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Striving for sustainable transportation solutions, hydrogen is often identified as a promising energy carrier and internal combustion engines are seen as a cost effective consumer of hydrogen to facilitate the development of a large-scale hydrogen infrastructure. Driven by efficiency and emissions targets defined by the U.S. Department of Energy, a research team at Argonne National Laboratory has worked on optimizing a spark-ignited direct injection engine for hydrogen. Using direct injection improves volumetric efficiency and provides the opportunity to properly stratify the fuel-air mixture in-cylinder. Collaborative 3D-CFD and experimental efforts have focused on optimizing the mixture stratification and have demonstrated the potential for high engine efficiency with low NOx emissions. Performance of the hydrogen engine is evaluated in this paper over a speed range from 1000 to 3000 RPM and a load range from 1.7 to 14.3 bar BMEP.

The objective of the research into modeling and simulation was to provide an improvement to the Wayne State EcoCAR 2 team’s math-based modeling and simulation tools for hybrid electric vehicle powertrain analysis, with a goal of improving the simulation results to be less than 10% error to experimental data. The team used the modeling and simulation tools for evaluating different outcomes based on hybrid powertrain architecture changes (hardware), and controls code development and testing (software). The first step was model validation to experimental data, as the plant models had not yet been validated. This paper includes the results of the team’s work in the U.S. Department of Energy’s EcoCAR 2 Advanced vehicle Technical Competition for university student teams to create and test a plug-in hybrid electric vehicle for reducing petroleum oil consumption, pollutant emissions, and Green House Gas (GHG) emissions.

Use of ethanol as gasoline replacement can contribute to the reduction of nitrogen oxide (NOx) and carbon oxide (CO) emissions. Depending on ethanol production, significant reduction of greenhouse-gas emissions is possible. Concentration of certain species, such as unburned ethanol and acetaldehyde in the engine-out emissions are known to rise when ratio of ethanol to gasoline increases in the fuel. This research explores on hydrous ethanol fueled port-fuel injection (PFI) spark ignition (SI) engine emissions that contribute to photochemical formation of ozone, or so-called ozone precursors and the precursor of peroxyacetyl nitrates (PANs). The results are compared to engine operation on gasoline. Concentration obtained by FTIR gas analyzer, and mass-specific emissions of formaldehyde (HCHO), acetaldehyde (MeCHO) and methane (CH4) under two engine speed, four load and two spark advance settings are analyzed and presented.

With an intention to improve the performance of reciprocating engines used for distributed generation US-Dept. of Energy has launched ARES program. Under this program, the performance targets for these natural gas-fuelled stationary engines are ≻ 50% efficiency and NOx emissions ≺ 0.1 g/bhp-hr by 2013. This paper presents two technologies developed under this program. Lean-burn operation is very popular with engine manufacturers as it offers simultaneous low-NOx emissions and high engine efficiencies, while not requiring the use of any aftertreatment devices. Though engines operating on lean-burn operation are capable of better performance, they are currently limited by the inability to sustain reliable ignition under lean conditions. Addressing such an issue, research has evaluated the use of laser ignition as an alternative to the conventional Capacitance Discharge Ignition (CDI).

The 2001 FutureTruck competition involved 15 universities from across North America that were invited to apply a wide range of advanced technologies to improve energy efficiency and reduce greenhouse gas impact while producing near-zero regulated exhaust emissions in a 2000 Chevrolet Suburban. The modified vehicles designated as FutureTrucks demonstrated improvements in greenhouse gas emissions, tailpipe emissions, and over-the-road fuel economy compared with the stock vehicle on which they were based. The technologies represented in the vehicles included ICE-engines and fuel cell hybrid electric vehicle propulsion systems, a range of conventional and alternative fuels, advanced exhaust emissions controls, and light weighting technologies.

In June of 2002, 15 universities participated in the third year of FutureTruck, an advanced vehicle competition sponsored by the U.S. Department of Energy and Ford Motor Company. Using advanced technologies, teams strived to improve vehicle energy efficiency by at least 25%, reduce tailpipe emissions to ULEV levels, and lower greenhouse gas impact of a 2002 Ford Explorer. The competition vehicles were tested for dynamic performance and emissions and were judged in static events to evaluate the design and features of the vehicle. The dynamic events include braking, acceleration, handling, and fuel economy, while the dynamometer testing provided data for both the emissions event and the greenhouse gas event. The vehicles were scored for their performance in each event relative to each other; those scores were summed to determine the winner of the competition. The competition structure included different available fuels and encouraged the use of hybrid electric drivetrains.

The current paper describes a methodology for combustion bowl assessment for diesel engines. The methodology is based on the application of Computational Fluid Dynamics (CFD) following a Design of Experiments (DoE) procedure. In this work the 3D CFD simulation was performed by the commercial CFD code AVL-FIRE for different combustion bowls from intake valve closing (IVC) to exhaust valve opening (EVO). The initial conditions (at IVC) and boundary conditions were obtained from 1D simulation. Since the work was concentrated on the spray injection, mixing, combustion as well as bowl aerodynamics only a sector mesh was employed for the calculations. A DoE procedure was also used for this simulation work in order to minimize the number of simulation runs and at the same time maintaining the accuracy required assessing the influences of different bowl geometry, spray and intake air motion parameters.

