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Our concern was with the phenomenon of the fuel flow rate change in the injector due to deposit formation in the direct injection gasoline engine. The fundamental factors in the deposit formation on the nozzle were investigated, and engine dynamometer tests were performed. It was clarified that the residual fuel in the nozzle hole should be kept in a liquid state so that deposit precursors could be washed away by fuel injections. As a consequence, the nozzle temperature had to be below the 90 vol. % distillation temperature of the fuel, which was the most important index to suppress the deposit formation.

Over the last few decades, in-cylinder visualization using optically accessible engines has been an important tool in the detailed analysis of the in-cylinder phenomena of internal combustion engines. However, most current optically accessible engines are recognized as being limited in terms of their speed and load, because of the fragility of certain components such as the elongated pistons and transparent windows. To overcome these speed and load limits, we developed a new generation of optically accessible engines which extends the operating range up to speeds of 6000 rpm for the SI engine version, and up to in-cylinder pressures of 20 MPa for the CI engine version. The main reason for the speed limitation is the vibration caused by the inertia force arising from the heavy elongated piston, which increases with the square of the engine speed.

Methyl esters of saturated/unsaturated higher aliphatic acids (FAMEs) and a FAME of waste cooking oil (WCOME) were heated at 120°C in an air gas flow. The samples were analyzed before and after heating, using six different methods including electrospray ionization mass spectrometry. As a result, the samples after heating were found to contain low molecular weight aliphatic compounds and oligomers of the FAME. Based on the chemical structure of these oxidation products, reaction schemes were proposed for the deterioration of FAMEs. In addition, two unsaturated FAMEs containing 2,6-di-t-butyl-p-cresol (BHT) were similarly heated and analyzed to examine the effect of BHT on the oxidation of these FAME.

The effect of GTL diesel fuel on organic materials used in fuel delivery systems of vehicles was investigated. Specimens made from 16 kinds of organic materials were immersed in GTL diesel fuels synthesized at Refinery-A and Refinery-B (referred to as GTL-A and GTL-B, respectively) and then subjected to tensile testing. The tensile test results revealed that elongation of the nylon sample immersed in GTL-A was extremely small, about 4% of that of untreated nylon. In the light of this finding, the GTL diesel fuels and nylons before and after immersion test were analyzed in detail using about 20 analysis methods to determine the cause for poor elongation. The following points were found. (1) GTL-A consisted of low molecular-weight paraffins. (2) GTL-A had low molecular-weight i-paraffins. (3) The nylon immersed in GTL-A contained low molecular-weight paraffins. (4) The paraffins in the nylon immersed in GTL-A were richer in i-paraffins than the original GTL-A.

Toyota participated in Formula One1 (F1) Racing from 2002 to 2009. As a result of the downturn in the world economy, various engine developments within F1 were restricted in order to reduce the cost of competing in F1. The limit on the maximum number of engines allowed has decreased year by year. Toyota focused on the engine performance deterioration due to the combustion chamber deposits. In 2009, Toyota was successful in reducing around 40% of the deterioration by making combustion chamber cleaner in cooperation with ExxonMobil. This contributed to good result of 2009 F1 season for Toyota, including two second place finishes.

The cause of the exhaust smoke and its reduction methods in a small DI Diesel engine with a small-orifice-diameter nozzle and common rail F.I.E. were investigated under high-speed and high-load condition, using both in-cylinder observations and Three-dimensional numerical analyses. The following points were clarified during this study. At these conditions, fuel sprays are easily pushed away by a strong swirl, and immediately flow out to the squish area by a strong reverse squish. Therefore, the air in the cavity is not effectively used. Suppressing the airflow in a piston cavity, using such ideas as enlarging the piston cavity diameter or reducing the port swirl ratio, decreases the excessive outflow of the fuel-air mixture into the squish area, and allows the full use of air in the whole cavity. Hence, exhaust smoke is reduced.

In diesel engines with a straight intake port and a lipless cavity to restrict in-cylinder flow, an injector with numerous small-diameter orifices with a narrow angle can be used to create a highly homogeneous air-fuel mixture that, during PCCI combustion, dramatically reduces the NOX and soot without the addition of expensive new devices. To further improve this new combustion concept, this research focused on cooling losses, which are generally thought to account for 16 to 35% of the total energy of the fuel, and approaches to reducing fuel consumption were explored. First, to clarify the proportions of convective heat transfer and radiation in the cooling losses, a Rapid Compression Machine (RCM) was used to measure the local heat flux and radiation to the combustion chamber wall. The results showed that though larger amounts of injected fuel increased the proportion of heat losses from radiation, the primary factor in cooling losses is convective heat transfer.

