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A prototype 2007 ISL Cummins diesel engine equipped with a diesel oxidation catalyst (DOC), diesel particle filter (DPF), variable geometry turbocharger (VGT), and cooled exhaust gas recirculation (EGR) was tested at Southwest Research Institute (SwRI) under a high-load accelerated durability cycle for 1000 hours with B20 soy-based biodiesel blends and ultra-low sulfur diesel (ULSD) fuel to determine the impact of B20 on engine durability, performance, emissions, and fuel consumption. At the completion of the 1000-hour test, a thorough engine teardown evaluation of the overhead, power transfer, cylinder, cooling, lube, air handling, gaskets, aftertreatment, and fuel system parts was performed. The engine operated successfully with no biodiesel-related failures. Results indicate that engine performance was essentially the same when tested at 125 and 1000 hours of accumulated durability operation.

Particle number concentrations and size distributions were measured for the diluted exhaust of a 1991 diesel engine during the US FTP transient cycle for heavy-duty diesel engines. The engine was operated on US 2-D on-highway diesel fuel. The particle measurement system consisted of a full flow dilution tunnel as the primary dilution stage, an air ejector pump as the secondary dilution stage, and an electrical low pressure impactor (ELPI) for particle size distribution measurements. Particle number emission rate was the highest during the Los Angeles Non Freeway (LANF) and the Los Angeles Freeway (LAF) segments of the transient cycle. However, on brake specific number basis the LAF had the lowest emission level. The particle size distribution was monomodal in shape with a mode between 0.084 μm and 0.14 μm. The shape of the size distribution suggested no presence of nanoparticles below the lower detection limit of the instrument (0.032 μm), except during engine idle.

The primary goal of this project was to characterize particulate emissions from a snowmobile engine through measurement of particulate matter volatile organic fraction (VOF), particle size, and biological activity. Emissions were evaluated using both a mineral oil and a biosynthetic oil. Basic criteria pollutants were also measured from diluted exhaust using conventional techniques. Particulate matter volatile organic fraction was determined using a gas chromatographic method (DFI/GC). Particle size was characterized using a scanning mobility particle sizer (SMPS), and particulate matter biological activity was measured using a modification of the Ames bioassay procedure. Results revealed that more than 99 percent of the particles were ultrafine (Dp<100nm), with a peak concentration in the nanoparticle (Dp<50nm) size range. It was also observed that the use of a biosynthetic lubricant increased both volatile and total PM mass emissions compared to the mineral lubricant.

Comparative exhaust emission tests were performed with five diesel fuels, namely a Sasol Fischer-Tropsch diesel, a fuel meeting the CARB diesel fuel specification, a fuel meeting the US 2-D diesel fuel specification, and two blends of the Fischer-Tropsch diesel and the 2-D diesel. Hot-start and cold-start heavy-duty transient emission tests were performed using a 1999 model year DDC series 60 engine. Regulated exhaust emissions with the Fischer-Tropsch diesel were significantly lower than with the 2-D and CARB diesel fuels, in both the hot-start and cold-start tests. When compared with test results obtained previously with a 1991 engine, it was found that the reduction in NOX with the Fischer-Tropsch fuel was smaller in the 1999 engine, while the reduction in PM was greater.

In the United States, most school buses are powered by diesel engines. Some have advocated replacing diesel school buses with natural gas school buses, but little research has been conducted to understand the emissions from school bus engines. This work provides a detailed characterization of exhaust emissions from school buses using a diesel engine meeting 1998 emission standards, a low emitting diesel engine with an advanced engine calibration and a catalyzed particulate filter, and a natural gas engine without catalyst. All three bus configurations were tested over the same cycle, test weight, and road load settings. Twenty-one of the 41 “toxic air contaminants” (TACs) listed by the California Air Resources Board (CARB) as being present in diesel exhaust were not found in the exhaust of any of the three bus configurations, even though special sampling provisions were utilized to detect low levels of TACs.

