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Technical Paper

A Case Study of a Cu-SSZ-13 SCR Catalyst Poisoned by Real-World High Sulfur Diesel Fuel

2020-04-14
2020-01-1319
To meet increasingly stringent diesel engine emission regulations, diesel engines are required to use ultra-low sulfur diesel (ULSD) and are equipped with advanced aftertreatment systems. Cu-SSZ-13 zeolite catalysts are widely used as selective catalytic reduction (SCR) catalysts due to their high NOx reduction and excellent hydrothermal stability. However, active Cu sites of Cu-SSZ-13 catalysts can be poisoned by exposure to engine exhaust sulfur species. This poison effect can be mitigated with the use of ULSD and high temperature exposure from engine operation. On the other hand, ULSD is still not universally available where regulations require it, and vehicles may inadvertently operate with high sulfur diesel fuel (HSD) in some locations. The high concentration of exhaust sulfur species resulting from HSD combustion may rapidly poison the Cu-SSZ-13 SCR catalyst. In this study, the catalytic performance of a sulfur poisoned Cu-SSZ-13 SCR catalyst is analyzed.
Technical Paper

A Comparison of Black Carbon Measurements to Solid Particle Number Measurements Made over Steady State and Transient Cycles

2015-04-14
2015-01-1074
Diesel engines have been identified as contributing to more than half of the transport sectors black carbon (BC) emissions in the US. This large contribution to atmospheric BC concentrations has raised concern about source specific emission rates, including off-highway engines. The European Union has recently implemented more stringent particulate regulations in the form of particle number via the Particle Measurement Programme (PMP) methodology. The PMP method counts the non-volatile fraction of particulate matter (PM) above 23 nm and below 2.5 μm via a condensation particle counter. This study evaluates a surrogate black carbon method which uses the PMP particle count method with a correlation factor to the BC fraction. The transient capable Magee Scientific Aethalometer (AE-33) 880 nm wavelength channel was used to determine the BC fraction.
Technical Paper

A Model Based Definition of a Reference CO2 Emissions Value for Passenger Cars under Real World Conditions

2018-05-30
2018-37-0031
With the adoption of the Worldwide harmonized Light Vehicles Test Procedure (WLTP) and the Real Driving Emissions (RDE) regulations for testing and monitoring the vehicle pollutant emissions, as well as CO2 and fuel consumption, the gap between real world and type approval performances is expected to decrease to a large extent. With respect to CO2, however, WLTP is not expected to fully eliminate the reported 40% discrepancy between real world and type approval values. This is mainly attributed to the fact that laboratory tests take place under average controlled conditions that do not fully replicate the environmental and traffic conditions experienced over daily driving across Europe. In addition, any uncertainties of a pre-defined test protocol and the vehicle operation can be optimized to lower the CO2 emissions of the type approval test. Such issues can be minimized in principle with the adoption of a real-world test for fuel consumption.
Technical Paper

A Novel Start Algorithm for CNG Engines Using Ion Sense Technology

2000-10-16
2000-01-2800
This paper presents a start algorithm that is able to control the air/fuel ratio (AFR) during the cranking phase and immediately hereafter, where the ordinary λ-control is not yet enabled. The control is based on the ion sense principle, which means that a current through the spark plug is measured directly after the spark has disappeared. This current is a measure for the temperature and therefore of the combustion in the cylinder. This is an excellent way to start a CNG (Compressed Natural Gas) engine with unknown gas qualities. A typical example of application is when the vehicle is almost out of fuel and is refueled at a motel stop. The small amount of old fuel that is left in the system will mix with the new fuel resulting in an unknown fuel quality. The control system shall then be able to start the engine directly or after an accommodation over night. During the last condition, the oxygen sensor is still cold and thus not able to correct for fuel quality changes.
Technical Paper

A Seat Sensitivity Study on Vertical Vibrations and Seat Pressure Distributions using Numerical Models

2004-06-15
2004-01-2142
The introduction of a new comfortable car seat or interior is a time consuming and costly process for car and seat manufacturers. The application of numerical models of human and seat could facilitate this process. Vertical vibrations and seat pressure distributions are two objective parameters that have been related to the subjective feeling of (dis)comfort that can be predicted by numerical tools. In this paper, human models suitable for prediction of human behaviour in vertical vibrations and seat pressure distributions are applied in a seat sensitivity study. The objective of this paper is to evaluate the applicability of the human models as design tools for car and seat developers in an early stage of the design process. The sensitivity of the output of the models for variations in seat characteristics for seat developers in the design process of a new comfortable car seat has been studied.
Technical Paper

