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The efficiency of the NOx Storage and Reduction (NSR) catalysts used in the aftertreatment of diesel engine exhaust gases can potentially be increased by using reactive reductants such as CO and H₂ that are formed during in-cylinder combustion. In this study, a multi-dimensional computational fluid dynamics (CFD) code coupled with complex chemical analysis was used to study combustion with various fuel after-injection patterns. The results obtained will be useful in designing fuel injection strategies for the efficient formation of CO.

Over the last few decades, in-cylinder visualization using optically accessible engines has been an important tool in the detailed analysis of the in-cylinder phenomena of internal combustion engines. However, most current optically accessible engines are recognized as being limited in terms of their speed and load, because of the fragility of certain components such as the elongated pistons and transparent windows. To overcome these speed and load limits, we developed a new generation of optically accessible engines which extends the operating range up to speeds of 6000 rpm for the SI engine version, and up to in-cylinder pressures of 20 MPa for the CI engine version. The main reason for the speed limitation is the vibration caused by the inertia force arising from the heavy elongated piston, which increases with the square of the engine speed.

To avoid knocking phenomena, a special crank mechanism for gasoline engine that allowed the piston to move rapidly near TDC (Top Dead Center) was developed and experimentally demonstrated in the previous study. As a result, knocking was successfully mitigated and indicated thermal efficiency was improved [1],[2],[3],[4]. However, performance of the proposed system was evaluated at only limited operating conditions. In the present study, to investigate the effect of piston movement near TDC on combustion characteristics and indicated thermal efficiency and to clarify the knock mitigation mechanism of the proposed method, experimental studies were carried out using a single cylinder engine with a compression ratio of 13.7 at various engine speeds and loads. The special crank mechanism, which allows piston to move rapidly near TDC developed in the previous study, was applied to the test engine with some modification of tooling accuracy.

A new stratified charge system has been developed for direct injection gasoline engines. The special feature of this system is employment of a thin fan-shaped fuel spray formed by a slit nozzle and a shell-shaped piston cavity. This system, basically classified into the wall-guided mixture preparation concept that leads air/fuel mixture to the spark plug periphery by means of spray penetration and piston cavity configuration without an extra intake air flow controlling system, obtained wide engine operating area with stratified combustion and high output performance. This report presents the characteristics of stratified mixture formation and combustion, especially the important factor for achieving stable stratified combustion in the high-speed region, which have been clarified through analytical studies.

In internal combustion engine, it is well-known that oil infiltrates the combustion chamber through the clearance between the piston ring and the cylinder bore with vertical reciprocating motion of the piston, leading to an increase in oil consumption. The deformation of the cylinder bore is inevitable to some extent in the actual engine because of the tightening of cylinder head bolt and heat load._As to the function of the piston ring, it is desirable that it conforms to such bore deformation. The author et al. made a glass cylinder engine in which closed piston ring gap could be visualized, based on the idea that piston ring conformability to the sliding surface of bore could be evaluated from minute changes of the piston ring gap. This newly-devised visualized engine was an in-line 4-cylinder engine, capable of running up to 6,000 rpm, in which the closed gap of piston ring could be observed minutely during engine operation.

The reduction of engine oil consumption rate is one of the important concerns for automotive engineers. However, it has been difficult to solve this subject, since the oil consumption mechanism has not yet been elucidated. In this study, to clarify the oil loss mechanism via the piston rings, a transparent glass cylinder engine was used to observe oil behavior between cylinder wall and piston surface. For photographic observation, a high speed camera, a still camera. and a TV camera were used. Since the new photographic system by using TV camera with a synchro - flash and a synchro-memory was applied, it was also possible to observe the oil behavior in detail. Moreover, a new visual method by which colored oil was injected from the various points on the piston surface and traced was developed for easy analysis of oil movement around the piston ring.

Methyl esters of saturated/unsaturated higher aliphatic acids (FAMEs) and a FAME of waste cooking oil (WCOME) were heated at 120°C in an air gas flow. The samples were analyzed before and after heating, using six different methods including electrospray ionization mass spectrometry. As a result, the samples after heating were found to contain low molecular weight aliphatic compounds and oligomers of the FAME. Based on the chemical structure of these oxidation products, reaction schemes were proposed for the deterioration of FAMEs. In addition, two unsaturated FAMEs containing 2,6-di-t-butyl-p-cresol (BHT) were similarly heated and analyzed to examine the effect of BHT on the oxidation of these FAME.