This paper summarizes the Heavy-Duty In-Use Testing (HDUIT) measurement allowance program for Particulate Matter Portable Emissions Measurement Systems (PM-PEMS). The measurement allowance program was designed to determine the incremental error between PM measurements using the laboratory constant volume sampler (CVS) filter method and in-use testing with a PEMS. Two independent PM-PEMS that included the Sensors Portable Particulate Measuring Device (PPMD) and the Horiba Transient Particulate Matter (TRPM) were used in this program. An additional instrument that included the AVL Micro Soot Sensor (MSS) was used in conjunction with the Sensors PPMD to be considered a PM-PEMS. A series of steady state and transient tests were performed in a 40 CFR Part 1065 compliant engine dynamometer test cell using a 2007 on-highway heavy-duty diesel engine to quantify the accuracy and precision of the PEMS in comparison with the CVS filter-based method.

A solid particle number measurement system (SPNMS) was developed using a catalytic stripper (CS) technology instead of an evaporation tube (ET). The ET is used in commercially available systems, compliant with the Particle Measurement Program (PMP) protocol developed for European Union (EU) solid particle number regulations. The catalytic stripper consists of a small core of a diesel exhaust oxidation catalyst. The SPNMS/CS met all performance requirements under the PMP protocol. It showed a much better performance in removing large volatile tetracontane particles down to a size well below the PMP lower cut-size of 23 nm, compared to a SPNMS equipped with an ET instead of a CS. The SPNMS/CS also showed a similar performance to a commercially available system when used on a gasoline direct injection (GDI) engine exhaust.

Emissions from existing diesel-powered urban buses are increasingly scrutinized as local, state, and federal governments require enforcement of more stringent emission regulations and expectations. Currently, visual observation of high smoke levels from diesel-powered equipment is a popular indicator of potential emission problems requiring tune-up or engine maintenance. It is important that bus inspection and maintenance (I/M) operations have a quality control “test” to check engine emissions or diagnose the engine state-of-tune before or after maintenance. Ideally, the “emission test” would be correlated to EPA transient emissions standards, be of short duration, and be compatible with garage procedures and equipment. In support of developing a useful “short-test,” equipment was designed to collect samples of raw exhaust over a short time period for gaseous and particulate emissions.

Horiba on-board diesel exhaust particulate sampler (OBS-PM) is a filter based partial flow particulate sampling system used for On-board diesel particulate matter (PM) measurement. It takes sample from either raw or diluted exhaust. It can run at constant dilution ratios or at variable dilution ratios with proportional control on the sample flow. The diluted exhaust moves through a pre-weighed 47 mm particulate filter and PM is collected on the filter. By weighing the loaded sample filter, PM emission from the engine or the vehicle can be determined. The performance of the OBS-PM meets most of requirements for a real-time partial flow sample system (PFSS) recommended by ISO 16183 [2]. The physical size and the power consumption of the instrument are minimized. It is powered with four 12 volts batteries, and can be installed on a vehicle for real-world PM emission evaluation.

Gasoline direct injected (GDI) engines are becoming a concern with respect to particulate matter (PM) emissions. The upcoming 2014 Euro 6 regulations may require a drastic reduction in solid particle number emissions from GDI engines and the proposed California Air Resources Board (CARB) LEV III regulations for 2014 and 2017 will also require some PM reduction measures. As a result, it is necessary to characterize PM emissions from GDI engines and investigate strategies that suppress particle formation during combustion. The main focus of this work was on using exhaust gas recirculation (EGR) as a means to reduce engine-out particle emissions from a GDI engine with an overall stoichiometric fuel to air mixture. A small displacement, turbocharged GDI engine was operated at a variety of steady-state conditions with differing levels of EGR to characterize total (solid plus volatile) and solid particle emissions with respect to size, number, and soot or black carbon mass.

