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In a gasoline engine, the unswept in-cylinder residual gas and introduction of external EGR is one of the important means of controlling engine raw NOx emissions and improving part load fuel economy via reduction of pumping losses. Since the trapped in-cylinder Residual Gas Fraction (RGF, comprised of both internal, and external) significantly affects the combustion process, on-line diagnosis and monitoring of in-cylinder RGF is very important to the understanding of the in-cylinder dilution condition. This is critical during the combustion system development testing and calibration processes. However, on-line measurement of in-cylinder RGF is difficult and requires an expensive exhaust gas analyzer, making it impractical for every application. Other existing methods, based on measured intake and exhaust pressures (steady state or dynamic traces) to calculate gas mass flowrate across the cylinder ports, provide a fast and economical solution to this problem.

Accurate accounting for fresh charge (fuel and air) along with trapped RGF is essential for the subsequent thermodynamic analysis of combustion in gasoline engines as well as for on-line and real-time quantification as relevant to engine calibration and control. Cost and complexity of such techniques renders direct measurement of RGF impractical for running engines. In this paper, an empirically-based approach is proposed for on-line RGF, based on an existing semi-empirical model [1]. The model developed expands the range over which the semi-empirical model is valid and further improves its accuracy. The model was rigorously validated against a well correlated GT-POWER model as well as results from 1D gas exchange model [2]. Overall, using this model, RGF estimation error was within ∼1.5% for a wide range of engine operating conditions. The model will be implemented in Dyno development and calibration at Chrysler Group.

This paper reports on DaimlerChrysler's participation in the Ad Hoc Diesel Fuels Test Program. This program was initiated by the U.S. Department of Energy and included major U.S. auto makers, major U.S. oil companies, and the Department of Energy. The purpose of this program was to identify diesel fuels and fuel properties that could facilitate the successful use of compression ignition engines in passenger cars and light-duty trucks in the United States at Tier 2 and LEV II tailpipe emissions standards. This portion of the program focused on minimizing engine-out particulates and NOx by using selected fuels, (not a matrix of fuel properties,) in steady state dynamometer tests on a modern, direct injection, common rail diesel engine.

Diesel vehicles have significant advantages over their gasoline counterparts including a more efficient engine, higher fuel economy, and lower emissions of HC, CO, and CO2. However, NOx control is more difficult on a diesel because of the high O2 concentration in the exhaust, making conventional three-way catalysts ineffective. The most promising technology for continuous NOx reduction onboard diesel vehicles is Selective Catalytic Reduction (SCR) using aqueous urea. Recent work with urea SCR has involved aftertreatment for the 1.2L DIATA common-rail diesel engine. This engine was used in Ford's hybrid-electric vehicle, the Prodigy, which was developed under the PNGV (Partnership for a New Generation of Vehicles) program. An emission control system consisting of a diesel particulate filter followed by an underbody SCR system was used successfully to meet ULEV emission standards (0.2 g/mi NOx, 0.04 g/mi particulate matter (PM)).

Cam-phasing is increasingly considered as a feasible Variable Valve Timing (VVT) technology for production engines. Additional independent control variables in a dual-independent VVT engine increase the complexity of the system, and achieving its full benefit depends critically on devising an optimum control strategy. A traditional approach relying on hardware experiments to generate set-point maps for all independent control variables leads to an exponential increase in the number of required tests and prohibitive cost. Instead, this work formulates the task of defining actuator set-points as an optimization problem. In our previous study, an optimization framework was developed and demonstrated with the objective of maximizing torque at full load. This study extends the technique and uses the optimization framework to minimize fuel consumption of a VVT engine at part load.

Projected NOx and fuel costs are compared for a plasma-catalyst system and an active lean NOx catalyst system. Comparisons are based on modeling of FTP cycle performance. The model uses steady state laboratory device characteristics, combined with measured vehicle exhaust data to predict NOx conversion efficiency and fuel economy penalties. The plasma system uses a proprietary catalyst downstream of a plasma discharge. The active lean NOx catalyst uses a catalyst along with addition of hydrocarbons to the exhaust. For the plasma catalyst system, NOx conversion is available over a wide temperature range. Increased electrical power improves conversion but degrades vehicle fuel economy; 10 J/L energy deposition costs roughly 3% fuel economy. Improved efficiency is also available with larger catalyst size or increased exhaust hydrocarbon content. For the active lean NOx system, NOx conversion is available only in a narrow temperature range.

Previously reported experiments revealed the presence of a small number of clusters or very small particles in the effluent of a nonthermal plasma reactor when treating a simulated engine exhaust mixture. These clusters are smaller than 7 nm. The quantity of clusters is orders of magnitude smaller than the particulate diesel or gasoline engine exhaust typically contains. In this report, we describe further experiments designed to determine the chemical composition of the clusters. Clusters were collected on the surface of a silicon substrate by exposing it to the effluent flow for extended time periods. The resulting deposits were analyzed by high mass resolution SIMS and by XPS. The SIMS analysis reveals NH4+, CH6N+, SO-, SO2-, SO3- and HSO4- ions. XPS reveals the presence of N and S at binding energies consistent with that of ammonium sulfate.

This paper addresses the critical parameters required for development of automotive thermal protection plans. The test conditions should consider the ambient air temperature, exhaust gas temperature, vehicle speed and engine speed. The choice of test conditions is critical in determining potential thermal issues during the development phase. Appropriate design alternatives can then be implemented.