A Stochastic Virtual Testing Approach in Vehicle Passive Safety Design: Effect of Scatter on Injury Response

2005-04-11
2005-01-1763
Virtual testing has grown to be an efficient tool in vehicle passive safety design. Most simulations currently are deterministic. Since the responses observed in real-life and standardized tests are greatly affected by scatter, a stochastic approach should be adopted in order to improve the predictability of the numerical responses with respect to the experimental data. In addition, an objective judgement of the performance of numerical models with respect to experimental data is necessary in order to improve the reliability of virtual testing. In the European VITES & ADVANCE project the software tool Adviser was developed in order to fulfil these two requirements. With Adviser, stochastic simulations can be performed and the quality of the numerical responses with respect to the experimental can be objectively rated using pre-defined and user-defined objective correlation criteria. The software Adviser was used to develop a stochastic HybridIII 50th% Madymo numerical model.
Technical Paper

A Study on the Emissions of Chemical Species from Heavy-Duty Diesel Engines and the Effects of Modern Aftertreatment Technology

2009-04-20
2009-01-1084
A comparative analysis was made on the emissions from a 2004 and a 2007 heavy-duty diesel engine to determine how new engine and emissions technologies have affected the chemical compounds found in the exhaust gases. Representative samples were collected from a source dilution sampling system and analyzed for both criteria and unregulated gaseous and particulate emissions. Results have shown that the 2007 regulations compliant engine and emissions technology not only reduced the specifically regulated exhaust pollutants, but also significantly reduced the majority of unregulated chemical species. It is believed that these reductions were achieved through the use of engine optimization, aftertreatment system integration, and ultra-low sulfur diesel fuel.
Technical Paper

Advances in numerical modelling of crash dummies

2001-06-04
2001-06-0007
Nowadays virtual testing and prototyping are generally accepted methods in crash safety research and design studies. Validated numerical crash dummy models are necessary tools in these methods. Computer models need to be robust, accurate and CPU efficient, where the balance between accuracy and efficiency is depending on the nature of the study performed. This paper presents the application of advanced multibody-modelling techniques, in order to generate crash dummy models that are accurate as well as CPU efficient. Two techniques, deformable body modelling and arbitrary surface modelling, are combined. Their application is presented by means of an example model: the Hybrid III 50th percentile thorax. The method for generating the model is explained, after which the accuracy and efficiency of the model is illustrated by presenting some simulation results.
Journal Article

Ammonia Sensor for Closed-Loop SCR Control

2008-04-14
2008-01-0919
Selective Catalytic Reduction (SCR) is the dominant solution for meeting future NOx reduction regulations for heavy-duty diesel powertrains. SCR systems benefit from closed-loop control if an appropriate exhaust gas sensor were available. An ammonia sensor has recently been developed for use as a feedback element in closed-loop control of urea dosing in a diesel SCR aftertreatment system. Closed-loop control of SCR dosing enables the SCR system to be robust against disturbances and to meet conformity of production (COP) and in-use compliance norms. The ammonia sensor is based on a non-equilibrium electrochemical principle and outputs emf signals. The sensor performs well when tested in a diesel engine exhaust environment and has minimum cross interference with CO, HC, NO, NO2, SO2, H2O and O2. Previous work, done in a simulation environment, demonstrated that an ammonia sensor provides the optimal feedback for urea dosing control algorithms in closed-loop SCR systems.
Technical Paper

Ammonium Nitrate Formation and Decomposition on an Extruded Vanadium-Based SCR Catalyst

2020-04-14
2020-01-1320
In this study, the formation and decomposition of ammonium nitrate (AN) on a state-of-the-art extruded vanadium-based SCR catalyst (V-SCR) under simulated exhaust conditions has been evaluated. Results show that AN readily forms and accumulates at temperatures below 200°C when exposed to NH3 and NO2. The rate of AN accumulation increases with decreasing temperature. A new low temperature NH3 release peak (not present following NH3 storage conditions with NH3 only) becomes apparent after AN accumulation at 100 and 125°C. This new NH3 release, with a peak release temperature of approximately 180°C, is evaluated in detail to better determine its origin. BET surface area, and thermal gravimetric analysis/differential scanning calorimetry (TGA/DSC), and reactor-based experiments are all used to characterize AN formed on the V-SCR catalyst in comparison to pure AN.
Technical Paper