This paper analyzes four recent major studies carried out by MIT, a GM-led team, Directed Technologies, Inc., and A. D. Little, Inc. to assess advanced technology vehicles. These analyses appear to differ greatly concerning their perception of the energy benefits of advanced technology vehicles, leading to great uncertainties in estimating full-fuel-cycle (or “well-to-wheel”) greenhouse gas (GHG) emission reduction potentials and/or fuel feedstock requirements per mile of service. Advanced vehicles include, but are not limited to, advanced gasoline and diesel internal combustion engine (ICE) vehicles, hybrid electric vehicles (HEVs) with gasoline, diesel, and compressed natural gas (CNG) ICEs, and various kinds of fuel-cell based vehicles (FCVs), such as direct hydrogen FCVs and gasoline or methanol fuel-based FCVs.

This paper analyzes fuel economy benefits of direct hydrogen and gasoline reformer fuel cell vehicles, with special focus on cold-start impacts on these fuel cell based vehicles. Comparing several existing influential studies reveals that the most probable estimates from these studies differ greatly on the implied benefits of both types of fuel cell vehicles at the tank-to-wheel level (vehicle-powertrain efficiency and/or specific power), leading to great uncertainties in estimating well-to-wheel fuel energy and/or greenhouse gas (GHG) emission reduction potentials. This paper first addresses methodological issues to influence the outcome of these analyses. With one exception, we find that these studies consistently ignore cold-start and warm-up issues, which play important roles in determining both energy penalties and start-up time of fuel cell vehicles. To better understand cold-start and warm-up behavior, this paper examines approaches and results based on two available U.S.

The U.S. Renewable Fuel Standard (RFS2) requires an increase in the use of advanced biofuels up to 36 billion gallons by 2022. Longer chain alcohols, in addition to cellulosic ethanol and synthetic biofuels, could be used to meet this demand while adhering to the RFS2 corn-based ethanol limitation. Higher carbon number alcohols can be utilized to improve the energy content, knock resistance, and/or petroleum displacement of gasoline-alcohol blends compared to traditional ethanol blends such as E10 while maintaining desired and regulated fuel properties. Part I of this paper focuses on the development of scenarios by which to compare higher alcohol fuel blends to traditional ethanol blends. It also details the implementation of fuel property prediction methods adapted from literature. Possible combinations of eight alcohols mixed with a gasoline blendstock were calculated and the properties of the theoretical fuel blends were predicted.

Higher carbon number alcohols offer an opportunity to meet the Renewable Fuel Standard (RFS2) and improve the energy content, petroleum displacement, and/or knock resistance of gasoline-alcohol blends from traditional ethanol blends such as E10 while maintaining desired and regulated fuel properties. Part II of this paper builds upon the alcohol selection, fuel implementation scenarios, criteria target values, and property prediction methodologies detailed in Part I. For each scenario, optimization schemes include maximizing energy content, knock resistance, or petroleum displacement. Optimum blend composition is very sensitive to energy content, knock resistance, vapor pressure, and oxygen content criteria target values. Iso-propanol is favored in both scenarios' suitable blends because of its high RON value.

Emissions from CI engines fueled with dimethyl ether (DME) were discussed in this paper. Thanks to its high content of fuel oxygen, DME combustion is virtually soot free. This characteristic of DME combustion indicates that the particulate filter will not be needed in the aftertreatment system for engines fueled with DME. NOx emissions from a CI engine fueled with DME can meet the US 2007 regulation with a high EGR rate. Because 49% more fuel mass must be delivered in each DME injection than the corresponding diesel-fuel injection, and the DME injection pressure is lower than 500 bar under the current fuel-system technology, the DME injection duration is generally longer than that of diesel-fuel injection. This is unfavorable to further NOx reduction. A multiple-injection strategy with timing for the primary injection determined by the cylinder temperature was proposed.

Preliminary research in our laboratory has demonstrated that boric acid is an effective lubricant with an unusual capacity to reduce the sliding friction (providing friction coefficients as low as 0.02) and wear of metallic and ceramic materials. More recent studies have revealed that water or methanol solutions of boric acid can be used to prepare strongly bonded layers of boric acid on aluminum surfaces. It appears that boric acid molecules have a strong tendency to bond chemically to the naturally oxidized surfaces of aluminum and its alloys and to make these surfaces very slippery. Recent metal-formability tests indicated that the boric acid films applied to aluminum surfaces worked quite well, improving draw scale performance by 58 to 75%.

