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Technical Paper

An Ethanol SCR for NOx Purification: Performance Evaluation on Engine Bench and Demonstration on Bus

2007-04-16
2007-01-1240
NOx -SCR over Ag/ Al2O3 catalyst using ethanol (C2H5OH) as a reductant has proven its ability to significantly reduce NOx emission in a simulated engine exhaust gas environment. However the real engine exhaust gas environment is too complicated to be simulated. Therefore, the performance evaluation of the Ag/ Al2O3 catalyst in real exhaust gas environment is necessary. Moreover, the ethanol dosing device and control strategy also need to be validated for the practical use. In this paper, firstly the catalyst performance and its sulfur tolerance was tested on an engine test bench and the effect of the catalyst on PM emission was investigated. Then the aftertreatment system composed of Ag/Al2O3 catalyst + Cu/TiO2 catalyst + Pt/TiO2 catalyst and ethanol dosing control based on open loop control was designed, and the diesel engine emission with the aftertreatment system was tested according to ESC test cycle.
Technical Paper

Effect of Urea Thermal Decomposition on Diesel NOx-SCR Aftertreatment Systems

2008-06-23
2008-01-1544
Urea Selective Catalytic Reduction (SCR) has been proven to significantly reduce NOx emissions from diesel engines. The thermal decomposition of urea, which forms the ammonia as the reactant, has a crucial effect on the performance and durability of the NOx-SCR system. The incomplete thermal decomposition of urea not only reduces the NOx conversion ratio and increases the ammonia slip, but also leads to deposit formation on the catalyst surface, which will block the pore and the active sites of the catalyst and then decreases the durability of the SCR systems. In this paper, the urea thermolysis was measured using the Thermal Gravimetric Analysis (TGA) and Fourier Transform Infrared Spectroscopy (FTIR). Then, the performance of the SCR systems under different injection parameters of the Urea-water solution was investigated on a diesel engine test bench. Finally, the deposits on the catalyst were also analyzed using TGA and FTIR.
Technical Paper

Effects of Fuel Quality on a Euro IV Diesel Engine with SCR After-Treatment

2008-04-14
2008-01-0638
Beijing will implement the 4th stage emission regulations (equivalent to Euro IV) in 2008 ahead of other provinces or cites in China. Beijing Environmental Protection Bureau (EPB) organized petroleum corporations, automobile and engine manufactories as well as research institutes to test the adaptability of the fuels from Chinese refineries to the modern vehicles or engines on the road running conditions in China. In this paper, the effects of diesel fuel quality on combustion and emission of a Euro IV heavy-duty diesel engine as one part of the program were studied to provide technical data to stipulate the feasible diesel fuel standard, which should guarantee modern vehicles or engines to meet the 4th stage regulations. Eight kinds of diesel fuels with different properties, such as cetane number, distillation temperature (T90) and sulfur content, were tested on a Euro IV Cummins heavy-duty diesel engine with urea SCR after-treatment.
Technical Paper

Effects of Gasoline Fuel Properties on Engine Performance

2008-04-14
2008-01-0628
Beijing will implement the national 4th stage emissions standards (equivalent to Euro IV emissions standards) in advance in China from 2008. The objective of this study was to provide some technical support for proposing automotive gasoline fuel standards matching with the emission standards. In this paper, tests were conducted on two engines and one gasoline passenger vehicle meeting Euro III or IV emission standards to study the correlation between gasoline fuel properties and engine performances, including power, fuel consumption and emissions. Test results showed that the effect of octane number on engine power depended on engine technologies. High octane number had a negative effect on fuel consumption and emissions. As olefin content increased, the engine-out THC emissions decreased significantly. The vehicle test results also showed that high olefin content greatly reduced the tailpipe THC emissions.
Technical Paper

Influence of Methanol Gasoline Blend Fuel on Engine and Catalyst Performance

2009-04-20
2009-01-1182
According to China's “oil-poor, gas-litte, coal-rich” structure of energy resources, to promote the development of coal-based methanol fuel as a clean alternative to gasoline and diesel fuel is one of the most realistic options. So the adaptability of methanol gasoline blend fuel used in the gasoline engine and vehilce should be investigated. Engine load performance, engine out emission, air fuel ratio variation and combustion characteristics were tested in a PFI Euro III gasoline engine using gasoline, M10, M15, M20, M30 as fuel without any modification of the engine. Air fuel ratio, light-off temperature and load characteristics of catalystic conversion coefficient were also investigated. And effects of methanol content on fuel consumption and vehicle out emissions of a Euro - vehicle are analyzed.
Technical Paper

Investigation of Soot Formation in Laminar Diesel Diffusion Flame by Two-Color Laser Induced Incandescence

2008-04-14
2008-01-1064
Soot emissions in the combustion process of diesel engines are greatly harmful to the environment and human health. Consequently, there is large interest and great efforts in decreasing soot emission from diesel engines to meet the increasingly stringent emission standards. The mechanisms of soot formation and oxidation so far have not been well understood. Laser induced incandescence (LII) is particularly suited to measure the instantaneous spatial distribution of the soot volume concentration, which can offer much needed detailed information of soot distribution for better understanding of soot formation and oxidation. In this paper, a two-color laser induced incandescence (2C-LII) technique was implemented for measuring absolute soot volume fraction in a laminar diesel fuel diffusion flame.
Technical Paper

Performance Evaluation and Application of Diesel NOx-SCR Catalyst by Ethanol Reductant

2005-04-11
2005-01-1089
A catalyst surfaced on Ag/Al2O3 substrate for the selective catalyst reduction (SCR) of NOx by ethanol was evaluated in a diesel engine, and the effect of the catalyst on the reduction of NOx from the diesel engine under the EURO III ESC test modes was also investigated. The reductant injecting device was designed by means of computational fluid dynamics (CFD) analysis, and the engine test bench including the reductant injection system for the evaluation of the NOx-SCR catalyst performance was established. On the bench, the SCR catalyst with the ethanol reductant was tested at different temperatures and space velocities (SV), and integrated with an oxidation catalyst to reduce the diesel exhaust emissions of NOx, HC and CO. Under the conditions of the SV=30,000 h-1 and the exhaust temperature range of 350∼420°C, the NOx conversion efficiency is high over 90% and low beyond the temperature range.
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