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The efficiency of the NOx Storage and Reduction (NSR) catalysts used in the aftertreatment of diesel engine exhaust gases can potentially be increased by using reactive reductants such as CO and H₂ that are formed during in-cylinder combustion. In this study, a multi-dimensional computational fluid dynamics (CFD) code coupled with complex chemical analysis was used to study combustion with various fuel after-injection patterns. The results obtained will be useful in designing fuel injection strategies for the efficient formation of CO.

In order to correspond to the exhaust emissions regulations that become severe every year, more advanced engine control becomes necessary. Engine engineers are concerned about the Hydrocarbons (HCs) that flow through the air-intake ports and that are difficult to precisely control. The main sources of the HCs are, the canister purge, PCV, back-flow gas through the intake valves, and Air / Fuel ratio (A/F) may be aggravated when they flow into the combustion chambers. The influences HCs give on the A/F may also grow even greater, which is due to the increasingly stringent EVAP emission regulations, by more effective ventilation in the crankcase, and also by the growth of the VVT-operated angle and timing, respectively. In order to control the A/F more correctly, it is important to estimate the amount of HCs that are difficult to manage, and seek for suitable controls over fuel injection and so on.

Non-equilibrium all-atom MD simulations are used to study the traction properties of hydrocarbon fluids. A fluid layer is confined between two solid Fe plates under the constant normal force of 1.0 GPa. Traction simulations are performed by applying a relative sliding motion to the Fe plates. Shear behaviors of nine hydrocarbon fluids are simulated on a sufficiently large film thickness of 6.7 nm, and succeeded in reproducing the order of the experimental traction coefficients. The dynamic mechanism of the momentum transfer on layers of fluid molecules are analyzed focusing on the intermolecular interactions (density profile, orientation factor, pair-correlation function) and intramolecular interactions (intramolecular interaction energy, conformation change of alicyclic ring). In contrast to the case of n-hexane, which shows low traction due to a fragile chain-like interaction, other mechanisms are obtained in the high traction molecules of cyclohexane, dicyclohexyl and santotrac 50.

The particle number (PN) emission regulation has been implemented since 2011 in Europe. PN measurement procedure defined in ECE regulation No. 83 requires detecting only solid particles by eliminating volatile particles, the concentrations of which are highly influenced by dilution conditions, using a volatile particle remover (VPR). To measure PN concentration after the VPR, a particle number counter (PNC) which has detection threshold at a particle size of 23 nm is used, because most solid particles generated by automotive engines are considered to be larger than 23 nm. On the other hand, several studies have reported the existence of solid and volatile particles smaller than 23 nm in engine exhaust. This paper describes investigation into a measurement method for ultrafine PNCs with thresholds of below 23 nm and evaluation of the VPR performance for the particles in this size range. The detection efficiency of an ultrafine PNC was verified by following the ECE regulation procedure.

Recently, the role of ECU(Electronic Control Unit) on vehicles has been becoming more important year by year in order to meet the requirements for safety and the environmental matters. Particularly, the ECU of Engine Management Systems has been becoming indispensable in order to realize high performance, low fuel consumption and low exhaust emission. Therefore, the size of software has also been increasing, and been becoming more complex and complicated. As the ECU software size becomes large and complex, the verification and validation of the software by using the current development method has been becoming more difficult. Especially it has been becoming more difficult to validate the Real-time property of the software. The Real-time property means whether the execution of the software is in time for the deadline which is decided on the software design.

The characteristics of exhausted smoke of a methanol DI diesel engine which is ignited by diesel fuel are investigated to clarify the soot formation process. At this engine, very little smoke is exhausted when diesel fuel is kept below a certain amount, so soot and smoke emitting characteristics are studied under the various diesel fuel amounts. By analyzing microstructure of soot, it is found that the soot emitted from the methanol diesel engine is composed of inner core and outer shell, similar to that of the conventional diesel engines. From more detailed qualitative analysis, the calcium percentage from the lubricating oil in outer shell is much higher than that of the conventional diesel engines. In consideration of soot characteristics, spray structure and combustion characteristics, the soot formation process of the methanol diesel engine was clarified.

The effects of multiple-injection on exhaust emissions and performance in a small HSDI (High Speed Direct Injection) Diesel engine were examined. The causes for the improvement were investigated using both in-cylinder observation and three-dimensional numerical analysis methods. It is possible to increase the maximum torque, which is limited by the exhaust smoke number, while decreasing the combustion noise under low speed and full load conditions by advancing the timing of the pilot injection. Dividing this early-timed pilot injection into two with a small fuel amount is effective for further decreasing the noise while suppressing the increase in HC emission and fuel consumption. This is realized by the reduced amount of adhered fuel to the cylinder wall. At light loads, the amount of pilot injection fuel must be reduced, and the injection must be timed just prior to the main injection in order to suppress a possible increase in smoke and HC.