The CFR F1 engine is the standard testing apparatus used for rating the research octane number (RON) of gasoline fuels. Unlike the motor octane number (MON) method, where the intake port temperature after the carburetor is controlled by an electric heater, the mixture temperature can vary during the RON test due to the heat of vaporization (HoV) of the fuel. Ethanol is receiving increasing attention as a high octane and high HoV fuel component. This work presents an analysis of the combustion characteristics during the RON rating of ethanol fuel blends according to the standard ASTM D2699 method, highlighting the effects of ethanol concentration and base fuel composition. All fuels were blended to a constant RON of 98. Ethanol levels varied from 0 to 50 vol% and the base fuels were surrogate blends composed of primary reference fuels (PRF), toluene standardization fuels (TSF), and a four component gasoline surrogate.

Because of their high efficiency and low emissions, fuel-cell vehicles are undergoing extensive research and development. When considering the introduction of advanced vehicles, a complete well-to-wheel evaluation must be performed to determine the potential impact of a technology on carbon dioxide and Green House Gases (GHGs) emissions. Several modeling tools developed by Argonne National Laboratory (ANL) were used to evaluate the impact of advanced powertrain configurations. The Powertrain System Analysis Toolkit (PSAT) transient vehicle simulation software was used with a variety of fuel cell system models derived from the General Computational Toolkit (GCtool) for pump-to-wheel (PTW) analysis, and GREET (Green house gases, Regulated Emissions and Energy use in Transportation) was used for well-to-pump (WTP) analysis. This paper compares advanced propulsion technologies on a well-to-wheel energy basis by using current technology for conventional, hybrid and fuel cell technologies.

SunDiesel fuel is a biomass-to-liquid (BTL) fuel that may have certain attributes different from conventional diesel. In this investigation, 100% SunDiesel was tested both in a Mercedes A-Class (MY1999) diesel vehicle and a single-cylinder heavy-duty compression-ignition direct-injection engine. The SunDiesel's emissions and fuel consumption were significantly better than conventional diesel fuel, especially in nitrogen oxides (NOx) reduction. In the vehicle U.S. Environmental Protection Agency (EPA), Federal Test Procedure 75 (FTP-75), and New European Drive Cycle (NEDC) tests, the carbon dioxide emissions on a mile basis (g/mile) from SunDiesel fuel were almost 10% lower than the conventional diesel fuel. Similarly, in the single-cylinder engine steady-state tests, the reductions in brake specific NOx, carbon monoxide (CO), and particulate matter (PM) are equally significant. Combustion analysis, though not conclusive, indicates that there are differences deserving further research.

To properly compare and contrast the environmental performance of one vehicle technology against another, it is necessary to consider their production, operation, and end-of-life fates. Since 1995, Argonne’s GREET® life cycle analysis model (Greenhouse gases, Regulated Emissions, and Energy use in Technologies) has been annually updated to model and refine the latest developments in fuels and materials production, as well as vehicle operational and composition characteristics. Updated cradle-to-grave life cycle analysis results from the model’s latest release are described for a wide variety of fuel and powertrain options for U.S. light-duty and medium/heavy-duty vehicles. Light-duty vehicles include a passenger car, sports utility vehicle (SUV), and pick-up truck, while medium/heavy-duty vehicles include a Class 6 pickup-and-delivery truck, Class 8 day-cab (regional) truck, and Class 8 sleeper-cab (long-haul) truck.

The Center for Transportation Research (CTR) Vehicle Systems team modified a Nissan CK-2 Continuously Variable Transmission (CVT) for a diesel hybrid powertrain application. Mechanical and electrical modifications were made to the CVT, both internal and external to the transmission. The goal of this experiment was to investigate and demonstrate the potential of CVT for diesel engines hybrid electric vehicles (HEVs) in fuel economy and emissions. The test set-up consisted of a diesel engine coupled to an electric motor driving a Continuously Variable Transmission (CVT). This hybrid drive is connected to a dynamometer and a DC electrical power source creating a vehicle context by combining advanced computer models and emulation techniques. The experiment focuses on the impact particular transmission control strategies have on measured fuel economy and emissions specifically, nitrogen oxides (NOx) and particulate matter (PM).

The correlations between the physical properties and autoignition parameters of several alternate fuels have been examined. The fuels are DF-2 and its blends with petroleum derived fuels, coal derived fuels, shale derived fuels, high aromatic naphtha sun-flower oils, methanol and ethanol. A total of eighteen existing correlations are discussed. An emphasis is made on the suitability of each of the correlations for the development of electronic controls for diesel engines when run on alternate fuels. A new correlation has been developed between the cetane number of the fuels and its kinematic viscosity and specific gravity.

A heavy-duty vehicle (HDV) module of the Greenhouse gases, Regulated Emissions, and Energy use in Transportation (GREETTM) model has been developed at Argonne National Laboratory. The fuel-cycle GREET model has been published extensively and contains data on fuel-cycles and vehicle operation of light-duty vehicles. The addition of the HDV module to the GREET model allows for well-to-wheel (WTW) analyses of heavy-duty advanced technology and alternative fuel vehicles (AFVs), which has been lacking in the literature. WTW analyses of HDVs becomes increasingly important to understand the fuel consumption and greenhouse gas (GHG) emissions impacts of newly enacted and future HDV regulations from the Environmental Protection Agency and the Department of Transportation’s National Highway Traffic Safety Administration.