Hybrid vehicles (HVs) are becoming more widely used. Since HVs supplement engine drive with motor power, the lubricant oil temperature remains at a lower level than in a conventional gasoline vehicle. This study analyzed the effect of cylinder bore temperature and lubricant oil temperature on engine friction. The results showed that, although the lubricant oil temperature was not relevant, the bore temperature had significant effect on piston friction. It was found that raising the temperature of the middle section of the cylinder bore was the most effective way of reducing piston friction.

The effect of GTL diesel fuel on organic materials used in fuel delivery systems of vehicles was investigated. Specimens made from 16 kinds of organic materials were immersed in GTL diesel fuels synthesized at Refinery-A and Refinery-B (referred to as GTL-A and GTL-B, respectively) and then subjected to tensile testing. The tensile test results revealed that elongation of the nylon sample immersed in GTL-A was extremely small, about 4% of that of untreated nylon. In the light of this finding, the GTL diesel fuels and nylons before and after immersion test were analyzed in detail using about 20 analysis methods to determine the cause for poor elongation. The following points were found. (1) GTL-A consisted of low molecular-weight paraffins. (2) GTL-A had low molecular-weight i-paraffins. (3) The nylon immersed in GTL-A contained low molecular-weight paraffins. (4) The paraffins in the nylon immersed in GTL-A were richer in i-paraffins than the original GTL-A.

A direct injection (DI) gasoline engine having a new stratified charge combustion system has been developed. This new combustion process (NCP) was achieved by a fan-shaped fuel spray and a combustion chamber with a shell-shaped cavity in the piston. Compared with the current Toyota D-4 engine, wider engine operating area with stratified combustion and higher output performance were obtained without a swirl control valve (SCV) and a helical port. This report presents the results of combustion analyses to optimize fuel spray characteristics and piston cavity shapes. Two factors were found to be important for achieving stable stratified combustion. The first is to create a ball-shaped uniform mixture cloud in the vicinity of the spark plug. The optimum ball-shaped mixture cloud is produced with a fuel spray having early breakup characteristics and uniform distribution, and a suitable side wall shape in the piston cavity to avoid the dispersion of the mixture.

The cause of the exhaust smoke and its reduction methods in a small DI Diesel engine with a small-orifice-diameter nozzle and common rail F.I.E. were investigated under high-speed and high-load condition, using both in-cylinder observations and Three-dimensional numerical analyses. The following points were clarified during this study. At these conditions, fuel sprays are easily pushed away by a strong swirl, and immediately flow out to the squish area by a strong reverse squish. Therefore, the air in the cavity is not effectively used. Suppressing the airflow in a piston cavity, using such ideas as enlarging the piston cavity diameter or reducing the port swirl ratio, decreases the excessive outflow of the fuel-air mixture into the squish area, and allows the full use of air in the whole cavity. Hence, exhaust smoke is reduced.

This research aimed to identify how combustion characteristics are affected by the addition of hydrogen to methane, which is the main components of natural gas, and to study a combustion method that takes advantage of the properties of the blended fuel. It was found that adding hydrogen did not achieve a thermal efficiency improvement effect under stoichiometric conditions because cooling loss increased. The same result was obtained under EGR stoichiometric conditions. In contrast, under lean burn conditions, higher thermal efficiency and lower NOx than with methane combustion was achieved by utilizing the wide flammability range of hydrogen to expand the lean limit. Although NOx can be decreased easily by the addition of large quantities of hydrogen, the substantially lower energy density of the fuel causes a substantial reduction in cruising range. Consequently, this research improved the combustion of a CNG engine by increasing the tumble ratio to 1.8.

Among the challenges for the future facing the development of gasoline engines, one of the most important is the reduction of particles emissions. This study proposes a critical and objective evaluation of the influence of fuel characteristics on gasoline particles emission through the use of Fuel Particle Indices. For this, a selected fuel matrix composed of 22 fuels was built presenting different volatility and chemical composition (content in total aromatics, heavy cuts and ethanol). To represent the fuel sooting tendency, seven Fuel Particle Indices were selected based on a literature review, namely, Particulate Matter Index (PMI), Particulate Number index (PNI), Threshold Sooting index (TSI), Smoke point (SP), Oxygen Extended Sooting Index (OESI), Simplified index 1 and 2 (sPMI 1, sPMI 2). These indices were computed on the fuel matrix and compared on the basis of three main axes. First, the sensitivity to fuel variation.