As stringent emission regulations further constrain engine manufacturers by tightening both NOx and particulate emission limits, a knowledge of fuel effects becomes more important than ever. Among the fuel properties that affect heavy-duty diesel engine emissions, cetane number can be very important. Part of the CRC-APRAC VE-10 Project was developed to quantify the effects of cetane number on NOx and other emissions from a prototype 1998 Detroit Diesel Series 60. Three fuels with different natural cetane number (41, 45, 52) were treated with several levels and types of cetane improvers to study a range of cetane number from 40 to 60. Statistical analysis was used to define how regulated emissions from this prototype 1998 engine decreased with chemically-induced cetane number increase. Variation of HC, CO, NOx, and PM were modeled using a combination of a fuel's naturally-occurring cetane number and its total cetane number obtained with cetane improver.

A Coordinating Research Council sponsored test program was conducted to determine the effects of diesel fuel properties on emissions from two heavy-duty diesel engines designed to meet EPA emission requirements for 1994. Results for a prototype 1994 DDC Series 60 were reported in SAE Paper 941020. This paper reports the results from a prototype 1994 Navistar DTA-466 engine equipped with an exhaust catalyst. A set of ten fuels having specific variations in cetane number, aromatics, and oxygen were used to study effects of these fuel properties on emissions. Using glycol diether compounds as an oxygenated additive, selected diesel fuels were treated to obtain 2 and 4 mass percent oxygen. Cetane number was increased for selected fuels using a cetane improver. Emissions were measured during transient FTP operation of the Navistar engine tuned for a nominal 5 g/hp-hr NOx, then repeated using a 4 g/hp-hr NOx calibration.

Several studies have investigated the effects of diesel fuel properties on heavy-duty engine emissions. The objective of this CRC-sponsored test program was to determine the effects of oxygenated diesel fuel, and to further investigate the effects of cetane number and aromatic content on emissions from a heavy-duty engine set to obtain transient NOx emissions below 5 and then 4 g/hp-hr. A fuel set was developed with controlled variations in cetane number, aromatics, and oxygen to superette their effects on emissions. Ignition improver was used to increase cetane number of several fuels. Oxygenated diesel fuel was achieved by adding a “glyme” compound to selected fuels to obtain 2 and 4 mass percent oxygen concentrations. With these fuels, emissions were measured over the EPA transient FTP using a prototype 1994 DDC Series 60 tuned for 5 and then 4 g/hp-hr NOx. No exhaust aftertreatment device was used on this engine.

Concern over emissions from heavy-duty diesel engines at high altitudes prompted an investigation into the effects of increasing altitude on gaseous and particulate emissions. On behalf of the Engine Manufacturers Association, emissions from a Detroit Diesel Corporation Series 60 at local test conditions (barometer 98.9 kPa), and two simulated altitudes, Denver (82.6 kPa) and Mexico City (77.9 kPa) were examined using a special altitude simulation CVS. Transient torque output and full load steady-state torque, for this turbocharged aftercooled engine, decreased slightly with increasing altitude. Although, the DDC Series 60 compensates for variation in barometer, transient composite emissions of HC, CO, CO2, smoke, and particulate matter generally increased with increasing altitude for both transient and steady-state operation.

A previous paper reported (SAE Paper 2002-01-2884) that it was possible to decrease mode-weighted NOx emissions compared to the OEM calibration with corresponding increases in particulate matter (PM) emissions. These PM emission increases were partially overcome with the use of oxygenated diesel fuel additives. We wanted to know if compounds of toxicological concern were emitted more or less using oxygenated diesel fuel additives that were used in conjunction with a modified engine operating strategy to lower engine-out NOx emissions. Emissions of toxicologically relevant compounds from fuels containing triproplyene glycol monomethyl ether and dibutyl maleate were the same or lower compared to a low sulfur fuel (15 ppm sulfur) even under engine operating conditions designed to lower engine-out NOx emissions.

