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The particle number (PN) emission regulation has been implemented since 2011 in Europe. PN measurement procedure defined in ECE regulation No. 83 requires detecting only solid particles by eliminating volatile particles, the concentrations of which are highly influenced by dilution conditions, using a volatile particle remover (VPR). To measure PN concentration after the VPR, a particle number counter (PNC) which has detection threshold at a particle size of 23 nm is used, because most solid particles generated by automotive engines are considered to be larger than 23 nm. On the other hand, several studies have reported the existence of solid and volatile particles smaller than 23 nm in engine exhaust. This paper describes investigation into a measurement method for ultrafine PNCs with thresholds of below 23 nm and evaluation of the VPR performance for the particles in this size range. The detection efficiency of an ultrafine PNC was verified by following the ECE regulation procedure.

The characteristics of exhausted smoke of a methanol DI diesel engine which is ignited by diesel fuel are investigated to clarify the soot formation process. At this engine, very little smoke is exhausted when diesel fuel is kept below a certain amount, so soot and smoke emitting characteristics are studied under the various diesel fuel amounts. By analyzing microstructure of soot, it is found that the soot emitted from the methanol diesel engine is composed of inner core and outer shell, similar to that of the conventional diesel engines. From more detailed qualitative analysis, the calcium percentage from the lubricating oil in outer shell is much higher than that of the conventional diesel engines. In consideration of soot characteristics, spray structure and combustion characteristics, the soot formation process of the methanol diesel engine was clarified.

The effects of multiple-injection on exhaust emissions and performance in a small HSDI (High Speed Direct Injection) Diesel engine were examined. The causes for the improvement were investigated using both in-cylinder observation and three-dimensional numerical analysis methods. It is possible to increase the maximum torque, which is limited by the exhaust smoke number, while decreasing the combustion noise under low speed and full load conditions by advancing the timing of the pilot injection. Dividing this early-timed pilot injection into two with a small fuel amount is effective for further decreasing the noise while suppressing the increase in HC emission and fuel consumption. This is realized by the reduced amount of adhered fuel to the cylinder wall. At light loads, the amount of pilot injection fuel must be reduced, and the injection must be timed just prior to the main injection in order to suppress a possible increase in smoke and HC.

Methyl esters of saturated/unsaturated higher aliphatic acids (FAMEs) and a FAME of waste cooking oil (WCOME) were heated at 120°C in an air gas flow. The samples were analyzed before and after heating, using six different methods including electrospray ionization mass spectrometry. As a result, the samples after heating were found to contain low molecular weight aliphatic compounds and oligomers of the FAME. Based on the chemical structure of these oxidation products, reaction schemes were proposed for the deterioration of FAMEs. In addition, two unsaturated FAMEs containing 2,6-di-t-butyl-p-cresol (BHT) were similarly heated and analyzed to examine the effect of BHT on the oxidation of these FAME.

This report describes the implementation of the spark channel short circuit and blow-out submodels, which were described in the previous report, into a spark ignition model. The spark channel which is modeled by a particle series is elongated by moving individual spark particles along local gas flows. The equation of the spark channel resistance developed by Kim et al. is modified in order to describe the behavior of the current and the voltage in high flow velocity conditions and implemented into the electrical circuit model of the electrical inductive system of the spark plug. Input parameters of the circuit model are the following: initial discharge energy, inductance, internal resistance and capacitance of the spark plug, and the spark channel length obtained by the spark channel model. The instantaneous discharge current and the voltage are obtained as outputs of the circuit model.

Means for reducing the particulate matter (PM) from swirl chamber type diesel engines were searched out, and the reducing mechanisms were examined using an optically accessible engine. The following points were clarified in this study. 1. At light load, the suppression of the initial injection rate reduces PM, because SOF is reduced by the change in ignition point and smoke is reduced by the retarded flowout of the dense soot from the swirl chamber 2. Under medium and high load conditions, the main cause of the exhaust smoke is fierce spray-wall impingement which leads to fuel adhesion on the wall and the stagnation of a rich fuel-air mixture. 3. Enlarging swirl chamber volume ratio suppresses the formation of dense soot in the swirl chamber. In the main chamber, however, the soot oxidization becomes insufficient due to the mixing effect reduced by the essentially decreased chamber depth. 4.