From the viewpoint of the global warming restraint, reduction of exhaust emissions from diesel engine is urgent demand. However, it needs further development in combustion control besides after treatment system. Larger amount of EGR (Exhaust Gas Recirculation) is effective to reduce NOx emission. On the other hand, in-cylinder physical conditions greatly influence on self-ignition and combustion process, especially low O2 fraction charged gas owing to excessive EGR causes misfire. A drastic solution for this problem, fuel injection timing should be optimally manipulated based on predicted ignition delay period before actual injection. For this purpose, Toyota has developed a model based diesel combustion control concept to avoid the misfire and to keep low emission combustion includes in transient condition.

A newly-developed time resolved exhaust gas analysis system was utilized in this study. The hydrocarbon compositions upstream and downstream of the catalytic converter were investigated during cold start and warm up of the Federal Test Procedure(FTP), with three fuels of different aromatic contents. Although engine-out hydrocarbon emissions had high concentrations right after cold start, the specific reactivity was low. This can be explained by the selective adsorption of the high boiling point components which had a high Maximum Incremental Reactivity (MIR) in the intake manifold and engine-oil films. Thereafter, the high boiling point components were desorbed rapidly and consequently specific reactivity increased. Hydrocarbon adsorption of high boiling point components and hydrocarbon conversion of low boiling point components occurred simultaneously on the catalyst during warm up.

Our two types of NOx storage-reduction (NSR) catalyst have been tested under various conditions of thermal endurance; the performance of these catalysts have been regressed to give the formulas that enable to estimate the performance after thermal endurance; and we have found the method to simplify (shorten the duration of) the thermal endurance tests and that the thermal deterioration of NSR catalysts is controlled by the worst condition of endurance (at least approximately). The regression formula for the amount of potassium that contributes to the catalyst performance (active K) after the endurance has also been obtained. These formulas predict that the amount of active K is the least for the worst condition of endurance and suggest a difference in deterioration mechanism that reflects the performance between low and high temperatures and the portion of worse deterioration (front or rear).

NO2 sources of roadside atmosphere at Matsubarabashi monitoring station in Tokyo were investigated analytically. The result showed that contribution of urban background is dominant from November to February and NO oxidation with O3 has large contribution from April to September. NO2 air quality standard will be achieved by reducing vehicle NOx emission to post-new long-term regulation level. The analytical method was verified by using our developed simulation system, which consists of micro traffic flow analyzer and CFD-based, unsteady-state diffusion with chemical reaction solver.

By using analytical techniques (FT-IR, TG-MS, ICP) and DFT calculations, the potassium (K) used as a storage component in NOx Catalysts can be analyzed. The results from this study show that the, K exists as K2CO3, and that the amount, molecular structure, and thermal stability of K2CO3 are different, depending on the support material (ZrO2, Al2O3, or TiO2). If the amount of K that interacts with the support to form an inactive complex oxide is decreased, the amount of K2CO3 and NOx storage is increased. The amount of the inactive K varies with the basicity of the supports. K2CO3 that exists in unstable structures on the supports can be easy to react with NOx to form the nitrate. So, the higher the quantity of unstable K2CO3, the higher the NOx storage capacity. Based on these results, a development guideline was proposed to improve the NOx storage performance.

Diesel particulate and NOx reduction system (DPNR) is an effective technology for the diesel after-treatment system, which can reduce particulate matter (PM) and nitrogen oxides (NOx) simultaneously. Further improvement of the DPNR is expected for cleaner air in the future. The catalyst for the DPNR (called DPNR catalyst) consists of a NOx Storage Reduction (NSR) catalyst coated onto a Diesel Particulate Filter (DPF). The development of the DPNR catalyst for the decrease of exhaust weight has been considered before now with respect to the PM combustion. But it will be necessary to focus on PM particle number emissions in the future. In this study, the relationship between the pore structure of the DPNR catalyst and the trapping of PM to lower particle number was clarified by evaluating a high-porosity, large-pore cordierite DPF with an average pore size of 20 μm or greater. Furthermore, the optimal pore structure to trap PM particles in a highly effective manner was discussed.

It has been reported that the middle range of gasoline distillation temperatures strongly affects vehicle driveability and exhaust hydrocarbon (HC) emissions, and that MTBE(CH3-O-C4H9)- blended gasoline causes poor driveability during warm-up. The present paper is concerned with the results of subsequent detailed research on gasoline characteristics, exhaust emissions and driveability. In this paper, first it is demonstrated by using four models of passenger cars having different types of exhaust gas treatment system that decreased 50% distillation temperature (T50) reduces exhaust HC emission. This result indicates lowering T50 in the market will contribute to improving air quality. Secondly gasoline behavior in the intake manifold is investigated by using an engine on the dynamometer in order to clarify the mechanisms of HC emission increase and poor engine response which are caused by high T50.