Previously we reported (SAE Paper 2005-01-0475) that emissions of toxicologically relevant compounds from an engine operating at low NOx conditions using Fischer-Tropsch fuel (FT100) were lower than those emissions from the engine using an ultra-low sulfur (15 PPM sulfur) diesel fuel (BP15). Those tests were performed at two operating modes: Mode 6 (4.2 bar BMEP, 2300 RPM) and Mode 11 (2.62 bar BMEP, 1500 RPM). We wanted to evaluate the effect on emissions of operating the engine at low power (near idle) in conjunction with the low NOx strategy. Specifically, we report on emissions of total hydrocarbon (HC), carbon monoxide (CO), NOx, particulates (PM), formaldehyde, acetaldehyde, benzene, 1,3-butadiene, gas phase polyaromatic hydrocarbons (PAH's) and particle phase PAH's from a DaimlerChrysler OM611 CIDI engine using a low NOx engine operating strategy at Mode 22 (1.0 bar BMEP and 1500 RPM).

The emission performance of a 1997 Mercedes OM 366 LA medium heavy-duty diesel engine and a 1998 Detroit Diesel Corporation (DDC) Series 60 heavy heavy-duty diesel engine was investigated using the US EPA hot-start transient cycle using different candidate diesel fuels developed by the Empresa Nacional Del Petroleo (ENAP), the state-owned oil production and refining company of Chile. The aim of the work was to identify a clean diesel fuel that can be readily produced and reduces emissions from diesel engines in Chile, particularly in Santiago Metropolitan Area where air pollution is a serious problem. Using a Mercedes engine of the type found in Chile, several candidate fuel formulations were tested in both the Mercedes and DDC engines to identify leading candidate formulations that would effectively reduce emission in both traditional and modern technology engines.

The U.S. EPA and the California Air Resources Board have adopted standards to reduce emissions from recreational marine vessels. Existing regulations focus on reducing hydrocarbons. There are no regulations on particulate emissions; particulate is expected to be reduced as a side benefit of hydrocarbon control. The goal of this study was to develop a sampling methodology to measure particulate emissions from marine outboard and personal watercraft engines. Eight marine engines of various engine technologies and power output were tested. Emissions measured in this program included hydrocarbons, carbon monoxide, oxides of nitrogen. Particulate emissions will be presented in a follow-up paper.

Nanoparticle formation during exhaust sampling and dilution has been examined using a two-stage micro-dilution system to sample the exhaust from a modern, medium-duty diesel engine. Growth rates of nanoparticles at different exhaust dilution ratios and temperatures have been determined by monitoring the evolution of particle size distributions in the first stage of the dilution system. Two methods, graphical and analytical, are described to determine particle growth rate. Extrapolation of size distribution down to 1 nm in diameter has been demonstrated using the graphical method. The average growth rate of nanoparticles is calculated using the analytical method. The growth rate ranges from 6 nm/sec to 24 nm/sec, except at a dilution ratio of 40 and primary dilution temperature of 48 °C where the growth rate drops to 2 nm /sec. This condition seems to represent a threshold for growth. Observed nucleation and growth patterns are consistent with predictions of a simple physical model.

The United States Environmental Protection Agency (EPA) has initiated Phase I of a regulatory program to control exhaust emissions of nonroad diesel engines over 37 kW. Central to any emissions regulation is the test procedure, which must include an appropriate test cycle. Based on actual in-use speed and estimated torque data collected from an agricultural tractor, a backhoe-loader, and a crawler tractor, three duty cycles were developed. Using an iterative process, comparison of chi-square statistical data was used to identify representative microtrips, segments of engine operation gathered during performance of selected activities. Representative microtrips for specific activities for a particular nonroad application were “strung” together to make up a test cycle. Before accepting the test cycle, data for the cycle was compared to statistical data used to characterize the raw data in an effort to validate that the cycle was representative of the raw data.