can easily lead to thermal runaway in a battery. In this paper, nickel manganese cobalt (NMC) battery modules from the Chevrolet Bolt, lithium manganese oxide (LMO) battery modules from the Chevrolet Volt, and lithium iron phosphate (LFP) battery modules from a hybrid transit bus were overcharged. The battery abuse and emissions tests were designed to intentionally drive the three different battery chemistries into thermal runaway while measuring battery temperatures, battery voltages, gaseous emissions, and feedback from volatile organic compound (VOC) sensors. Overcharging a battery can cause lithium plating and other exothermic reactions that will lead to thermal runaway.
Technical Paper

Container Deformation Procedure for Ceramic Monolith Catalytic Converters

2000-03-06
2000-01-0217
A typical automotive catalytic converter is constructed with a ceramic substrate and a steel shell. Due to a mismatch in coefficients of thermal expansion, the steel shell will expand away from the ceramic substrate at high temperatures. The gap between the substrate and shell is usually filled with a fiber composite material referred to as “mat.” Mat materials are compressed during assembly and must maintain an adequate pressure around the substrate under extreme temperature conditions. The container deformation measurement procedure is used to determine catalytic converter shell expansion during and after a period of hot catalytic converter operation. This procedure is useful in determining the potential physical durability of a catalytic converter system, and involves measuring converter shell expansion as a function of inlet temperature. A post-test dimensional measurement is used to determine permanent container deformation.
Technical Paper

Development of an In-Situ Diagnostic to Detect Lithium Plating in Commercial Automotive Battery Cells

2021-04-06
2021-01-0749
Lithium plating refers to the phenomenon where lithium metal is deposited onto the surface of the anode instead of being intercalated into the carbon sites of the graphite. The lithium metal will cover a portion of the surface area of the anode, which blocks intercalation sites and increases charge gradients. Lithium plating most often occurs when charging the battery at low ambient temperatures or at a high current rate, but lithium plating formation has also been linked to solid electrolyte interface (SEI) growth towards the later stages of life. Lithium plating may significantly reduce a battery cell’s performance in terms of charge capacity, and if severe enough, the lithium metal may form a bridge across the separator of the cell, leading to short circuits and potential safety concerns. The internal research performed by Southwest Research Institute explored how to create a battery model to detect the formation of lithium plating in real time.
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