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Technical Paper

42 Catalytic Reduction of Marine Sterndrive Engine Emissions

2002-10-29
2002-32-1811
A 2001 General Motors 4.3 liter V-6 marine engine was baseline emissions tested and then equipped with catalysts. Emission reduction effects of exhaust gas recirculation (EGR) were also explored. Because of a U.S. Coast Guard requirement that inboard engine surface temperatures be kept below 200°F, the engine's exhaust system, including the catalysts, was water-cooled. Engine emissions were measured using the ISO-8178-E4 5-mode steady-state test for recreational marine engines. In baseline configuration, the engine produced 16.6 g HC+NOx/kW-hr, and 111 g CO/kW-hr. In closed-loop control with catalysts, HC+NOx emissions were reduced by 75 percent to 4.1 g/kW-hr, and CO emissions were reduced by 36 percent to 70 g/kW-hr of CO. The catalyzed engine was then installed in a Sea Ray 190 boat, and tested for water reversion on both fresh and salt water using National Marine Manufacturers Association procedures.
Technical Paper

A Gas Separation Membrane Highly Selective to CO2 in the Exhaust of Internal Combustion Engines

2019-12-19
2019-01-2265
Southwest Research Institute has developed a passive, flow-through, membrane which separates carbon dioxide (CO2) from other exhaust gas species. Stoichiometric exhaust gas for 0% ethanol fuels contain approximately 14% CO2 by concentration. The membrane consists of a ceramic substrate impregnated with lithium zirconate (Li2ZrO3). In the presence of temperatures of 400-600 °C the CO2 reacts with lithium zirconate to form lithium carbonate (Li2CO3). The new compound moves from the inner surface of the membrane via partial pressure gradient to the outer wall of the membrane and desorbs into a low concentration CO2 environment, e.g. atmospheric air with 400 ppm CO2. SwRI has tested the membrane under engine-like conditions, comparable to 2000 rpm 10 bar BMEP operation, on a standalone burner rig (ECTO-lab burner). On the SwRI ECTO-lab burner rig temperature, flow-rate and exhaust gas products can be independently varied.
Technical Paper

A History of Mack Engine Lubricant Tests from 1985-2005: Mack T-7 through Mack T-12

2005-10-24
2005-01-3713
As on-highway, heavy-duty diesel engine designs have evolved to meet tighter emissions specifications and greater customer requirements, the crankcase environment for heavy-duty engine lubricants has changed. Engine lubricant quality is very important to help ensure engine durability, engine performance, and reduce maintenance downtime. Beginning in the late 1980's, a new Mack genuine oil specification and a new American Petroleum Institute (API) heavy-duty engine lubricant category have been introduced with each new U.S. heavy-duty, on-highway emissions specification. This paper documents the history and development of the Mack T-7, T-8, T-8A, T-8E, T-9, T-10, T-11, and T-12 engine lubricant tests.
Technical Paper

A Next-Generation Emission Test Procedure for Small Utility Engines - Part 1, Background and Approach

1990-09-01
901595
Measurement of emissions from small utility engines has usually been accomplished using steady-state raw emissions procedures such as SAE Recommended Practice J1088. While raw exhaust measurements have the advantage of producing modal exhaust gas concentration data for design feedback; they are laborious, may influence both engine performance and the emissions themselves, and have no provision for concurrent particulate measurements. It is time to consider a full-dilution procedure similar in principle to automotive and heavy-duty on-highway emission measurement practice, leading to improvements in many of the areas noted above, and generally to much higher confidence in data obtained. When certification and audit of small engine emissions become a reality, a brief dilute exhaust procedure generating only the necessary data will be a tremendous advantage to both manufacturers and regulatory agencies.
Technical Paper

A Non-Intrusive Method of Measuring PCV Blowby Constituents

1994-10-01
941947
A technique is presented that has been successfully demonstrated to non-intrusively and quickly sample gases typically found in PCV systems. Color Detection Tubes (CDTs) were used with a simple sampling arrangement to monitor CO2, NOx, O2, and H2O(g) at the closure line, crankcase, and PCV line. Measurements were accurate and could be made instantaneously. Short Path Thermal Desorbtion Tubes (SPTDTs) were used at the same engine locations for the characterization of fuel- and oil-derived hydrocarbon (HC) fractions and required only 50 cc samples. High engine loads caused pushover of blowby vapors as indicated by increased concentrations of CO2, NOx, H2O(g), and fuel HCs in the engines' fresh air inlets during WOT operation. Peak concentrations of blowby vapors were measured in the crankcase under no load and part throttle conditions. Oxygen concentrations always opposed the trends of CO2, NOx, and H2O(g).
Technical Paper