This report describes the implementation of the spark channel short circuit and blow-out submodels, which were described in the previous report, into a spark ignition model. The spark channel which is modeled by a particle series is elongated by moving individual spark particles along local gas flows. The equation of the spark channel resistance developed by Kim et al. is modified in order to describe the behavior of the current and the voltage in high flow velocity conditions and implemented into the electrical circuit model of the electrical inductive system of the spark plug. Input parameters of the circuit model are the following: initial discharge energy, inductance, internal resistance and capacitance of the spark plug, and the spark channel length obtained by the spark channel model. The instantaneous discharge current and the voltage are obtained as outputs of the circuit model.

Since the regulations of CO2 emissions have been tightened in each country recently, each automotive manufacturer has responded by bringing competitive technologies that maximize efficiency while promoting vehicle electrification such as xEV. Not only the efficiency, we need to meet or exceed occupant performance and comfort expectations. The climate control system expends a large amount of energy to keep a comfortable environment, having a significant impact on fuel consumption and EV driving range. Therefore, many manufacturers try to save energy and improve occupant comfort quickly by using not only the conventional convective heating by HVAC but also the conductive heating to heat the human body directly such as seat and steering wheel heater. In this study, a radiative heater, which is more efficient than a convective heating to warm anterior thigh and shin where a conductive heating cannot warm, was applied to vehicle.

To meet future stringent emission regulations such as Euro6, the design and control of diesel exhaust after-treatment systems will become more complex in order to ensure their optimum operation over time. Moreover, because of the strong pressure for CO₂ emissions reduction, the average exhaust temperature is expected to decrease, posing significant challenges on exhaust after-treatment. Diesel Oxidation Catalysts (DOCs) are already widely used to reduce CO and hydrocarbons (HC) from diesel engine emissions. In addition, DOC is also used to control the NO₂/NOx ratio and to generate the exothermic reactions necessary for the thermal regeneration of Diesel Particulate Filter (DPF) and NOx Storage and Reduction catalysts (NSR). The expected temperature decrease of diesel exhaust will adversely affect the CO and unburned hydrocarbons (UHC) conversion efficiency of the catalysts. Therefore, the development cost for the design and control of new DOCs is increasing.

The authors have developed an instrument that measures the CO2 concentration in engine combustion chambers using the infrared absorption method. The characteristics of this technology are as follows: 1 Measuring can be carried out while the engine is running at 600r/min to more than 3000r/min, full load operation. (Applicable to all EGR conditions) 2 Quick response; 2ms 3 High linearity; ±1% Full Scale and under (FS: 10%) 4 No aggravation is caused to the intake/exhaust performance of engines This technology contributes to the improvement of the in-cylinder EGR system using, for instance, a variable valve-timing mechanism that is now expanding in number of applications, and also the conventional EGR system.

The effects of intake dilution with various dilution gases including nitrogen, argon, and carbon dioxide on low temperature diesel combustion were investigated in a naturally aspirated DI diesel engine to understand the mechanism of the simultaneous reductions in smoke and NOx with ultra-high EGR. NOx almost completely disappears with the intake oxygen concentration diluted below 16% regardless of the kind of dilution gas. Smoke emissions decrease with increased heat capacity of the charged gas due to promotion of mixture homogeneity with longer ignition delays. Intake dilution with the 36% CO2 + 64% Ar mixture which has a similar specific heat capacity as N2 shows lower smoke emissions than with N2. Chemical kinetics analysis shows that carbon dioxide may help to reduce NOx and soot by lowering the reaction temperature as well as by changing the concentrations of some radicals or/and species related to soot and NOx formation.

Means for reducing the particulate matter (PM) from swirl chamber type diesel engines were searched out, and the reducing mechanisms were examined using an optically accessible engine. The following points were clarified in this study. 1. At light load, the suppression of the initial injection rate reduces PM, because SOF is reduced by the change in ignition point and smoke is reduced by the retarded flowout of the dense soot from the swirl chamber 2. Under medium and high load conditions, the main cause of the exhaust smoke is fierce spray-wall impingement which leads to fuel adhesion on the wall and the stagnation of a rich fuel-air mixture. 3. Enlarging swirl chamber volume ratio suppresses the formation of dense soot in the swirl chamber. In the main chamber, however, the soot oxidization becomes insufficient due to the mixing effect reduced by the essentially decreased chamber depth. 4.