Piston ring moving zone in the cylinder is one of the most critical lubrication regimes in diesel engines. This area is susceptible to combustion substances. In particular, abnormal wear is occasionally detected due to Exhaust Gas Recirculation (EGR) system equipment. In Japan, NOx emission requirements for passenger car diesels have become more stringent effective October 1, 1986. OEMs tend to apply EGR systems to reduce NOx in exhaust gas. In order to identify the phenomenon of abnormal cylinder wear of EGR equipped engine, engine bench tests were conducted under varied conditions in EGR equipment, cooling water temperature and fuel sulfur content. The test results suggest that wear caused at low temperature is mainly corrosive wear attributable to sulfuric acid formed by reaction with fuel sulfur and condensed water.

Countries and regions around the world are tightening emissions regulations in reaction to the increasing awareness of environmental conservation. At the same time, growing concerns about the depletion of raw materials as vehicle ownership continues to increase is prompting automakers to look for ways of decreasing the use of platinum-group metals (PGMs) in the exhaust systems. This research has developed a new catalyst with strong robustness against fluctuations in the exhaust gas and excellent nitrogen oxide (NOx) conversion performance. This catalyst incorporates rhodium (Rh) clusters with a particle size of several nanometers, and stabilized CeO2-ZrO2 solid-solution (CZ) with a pyrochlore crystal structure as a high-volume oxygen storage capacity (OSC) material with a slow O2 storage rate.

The new generation engines currently being developed tend to require cold type spark plugs, which are prone to fouling. This paper describes the development of a new Coil on Plug ignition system that resolves this problem by using the high energy and the fast secondary voltage rise time of a capacitive ignition while maintaining inductive ignition characteristics for good ignitability. To evaluate the effectiveness of the system, spark plug insulation resistance was monitored and cold tests were conducted. The results demonstrated that the new ignition system is remarkably effective: insulation resistance remains high and startability and driveability are unaffected under conditions normally leading to excessive misfires and failure to start with a conventional inductive system. To satisfy environmental concerns, automobile manufactures are increasingly turning to high compression ratio engines in view of their improved performance.

Diesel engines with relatively good fuel economy are known as an effective means of reducing CO₂ emissions. It is expected that diesel engines will continue to expand as efforts to slow global warming are intensified. Diesel particulate and NOx reduction system (DPNR), which was first developed in 2003 for introduction in the Japanese and European markets, shows high purification performance which can meet more stringent regulations in the future. However, it is poisoned by sulfur components in exhaust gas derived from fuel and lubricant. We then developed the sulfur trap DPNR with a sulfur trap catalyst that traps sulfur components in the exhaust gas. High purification performance could be achieved with a small amount of platinum group metal (PGM) due to prevention of sulfur poisoning and thermal deterioration.

An unprecedented phenomenon that achieves high NOx conversion was found over an NSR catalyst. This phenomenon occurs when continuous short cycle injections of hydrocarbons (HCs) are supplied at a predetermined concentration in lean conditions. Furthermore, this phenomenon has a wider range of applicability for different catalyst temperatures (up to 800 degrees Celsius) and SVs, and for extending thermal and sulfur durability than a conventional NOx storage and reduction system. This paper analyzes the reaction mechanism and concludes it to be highly active HC-deNOx by intermediates generated from adsorbed NOx over the base catalysts and HCs partially oxidized by oscillated HC injection. Subsequently, a high performance deNOx system named Di-Air (diesel NOx aftertreatment by adsorbed intermediate reductants) was demonstrated that applies this concept to high speed driving cycles.

Effects of spray characteristics for stratified combustion of direct injection gasoline engine have been researched. The highly functional piezoelectric (PZT) injector was selected for this research. A hole and swirl nozzle were examined in a wide range of fuel pressure. The hole nozzle aims to make stratified mixture formation by vaporizing fuel on the piston, and the swirl nozzle aims to do so in the air above the piston by utilizing the spray characteristic of lower penetration and higher dispersibility. Both sprays could realize stable stratified combustion. The stability mainly depends on the combination of spray characteristic and piston cavity shape, and the swirl air motion which strength changes corresponding to engine operating conditions. The hole nozzle requires high, and the swirl nozzle less fuel pressure. Even by a large amount of EGR, stratified combustion has the advantage of combustion stability, and is useful to reduce exhaust emissions, especially NOx emissions.

The outline of the TOYOTA FCHV-adv is described in this paper. The TOYOTA FCHVadv achieved an approximately 25 percent improvement in vehicle fuel efficiency and about 1.9 times the amount of usable hydrogen in comparison with the previous model. These improvements have enabled almost 2.5 times longer practical cruising range, more than 500 km. The freeze start capabilities of the FCHV-adv were improved by modifying the FC stack and control system. As a result, the FCHV-adv has been capable of starting at a temperature of -30°C. In the future, TOYOTA intends to improve durability and reduce costs.