A Performance Comparison of Various Automatic Transmission Pumping Systems

1996-02-01
960424
The pumping system used in a step ratio automatic transmission can consume up to 20% of the total power required to operate a typical automotive transmission through the EPA city cycle. As such, it represents an area manufacturers have focused their efforts towards in their quest to obtain improved transmission efficiency. This paper will discuss the history of automatic transmission pumps that develop up to 300 psi along with a description of the factors used to size pumps and establish pump flow requirements. The various types of pumps used in current automatic transmissions will be described with a discussion of their characteristics including a comparison based upon observations of their performance. Specific attention will be focused on comparing the volumetric efficiency, mechanical efficiency, overall efficiency, pumping torque and discharge flow.
Technical Paper

Achieving Heavy-Duty Diesel NOx/PM Levels Below the EPA 2002 Standards--An Integrated Solution

2000-03-06
2000-01-0187
The diesel engine has long been the most energy efficient powerplant for transportation. Moreover, diesels emit extremely low levels of hydrocarbon and carbon monoxide that do not require post-combustion treatment to comply with current and projected standards. It is admittedly, however, difficult for diesel engines to simultaneously meet projected nitrogen oxides and particulate matter standards. Traditionally, measures aimed at reducing one of these two exhaust species have led to increasing the other. This physical characteristic, which is known as NOx/PM tradeoff, remains the subject of an intense research effort. Despite this challenge, there is significant evidence that heavy-duty highway engine manufacturers can achieve substantial emission reductions. Many development programs carried out over the last five years have yielded remarkable results in laboratory demonstrations.
Technical Paper

Achieving the 2004 Heavy-Duty Diesel Emissions Using Electronic EGR and a Cerium Based Fuel Borne Catalyst

1997-02-24
970189
The post-1998 diesel engine emissions challenge was put forth in July 1995 by the Statement of Principles (SOP) signed by the manufacturers of heavy duty engines, the U.S. Environmental Protection Agency (EPA) and the California Air Resources Board (CARB). Through this SOP, the signatories agreed to reduce the on-highway diesel engine NOx emissions by 50% from the legislated 1998 4.0 g/bhp.hr to 2.0 g/bhp.hr by the year 2004 with no increase over the 1998 particulate matter legislated level set at 0.1 g/bhp.hr. There are provisions in the SOP for the optional grouping of the gaseous hydrocarbons and NOx, limiting them at a combined value of 2.5 g/bhp.hr with a 0.5 g/bhp.hr hydrocarbon limit. In North America, particulate matter emissions standards were first imposed on heavy duty diesel engines in 1988. Since then, the NOx and particulate matter were balanced by taking advantage of the trade-off between the two pollutants inherent in diesel engines.
Technical Paper

Advanced Performance of Metallic Converter Systems Demonstrated on a Production V8 Engine

2002-03-04
2002-01-0347
It has been shown within the catalyst industry that the emission performance with higher cell density technology and therefore with higher specific geometric area is improved. The focus of this study was to compare the overall performance of high cell density catalysts, up to 1600cpsi, using a MY 2001 production vehicle with a 4.7ltr.V8 engine. The substrates were configured to be on the edge of the design capability. The goal was to develop cost optimized systems with similar emission and back pressure performance, which meet physical and production requirements. This paper will present the results of a preliminary computer simulation study and the final emission testing of a production vehicle. For the pre-evaluation a numerical simulation model was used to compare the light-off performance of different substrate designs in the cold start portion of the FTP test cycle.
Technical Paper

Aging of Zeolite Based Automotive Hydrocarbon Traps

2007-04-16
2007-01-1058
This paper analyzes the aging of zeolite based hydrocarbon traps to guide development of diagnostic algorithms. Previous research has shown the water adsorption ability of zeolite ages along with the hydrocarbon adsorption ability, and this leads to a possible diagnostic algorithm: the water concentration in the exhaust can be measured and related to aging. In the present research, engine experiments demonstrate that temperature measurements are also related to aging. To examine the relationship between temperature-based and moisture-based diagnostic algorithms, a transient, nonlinear heat and mass transfer model of the exhaust during cold-start is developed. Despite some idealizations, the model replicates the qualitative behavior of the exhaust system. A series of parametric studies reveals the sensitivity of the system response to aging and various noise factors.
Technical Paper

