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The European Commission has released strict emission regulations for passenger cars in the past decade in order to improve air quality in cities and limit harmful emission exposure to humans. In the near future, even stricter regulations containing more realistic/demanding driving scenarios and covering more exhaust gas components are expected to be released. Passenger cars fueled with gasoline are one contributor to unhealthy air conditions, due to the fact that gasoline engines emit harmful air pollutants. One option to minimize harmful emissions would be to utilize specifically tailored, low emission synthetic fuels or fuel blends in internal combustion engines. Methyl formate and dimethyl carbonate are two promising candidates to replace or substitute gasoline, which in previous studies have proven to significantly decrease harmful pollutants.

Photochromism is a reversible color change phenomenon based on chemical reactions caused by light illumination. In the present study, this technique is applied to visualize the lubricating oil and fuel around the piston rings in the gasoline engine. The oil film was colored with a UV laser and photographed by synchronizing the shutter of a high-speed camera with a flashlight. The color density was evaluated as a value of absorbance, calculated from images taken at two different wavelengths and two different times before and after the coloration. The authors performed photochromism visualization experiments in an engine under motored operation. However, using photochromic dyes that are robust to temperature changes makes it possible to visualize the engine under fired operation. The experiment was conducted mainly by switching to the motored operation for a fixed time between the fired operations.