We have developed a high capacity electromagnetic clutch by means of Si-containing diamond-like carbon (DLC-Si) coating. The durability of the new clutch is enhanced up to 8 times higher than that of the conventional one. Such a superior performance is due to several tribological properties of the DLC-Si film and micro morphology on the clutch surface. In particular, the DLC-Si plays a significant role in maintaining the groove shape of the clutch and giving sufficient friction in fluid, which is required for a drivetrain device. Besides, our deposition process (using direct current plasma-assisted chemical vapor deposition) has afforded homogeneous DLC-Si-coated clutches in large quantities. These techniques have enabled us to reduce the number of clutch discs per coupling and achieve a more compact and higher capacity AWD coupling at a lower cost.

In conventional gasoline engine vehicles, three-way catalysts are used to simultaneously remove HC, CO and NOx from the exhaust gas. The effectiveness of the catalyst to remove these harmful species depends strongly on the oxygen concentration in the exhaust gas. Deterioration of three-way catalyst results in a reduction in its purification activity and OSC (oxygen storage capacity). In this investigation, additive elements were used to enhance the durability and OSC of the catalyst support material. An optimized formulation of a CeO2-ZrO2 and a ZrO2 material was developed to have excellent durability, improved OSC, enhanced interaction between precious metals and support materials, and increase thermal stability. Using these newly developed support materials, catalysts with increased performance was designed.

In order to reduce the energy consumption of the automotive air conditioning system, adsorption heat pump (AHP) system is one of the key technologies. We have been developing compact AHP system utilizing the exhaust heat from the engine coolant system (80-100 °C), which can meet the requirements in the automotive application. However, AHP systems have not been practically used in automotive applications because of its low volumetric power density of the adsorber. The volumetric power density of the adsorber is proportional to sorption rate, packing density and latent heat. In general, the sorption rate is determined by mass transfer resistance in primary particle of an adsorbent and heat and mass transfer resistance in packed bed. In order to improve the volumetric power density of the adsorber, it is necessary to increase the production of the sorption rate and the packing density.

According to the principle of pH measurement, an on-board type engine oil deterioration sensor has been developed. The developed sensor is composed of a Pb and oxidized stainless steel electrodes. The sensor signal shows a good linear relationship to the quasi-pH value of the oil. Especially in the region where the oil deterioration proceeds, the remaining basic additives in the oil is easily estimated from the sensor signal.

Fretting fatigue mechanism of rapidly solidified powder aluminum alloy has been studied by model tests and analysis using fracture mechanics. The factors which influences upon fretting scar formation and fatigue crack propagation were the main concerns in the present work. In order to investigate the mechanism of fretting scar formation in detail, fretting wear tests in which small amplitude oscillatory movement occurred in the contact region were carried out. Test results showed that the size of fretting scar increased with increasing tangential force coefficient. Characteristics of fretting fatigue crack propagation were analyzed using fracture mechanics. The fatigue limits under fretting conditions were estimated by connecting the applied stress intensity factor range calculated from applied cyclic stress and tangential force, with the threshold stress intensity factor range of small crack.

The properties of diesel fuels were investigated in terms of particulate emissions to clarify the specification of such a diesel fuel for minimizing particulate emissions. Diesel fuels were analyzed using thin layer chromatography (TLC), and gas chromatography/mass spectrometry (GC/MS). These analysis revealed the entire composition of hydrocarbons in diesel fuels according to molecular formula. The entire composition of hydrocarbons in diesel fuels could be expressd on a three-dimensional graph: the X-axis as carbon number, the Y-axis as H/C ratio and the Z-axis as the amount of hydrocarbons of identical molecular formula. By using the graph, the properties reported so far were investigated. Also, simplified images of the fuel sprayed into a cylinder and its flame were derived from the observational results previously reported.

In direct-injection (DI) gasoline engines, spray characteristics greatly affect engine combustion. For the rapid development of new gasoline direct-injectors, it is necessary to predict the spray characteristics accurately by numerical analysis based on the injector nozzle geometry. In this study, two-phase flow inside slit nozzle injectors is calculated using the volume of fluid method in a three-dimensional CFD. The calculation results are directly applied to the boundary conditions of spray calculations, of which the submodels are recently developed to predict spray formation process in direct injection gasoline engines. The calculation results are compared with the experiments. Good agreements are obtained for typical spray characteristics such as spray shape, penetration and Sauter mean diameter at both low and high ambient pressures. Two slit nozzle injectors of which the slit thickness is different are compared.