This research aimed to identify how combustion characteristics are affected by the addition of hydrogen to methane, which is the main components of natural gas, and to study a combustion method that takes advantage of the properties of the blended fuel. It was found that adding hydrogen did not achieve a thermal efficiency improvement effect under stoichiometric conditions because cooling loss increased. The same result was obtained under EGR stoichiometric conditions. In contrast, under lean burn conditions, higher thermal efficiency and lower NOx than with methane combustion was achieved by utilizing the wide flammability range of hydrogen to expand the lean limit. Although NOx can be decreased easily by the addition of large quantities of hydrogen, the substantially lower energy density of the fuel causes a substantial reduction in cruising range. Consequently, this research improved the combustion of a CNG engine by increasing the tumble ratio to 1.8.

Among the challenges for the future facing the development of gasoline engines, one of the most important is the reduction of particles emissions. This study proposes a critical and objective evaluation of the influence of fuel characteristics on gasoline particles emission through the use of Fuel Particle Indices. For this, a selected fuel matrix composed of 22 fuels was built presenting different volatility and chemical composition (content in total aromatics, heavy cuts and ethanol). To represent the fuel sooting tendency, seven Fuel Particle Indices were selected based on a literature review, namely, Particulate Matter Index (PMI), Particulate Number index (PNI), Threshold Sooting index (TSI), Smoke point (SP), Oxygen Extended Sooting Index (OESI), Simplified index 1 and 2 (sPMI 1, sPMI 2). These indices were computed on the fuel matrix and compared on the basis of three main axes. First, the sensitivity to fuel variation.

The fluorescent magnetic particle inspection is widely used as a visual inspection method for checking cracks generated in hardening and grinding of induction-hardened parts. However, automation of this inspection process has strongly been demanded, due to poor environmental conditions and production line speed. To satisfy such a demand, we have developed a method for picking up images of automotive parts with higher S/N ratio and an original algorithm for image processing which helps measure cracks accurately without being affected by the illuminance and magnetic particle solution concentration. Then we selected the front axle shaft as the object to study practical use and have solved various technical problems in actual use, thereby succeeding in actual application to our production lines.

Countries and regions around the world are tightening emissions regulations in reaction to the increasing awareness of environmental conservation. At the same time, growing concerns about the depletion of raw materials as vehicle ownership continues to increase is prompting automakers to look for ways of decreasing the use of platinum-group metals (PGMs) in the exhaust systems. This research has developed a new catalyst with strong robustness against fluctuations in the exhaust gas and excellent nitrogen oxide (NOx) conversion performance. This catalyst incorporates rhodium (Rh) clusters with a particle size of several nanometers, and stabilized CeO2-ZrO2 solid-solution (CZ) with a pyrochlore crystal structure as a high-volume oxygen storage capacity (OSC) material with a slow O2 storage rate.

The new generation engines currently being developed tend to require cold type spark plugs, which are prone to fouling. This paper describes the development of a new Coil on Plug ignition system that resolves this problem by using the high energy and the fast secondary voltage rise time of a capacitive ignition while maintaining inductive ignition characteristics for good ignitability. To evaluate the effectiveness of the system, spark plug insulation resistance was monitored and cold tests were conducted. The results demonstrated that the new ignition system is remarkably effective: insulation resistance remains high and startability and driveability are unaffected under conditions normally leading to excessive misfires and failure to start with a conventional inductive system. To satisfy environmental concerns, automobile manufactures are increasingly turning to high compression ratio engines in view of their improved performance.

Recently, there has been a tendency of high power and high speed in automotive engines. In addition they have been also required high reliability. And engine bearings have been required to be advanced in wear resistance as well as seizure resistance. Therefore, copper-lead alloy bearings with overlay, which have better seizure resistance, have been widely used for high speed engines up to the present. But it becomes very important for them to advance the overlay wear resistance. In this paper, the composite overlay is mainly researched to improve wear resistance regarding kind of hard particles and their amounts in the overlay.

Diesel engines with relatively good fuel economy are known as an effective means of reducing CO₂ emissions. It is expected that diesel engines will continue to expand as efforts to slow global warming are intensified. Diesel particulate and NOx reduction system (DPNR), which was first developed in 2003 for introduction in the Japanese and European markets, shows high purification performance which can meet more stringent regulations in the future. However, it is poisoned by sulfur components in exhaust gas derived from fuel and lubricant. We then developed the sulfur trap DPNR with a sulfur trap catalyst that traps sulfur components in the exhaust gas. High purification performance could be achieved with a small amount of platinum group metal (PGM) due to prevention of sulfur poisoning and thermal deterioration.