An Investigation of Sample Bag Hydrocarbon Emissions and Carbon Dioxide Permeation Properties

2004-03-08
2004-01-0593
The equipment for collecting dilute exhaust samples involves the use of bag materials (i.e., Tedlar®) that emit hydrocarbons that contaminate samples. This study identifies a list of materials and treatments to produce bags that reduce contamination. Based on the average emission rates, baked Tedlar®, Capran® treated with alumina deposition, supercritical CO2 extracted Kynar® and supercritical CO2 extracted Teflon NXT are capable of achieving the target hydrocarbon emission rate of less than 15 ppbC per 30 minutes. CO2 permeation tests were also performed. Tedlar, Capran, Kynar and Teflon NXT showed comparable average permeation rates. Based on the criteria of HC emission performance, changes in measured CO2 concentration, ease of sealing, and ease of surface treatment, none of the four materials could be distinguished from one another.
Technical Paper

Application of On-Highway Emissions Technology to a Backhoe

1992-04-01
920922
Recent legislation, including the California Clean Air Act of 1988 and the Federal Clean Air Act Amendment of 1990, includes off-road engines, equipment, and vehicles as targets for new exhaust emissions regulations. The Santa Barbara County Air Pollution Control District in cooperation with EXXON USA is conducting a major Low NOx Demonstration Program including mobile sources, construction equipment, and offshore equipment. As a part of this program, an existing backhoe has been retrofitted with a low NOx engine and demonstrated in the field. This paper discusses the work performed to allow Case model 580 backhoes to be retrofitted with Cummins 4BTAA3.9 on-highway turbocharged diesel engines. A standard production conversion kit can be used to mount the new engines in place of the older existing JI Case engines in some models while other newer models already have 4B3.9 engines. In addition, an air-to-air aftercooler and associated plumbing was designed and installed.
Journal Article

Automated Driving Impediments

2016-09-27
2016-01-8007
Since the turn of the millennium, automated vehicle technology has matured at an exponential rate, evolving from research largely funded and motivated by military and agricultural needs to a near-production market focused on everyday driving on public roads. Research and development has been conducted by a variety of entities ranging from universities to automotive manufacturers to technology firms demonstrating capabilities in both highway and urban environments. While this technology continues to show promise, corner cases, or situations outside the average driving environment, have emerged highlighting scenarios that impede the realization of full automation anywhere, anytime. This paper will review several of these corner cases and research deficiencies that need to be addressed for automated driving systems to be broadly deployed and trusted.
Technical Paper

Cetane Number Prediction from Proton-Type Distribution and Relative Hydrogen Population

1986-10-01
861521
A theoretical model for predicting cetane number of primary reference fuels from parameters measurable by proton nuclear magnetic resonance is presented. This modeling technique is expanded to include secondary reference fuels, pure hydrocarbons, and commercial-type fuels. An evaluation of the ignition process indicated that not only hydrogen type distribution measurable by proton NMR, but also relative hydrogen population is important in predicting cetane number. Two mathematical models are developed. One predicts cetane number of saturate fuels and the second predicts cetane number of fuels containing aromatic components. The aromatic fuel model is tested using the ASTM Diesel Check Fuels and shown to predict within the standard error of the model.
Technical Paper

Characterization of Particle Size Distribution of a Heavy-Duty Diesel Engine During FTP Transient Cycle Using ELPI

2000-06-19
2000-01-2001
Particle number concentrations and size distributions were measured for the diluted exhaust of a 1991 diesel engine during the US FTP transient cycle for heavy-duty diesel engines. The engine was operated on US 2-D on-highway diesel fuel. The particle measurement system consisted of a full flow dilution tunnel as the primary dilution stage, an air ejector pump as the secondary dilution stage, and an electrical low pressure impactor (ELPI) for particle size distribution measurements. Particle number emission rate was the highest during the Los Angeles Non Freeway (LANF) and the Los Angeles Freeway (LAF) segments of the transient cycle. However, on brake specific number basis the LAF had the lowest emission level. The particle size distribution was monomodal in shape with a mode between 0.084 μm and 0.14 μm. The shape of the size distribution suggested no presence of nanoparticles below the lower detection limit of the instrument (0.032 μm), except during engine idle.
Technical Paper