Analysis of Packaging Impact on Emission Catalyst Design

2014-04-01
2014-01-1560
Diesel emission aftertreatment system is usually designed to meet stringent packaging constraints, rendering a difficult situation to achieve perfect flow distribution inside the catalytic unit. The non-uniform flow pattern leads to a mal-distribution of flow velocity, temperature, and gas species in catalyst unit. Some catalysts are exposed to harsh working environment, while the rest catalysts are underutilized. This lowers the efficiency of overall catalyst unit and thus requires an oversized system to meet emission requirements. The flow mal-distribution also accelerates the uneven catalyst degradation, lowering the system durability. Hence, a quantitative description of packaging impact on catalyst performance is critical to assess the system efficiency and durability. In the present work, a mapping method is developed to combine catalyst performance with computational fluid dynamics (CFD) simulation.
Technical Paper

Appliance of High EGR Rates With a Short and Long Route EGR System on a Heavy Duty Diesel Engine

2007-04-16
2007-01-0906
The goal of this work was to investigate the possibilities of applying high EGR rates with low NOx and PM emission levels on a two-stage turbocharged 12 liter heavy duty diesel engine. The EGR is applied by using a long and short route EGR system. For the ESC operating points A25 and C100 EGR is applied, such that the NOx emission is 0.5 g/kWh. Lowest PM level and BSFC are achieved when long route EGR is applied in A25 and short route is applied in C100. Increasing the fuel line pressure is an effective way to reduce PM at high EGR rate engine running conditions. At a fuel line pressure of 2400 bar PM emission are 0.06 g/kWh for A25 and 0.54 g/kWh for C100. At C100 the PM reduction coincides with also a significant fuel consumption improvement. Retarding the injection timing at C100 can improve the PM emission further to a level of 0.13 g/kWh at the expense of an increase in BSFC.
Journal Article

Automated Model Fit Method for Diesel Engine Control Development

2014-04-01
2014-01-1153
This paper presents an automated fit for a control-oriented physics-based diesel engine combustion model. This method is based on the combination of a dedicated measurement procedure and structured approach to fit the required combustion model parameters. Only a data set is required that is considered to be standard for engine testing. The potential of the automated fit tool is demonstrated for two different heavy-duty diesel engines. This demonstrates that the combustion model and model fit methodology is not engine specific. Comparison of model and experimental results shows accurate prediction of in-cylinder peak pressure, IMEP, CA10, and CA50 over a wide operating range. This makes the model suitable for closed-loop combustion control development. However, NO emission prediction has to be improved.
Technical Paper

Automated Model Fit Tool for SCR Control and OBD Development

2009-04-20
2009-01-1285
Reaching EUROVI Heavy Duty emission limits will result in more testing time for developing control and OBD algorithms than to reach EUROV emissions. It is likely that these algorithms have to be adapted for a WHTC (World Heavy Duty Transient Cycle) for EUROVI. This cycle when started cold can only be performed a limited times a day on the engine testbench, because of the cooling down time. The development time and cost increases to reach EUROVI emission levels. Accurate simulation tools can reduce the time and costs by reducing the amount of tests required on the testbench. In order to use simulation tools to develop pre calibrations, the models must be fitted and validated. This paper will focus on the fit process of an SCR (Selective Catalytic Reduction) model. A unique test procedure has been developed to characterize an SCR catalyst using an engine testbench in ±2 days. This data is used in an automatic SCR fit tool to obtain the model parameters in a few days.
Technical Paper

CO2 Neutral Heavy-Duty Engine Concept with RCCI Combustion Using Seaweed-based Fuels

2020-04-14
2020-01-0808
This paper focusses on the application of bioalcohols (ethanol and butanol) derived from seaweed in Heavy-Duty (HD) Compression Ignition (CI) combustion engines. Seaweed-based fuels do not claim land and are not in competition with the food chain. Currently, the application of high octane bioalcohols is limited to Spark Ignition (SI) engines. The Reactivity Controlled Compression Ignition (RCCI) combustion concept allows the use of these low carbon fuels in CI engines which have higher efficiencies associated with them than SI engines. This contributes to the reduction of tailpipe CO2 emissions as required by (future) legislation and reducing fuel consumption, i.e. Total-Cost-of-Ownership (TCO). Furthermore, it opens the HD transport market for these low carbon bioalcohol fuels from a novel sustainable biomass source. In this paper, both the production of seaweed-based fuels and the application of these fuels in CI engines is discussed.
Technical Paper