A new combustion concept for DISI gasoline engine was developed to achieve superior performances of high power and low environmental load. It realizes a high specific power and a good lean combustion performance simultaneously by utilizing a DI spray jet effectively to accelerate the in-cylinder tumble flow. Injection direction and configuration of the DI spray was optimized for intensification of the in-cylinder flow and high mixture homogeneity, a thin fan-shaped spray generated by a slit nozzle was adopted. As a result, combustion was accelerated by increase of in-cylinder turbulence intensity, and homogeneity of air-fuel mixture was improved. In addition, in-cylinder fuel wall wetting, which causes emission of particulate matter (PM) and oil dilution, was drastically reduced by improvement of the fan-shaped spray.

This paper presents an improvement in the accuracy of NOx sensors at high NOx concentration regions by optimizing the manufacturing process, sensor electrode materials and structure, in order to suppress the deterioration mechanism of sensor electrodes. Though NOx sensors generally consist of Pt/Au alloy based oxygen pump electrodes and Pt/Rh alloy based sensor electrodes, detailed experimental analysis of aged NOx sensors showed changes in the surface composition and morphology of the sensor electrode. The surface of the sensor electrode was covered with Au, which is not originally contained in the electrode, resulting in a diminished active site for NOx detection on the sensor electrode and a decrease in sensor output. Theoretical analysis using CAE with molecular dynamics supported that Au tends to be concentrated on the surface of the sensor electrode.

A methanol fueled, lean burn system has been developed to improve both specific fuel consumption and NOx emissions. A 1.6L four-cylinder engine with increased compression ratio has been used to develop this system. Three major components of the Toyota Lean Combustion System (T-LCS) have been applied: (1) A helical port with a swirl control valve (2) A lean mixture sensor (3) Timed, multi-point fuel injection. A 2250 lb. Inertia Weight test vehicle has been fitted with this engine, and fuel system materials have been modified. This methanol, lean burn system has improved the fuel economy by about 12% still satisfying the 1986 emission standards of the U.S.A. and Japan. Aldehyde emissions have also been evaluated.

A new 3-way catalyst with NOx conversion performance for lean-burn engines has been developed. The catalyst oxidizes NOx and stores the resulting nitrate, which is then reduced by HC and CO during engine operation around the stoichiometric air/fuel ratio. Both the composition of the storage component and the particle sizes of the noble metal were optimized. In addition, a special air fuel mixture control has been developed to make the best of the NOx storage-reduction function. The present catalyst showed 90% conversion efficiency and improved fuel economy by 4% in the Japanese 10-15 mode test cycle. The efficiency remained at 60% or more after durability test.

In developing an oxidation catalyst for reducing diesel particulates, it is necessary to balance two conflicting characteristics. One is high oxidizing activity so that the catalyst can reduce the Soluble Organic Fraction (SOF) efficiency even at low exhaust temperatures. The other is the suppression of sulphate formation at high exhaust temperatures. First it was studied that active metals and coating materials are given effects on the reduction of SOF, the formulation of sulphate and durability, by using catalysts equivalent in composition to the oxidation catalyst for gasoline-engines. Based on these findings, a two-stage catalyst wasdeveloped. It satisfies the two characteristics at a comparatively high levelby slecting materials and optimizing the catalyst composition.

To realize the high performance of the three-way catalyst, this development focused on the heat resistance of the CeO2-ZrO2 solid solution (CZ) that possesses the oxygen storage capacity (OSC). A new concept of the OSC compound with high durability is proposed. We devised a new method of inhibiting the coagulation of the primary CZ particles by placing diffusion barrier layers made of alumina among the primary CZ particles. This material is called “ACZ”. The specific surface area of ACZ was larger than that of the conventional CZ after durability test. The sintering of Pt on the ACZ-added catalyst is inhibited and the crystal size of CZ in the ACZ-added catalyst is smaller than that in the CZ-added catalyst. The OSC and the light off temperature of the ACZ-added catalyst are improved.

An on-board particulate matter (PM) sensor, consisting of a gas-permeable electrochemical cell with a porous yttria-stabilized zirconia solid oxide electrolyte, was developed to assist the on-board diagnostics (OBD) system of a vehicle. Exhaust is pumped from the anode side to the cathode side and PM deposited on the anode is instantly oxidized by the catalytic effects of the metal component of the electrode at temperatures higher than 350°C. The PM oxidation reaction occurs at the three-phase boundary between the anode, electrolyte and gas phase, and causes a slight change in the bulk average oxygen concentration, which produces electrochemical polarization by the difference in oxygen partial pressures between the anode and cathode. The developed PM sensor has a detection limit of 2 mg/m₃, at which level will enable PM detection in the OBD system according to the EURO VI regulation.