Cold-Start Hydrocarbon Collection for Advanced Exhaust Emission Control

1992-02-01
920847
This paper describes the findings of a laboratory effort to demonstrate improved automotive exhaust emission control with a cold-start hydrocarbon collection system. The emission control strategy developed in this study incorporated a zeolite molecular sieve in the exhaust system to collect cold-start hydrocarbons for subsequent release to an active catalytic converter. A prototype emission control system was designed and tested on a gasoline-fueled vehicle. Continuous raw exhaust emission measurements upstream and downstream of the zeolite molecular sieve revealed collection, storage, and release of cold-start hydrocarbons. Federal Test Procedure (FTP) emission results show a 35 percent reduction in hydrocarbons emitted during the cold-transient segment (Bag 1) due to adsorption by the zeolite.
Technical Paper

Comparative Emissions Performance of Sasol Fischer-Tropsch Diesel Fuel in Current and Older Technology Heavy-Duty Engines

2000-06-19
2000-01-1912
Comparative exhaust emission tests were performed with five diesel fuels, namely a Sasol Fischer-Tropsch diesel, a fuel meeting the CARB diesel fuel specification, a fuel meeting the US 2-D diesel fuel specification, and two blends of the Fischer-Tropsch diesel and the 2-D diesel. Hot-start and cold-start heavy-duty transient emission tests were performed using a 1999 model year DDC series 60 engine. Regulated exhaust emissions with the Fischer-Tropsch diesel were significantly lower than with the 2-D and CARB diesel fuels, in both the hot-start and cold-start tests. When compared with test results obtained previously with a 1991 engine, it was found that the reduction in NOX with the Fischer-Tropsch fuel was smaller in the 1999 engine, while the reduction in PM was greater.
Technical Paper

Comparison Between Real-Life Dust Samples and Standardized Test Dusts

1994-03-01
940322
Soil samples were collected from various geographical areas in the United States and Saudi Arabia. The samples were obtained from U.S. military installations at which off-road maneuvers are conducted. Saudi Arabia samples were obtained from the deserts surrounding Riyadh. The samples were characterized using particle size distributions, elemental analysis, mineral composition and particle angularity. Particle size distributions were determined for simulated fuel cells with intermittent and continual mixing. The results obtained from the world-wide soil sample analyses were compared against AC and PTI SAE fine and coarse test dust results.
Technical Paper

Comparison of Emission Characteristics of Conventional, Hydrotreated, and Fischer-Tropsch Diesel Fuels in a Heavy-Duty Diesel Engine

2001-09-24
2001-01-3519
This study compared diesel exhaust emission from four different diesel fuels: a conventional low sulfur D2 diesel (0.03% sulfur, 28% aromatics), California Air Resources Board (CARB) diesel (0.015% sulfur, 8% aromatics), “Swedish” diesel (<0.001% sulfur, 4% aromatics), and a Fischer-Tropsch (F-T) diesel (<0.0001% sulfur, <0.1% aromatics) fuel. The comparison included regulated emissions, hydrocarbon speciation, air toxics, aldehydes and ketones, particle size distribution, and greenhouse gas emissions. Testing was conducted using a Cummins B-Series engine installed both in a heavy light-duty truck operating on a chassis dynamometer and on an engine dynamometer. The chassis driving cycles included city, highway, and aggressive driving operation. Engine dynamometer tests included the U.S. transient cycle.
Technical Paper

Comparison of Emissions and Fuel Economy Characteristics of Conventional, Additized, and Substantially Synthetic Diesel Fuels in a Heavy-Duty Diesel Engine

2002-05-06
2002-01-1702
This study compared four different candidate fuels which were prepared by blending different components with a typical No. 2 diesel. Two fuels were blended with a synthetic diesel prepared from natural gas condensate, and all candidate fuels were splash blended with a proprietary additive package from International Fuel Technology Inc. (IFT). These fuels were then compared to the No. 2 diesel and to a California Air Resources Board (CARB) equivalent diesel fuel. The comparisons included fuel properties such as sulfur content, aromatics, cetane, lubricity, distillation; emissions; and fuel consumption. Emission testing was conducted on a 1991 Detroit Diesel Series 60. The Environmental Protection Agency (EPA) transient cycle was utilized for emissions, fuel characterization was performed according to ASTM standards, and fuel consumption was calculated by the carbon balance method.
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