Catalyst Sulfur Poisoning and Recovery Behaviors: Key for Designing Advanced Emission Control Systems

2017-01-10
2017-26-0133
Advanced emission control systems for diesel engines usually include a combination of Diesel Oxidation Catalyst (DOC), Diesel Particulate Filter (DPF), Selective Catalytic Reduction (SCR), and Ammonia Slip Catalyst (ASC). The performance of these catalysts individually, and of the aftertreatment system overall, is negatively affected by the presence of oxides of sulfur, originating from fuel and lubricant. In this paper, we illustrated some key aspects of sulfur interactions with the most commonly used types of catalysts in advanced aftertreatment systems. In particular, DOC can oxidize SO2 to SO3, collectively referred to as SOx, and store these sulfur containing species. The key functions of a DOC, such as the ability to oxidize NO and HC, are degraded upon SOx poisoning. The impact of sulfur poisoning on the catalytic functions of a DPF is qualitatively similar to DOC.
Technical Paper

Characterization of Criteria and Organic Matter Emissions from a Nonroad Diesel Engine Equipped with a Selective Catalytic Reduction System

2014-10-13
2014-01-2911
More stringent emission requirements for nonroad diesel engines both in the U.S. and Europe have spurred the development of engines and exhaust aftertreatment technologies. In this study, one such system consisting of a diesel oxidation catalyst, zeolite-based selective catalytic reduction catalyst, and an ammonia oxidation catalyst was evaluated using both nonroad transient and steady-state cycles in order to understand the emission characteristics of this configuration. Criteria pollutants were analyzed and particular attention was given to organic compound and NO2 emissions since both of these could be significantly affected by the absence of a diesel particulate filter that typically helps reduce semi-volatile and particle-phase organics and consumes NO2 via passive soot oxidation. Results are then presented on a detailed speciation of organic emissions including alkanes, cycloalkanes, aromatics, polycyclic aromatic hydrocarbons and their derivatives, and hopanes and steranes.
Journal Article

Comparative Study on Various Methods for Measuring Engine Particulate Matter Emissions

2008-06-23
2008-01-1748
Studies have shown that there are a significant number of chemical species present in engine exhaust particulate matter emissions. Additionally, the majority of current world-wide regulatory methods for measuring engine particulate emissions are gravimetrically based. As modern engines considerably reduce particulate mass emissions, these methods become less stable and begin to display higher levels of measurement uncertainty. In this study, a characterization of mass emissions from three heavy-duty diesel engines, with a range of particulate emission levels, was made in order to gain a better understanding of the variability and uncertainty associated with common mass measurement methods, as well as how well these methods compare with each other. Two gravimetric mass measurement methods and a reconstructed mass method were analyzed as part of the present study.
Journal Article

Comparison of Measurement Strategies for Light Absorbing Aerosols from Modern Diesel Engines

2014-04-01
2014-01-1570
Light absorbing components of aerosols, often called black carbon (BC), are emitted from combustion sources and are believed to play a considerable role in direct atmospheric radiative forcing by a number of climate scientists. In addition, it has been shown that BC is associated with adverse health effects in a number of epidemiological studies. Although the optical properties (both absorbing and scattering) of combustion aerosols are needed in order to accurately assess the impact of emissions on radiative forcing, many models use radiative properties of diesel particulate matter that were determined over two decades ago. In response to concerns of the human health impacts of particulate matter (PM), regulatory bodies around the world have significantly tightened PM emission limits for diesel engines. These requirements have resulted in considerable changes in engine technology requiring updated BC measurements from modern engines equipped with aftertreatment systems.
Technical Paper

Control Oriented Engine Model Development for Model-Based PPC Control

2022-03-29
2022-01-0480
A model-based control approach is proposed to give proper reference for the feed-forward combustion control of Partially Pre-mixed Combustion (PPC) engines. The current study presents a simplified first principal model, which has been developed to provide a base estimation of the ignition properties. This model is used to describe the behavior of a single-cylinder heavy-duty diesel engine fueled with a mix of bio-butanol and n-heptane (80vol% bio-butanol and 20 vol% n-heptane). The model has been validated at 8 bar gross Indicated Mean Effective Pressure (gIMEP) in PPC mode. Inlet temperature and pressure have been varied to test the model capabilities. First the experiments were conducted to generate reference points with BH80 under PPC conditions. And then CFD simulations were conducted to give initial parameter set up, e.g. fuel distribution, zone dividing, for the multi-zone model.
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