The influence of engine oil viscosity on the wear of piston rings and cam faces has been investigated by fired engine tests using a radioisotope (RI) tracer technique. High-temperature and high-shear-rate (HTHS; 150°C, 1O6 s-1) viscosities of the experimental oils prepared are 2.2, 2.4, 2.6 and 3.1 mPa•s. At an oil temperature of 90°C the wear of piston rings and cam faces did not increase, even if the HTHS viscosity was lowered down to 2.2 mPa•s. However, both piston rings and cam faces exhibited an increase in wear below 2.4 mPa•s at 130°C. It was also recognized that valve train wear did not significantly increase with reducing viscosity in the motored engine tests at a temperature of 50°C. From these test results, it was suggested that the oil with the HTHS viscosity of 2.6 mPa•s sufficiently demonstrates the antiwear performance equivalent to that with around 3.0 mPa•s for application to piston rings and cam faces.

A new clean diesel combustion concept has been proposed and its excellent performance with respect to gas emissions and fuel economy were demonstrated using a single cylinder diesel engine. It features the following three items: (1) low-penetrating and highly dispersed spray using a specially designed injector with very small and numerous orifices, (2) a lower compression ratio, and (3) drastically restricted in-cylinder flow by means of very low swirl ports and a lip-less shallow dish type piston cavity. Item (1) creates a more homogeneous air-fuel mixture with early fuel injection timings, while preventing wall wetting, i.e., impingement of the spray onto the wall. In other words, this spray is suitable for premixed charge compression ignition (PCCI) operation, and can decrease both nitrogen oxides (NOx) and soot considerably when the utilization range of PCCI is maximized.

Diamond-like carbon (DLC) films are of significant interest for the automobile field, because they possess the potential to improve friction properties under various sliding conditions. Among the various DLC films, the authors focus on silicon-containing DLC (DLC-Si) films, which exhibit extremely low friction coefficient under dry sliding conditions in an ambient air atmosphere. The aim of this study is to examine the influence of silicon content in DLC-Si films on the friction property of the films, and to clarify the low friction mechanism of the films. The friction test was conducted under dry sliding conditions. It was found that the films have an exceedingly low friction coefficient (about 0.05) ranging in silicon content from 4 at% to 17 at%. In order to examine the low friction mechanism of the films, surface analyses were done on the wear surface of DLC-Si films slid against bearing steel.

This study models short circuits and blow-outs of spark channels. The short circuit model assumes that a spark channel is short-circuited between two arbitrary locations when the electric potential difference between the two locations exceeds the voltage which enables electrical insulation breakage in-between. The threshold voltage can be raised by increasing the distance between the two locations and decreasing the discharge current. Discharge current, in this model, represents the influence of both the spread and the number of electrically charged particles, i.e., electrons and positive ions, distributed near the two locations. Meanwhile, the blow-out model assumes that a strong flow diffuses electrons and positive ions in the spark channel, and consequently the discharge blows out.

A study was conducted to reduce unburned oil fractions in diesel particulate matter (PM) by improving oil consumption. A method utilizing radioisotope 14C was developed to measure the unburned oil fractions separately for the four paths by which oil is consumed: valve stem seals, piston rings, PCV system, turbocharger. The conversion ratio of oil consumption to PM was calculated by comparing the unburned oil emission rates with oil consumption rates, which were obtained by the use of the 35S tracer method. The result in an experimental diesel engine shows the highest conversion ratio for the oil leaking through the valve stem seals. The modifications to the engine were thereby focused on reducing the leakage of the stem seals. This stem seal modification, along with piston ring improvements, reduced oil consumption, resulting in the unburned oil fractions in PM being effectively reduced.

A new stratified charge combustion system has been developed for direct injection gasoline engines. The special feature of this system is employment of a thin fan-shaped fuel spray formed by a slit nozzle. The stratified mixture is produced by the combination of this fan-spray and a shell-shaped piston cavity. Both under-mixing and over-mixing of fuel in the stratified mixture is reduced by this system. This combustion system does not require distinct charge motion such as tumble or swirl, which enables intake port geometry to be simplified to improve full load performance. The effects of the new system on engine performance at part load are improved fuel consumption and reduced smoke, CO and HC emissions, obviously at medium load and medium engine speed. HC emissions at light load are also improved even with high EGR conditions.