In 1999, the first generation NOx sensor from NGK Spark Plug, Co., Ltd. was commercialized for use in gasoline LNT NOx after-treatment systems [ 1 ]. Since then, as emissions regulations and OBD requirements have become more stringent, the demand for a high-accuracy NOx sensor with fast light-off has increased, particularly for diesel after-treatment systems. To meet such market demands, NGK Spark Plug, Co., Ltd. has developed, in collaboration with Ford Motor Company, a second generation NOx sensor.

A diesel fuel and air diffusion flame burner system has been designed for laboratory simulation of diesel exhaust gas. The system consists of mass flow controllers and a fuel pump, and employs several unique design and construction features. It produces particulate emissions with size, number distribution, and morphology similar to diesel exhaust. At the same time, it generates NOx emissions and HC similar to diesel. The system has been applied to test plasma discharges. Different design discharge devices have been tested, with results indicating the importance of testing devices with soot and moisture. Both packed bed reactor and flat plate dielectric barrier discharge systems remove some soot from the gas, but the designs tested are susceptible to soot fouling and related electrical failures. The burner is simple and stable, and is suitable for development and aging of plasma and catalysts systems in the laboratory environment.

A serpentine flow channel is one of the most common and practical channel layouts for a PEM fuel cell since it ensures the removal of water produced in a cell. While the reactant flows along the flow channel, it can also leak or cross to neighboring channels via the porous gas diffusion layer due to a high pressure gradient. Such a cross flow leads to effective water removal in a gas diffusion layer thus enlarging the active area for reaction although this cross flow has largely been ignored in previous studies. In this study, neutron radiography is applied to investigate the liquid water accumulation and its effect on the performance of a PEM fuel cell. Liquid water tends to accumulate in the gas diffusion layer adjacent to the flow channel area while the liquid water formed in the gas diffusion layer next to the channel land area seems to be effectively removed by the cross leakage flow between the adjacent flow channels.

A planar dielectric barrier discharge device has been tested for exhaust emission reduction in simulated engine exhaust. This device's electrical characteristics have been measured and are presented in this paper. The device consists of two dielectric barriers which act like series capacitors, with the gas gap between them. At low gap voltages, the gas gap also acts like a capacitance, with a much smaller capacitance than the barriers. At higher voltages, the gas gap breaks down and a blue–purple glow visually fills the gap. The partially ionized gas conducts charge across the gap, building electrical charge on the dielectric barrier inner surface. When the AC excitation voltage peaks and starts to go toward an opposite polarity, the discharge momentarily extinguishes, trapping charge in the dielectric barrier capacitance.

Traditionally, vehicle emission testing has used non-intelligent analyzers to meet government-regulated standards. Typically, these instruments would provide a 0 to 5-volt signal to a central test cell computer which would then handle all calibrations including analyzer linearization, zero and span corrections, stability checks, time delays, and sample readings. Modern gas analyzers now contain intelligence within each individual analyzer; this has caused the calibration methods to change dramatically. New methods were developed in the bench control system to take advantage of the intelligence of the analyzers by creating a distributed control architecture. The zeroing, spanning, and linearization methods are quite different from the previous protocols. The results, however, will provide more accurate reading to be used in calculating vehicle emissions.

Nonthermal plasma discharges in combination with catalysts are being developed for diesel aftertreatment. NOx conversion has been shown over several different catalyst materials. Particulate removal has also been demonstrated. The gas phase chemistry of the plasma discharge is described. The plasma is oxidative. NO is converted to NO2, CH3ONO2 and HNO3. Hydrocarbons are partially oxidized resulting in aldehydes and CO along with various organic species. Soot will oxidize if it is held in the plasma. When HC is present, SO2 is not converted to sulfates. Suitable plasma-catalysts can achieve NOx conversion over 70%, with a wider effective temperature range than non-plasma catalysts. NOx conversion requires HC and O2. Electrical power consumption and required exhaust HC levels increase fuel consumption by several percent. A plasma catalyst system has demonstrated over 90% particulate removal in vehicle exhaust.

The existence of the cyclic variation of the flow inside an cylinder affects the performance of the engine. Developing methods to understand and control in-cylinder flow has been a goal of engine designers for nearly 100 years. In this paper, passive control of the intake flow of a 3.5-liter DaimlerChrysler engine was examined using a unique optical diagnostic technique: Molecular Tagging Velocimetry (MTV), which has been developed at Michigan State University. Probability density functions (PDFs) of the normalized circulation are calculated from instantaneous planar velocity measurements to quantify gas motion within a cylinder. Emphasis of this work is examination of methods that quantify the cyclic variability of the flow. In addition, the turbulent kinetic energy (TKE) of the flow on the tumble and swirl plane is calculated and compared to the PDF circulation results.

Ford Motor Company is participating in the Department of Energy's (DOE) Ultra-Clean Transportation Fuels Program with the goal to explore the development of innovative emission control systems for advanced compression-ignition direct-injection (CIDI) transportation engines. CIDI (or diesel) engines have the advantages of a potential 40% fuel economy improvement and 20% less CO2 emissions than current gasoline counterparts. To support this goal, Ford plans to demonstrate an exhaust emission control system that provides high efficiency particulate matter (PM) and NOx reduction. Very low sulfur diesel fuel will be used to enable low PM emissions, reduce the fuel economy penalty associated with the emission control system, and increase the long-term durability of the system. The end result will allow vehicles with CIDI engines to be Tier II emissions certified at a minimum cost to the consumer.