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A multi-dimensional numerical method for predicting the warm-up characteristic of automobile catalytic converter systems was developed to effectively design catalytic converter systems which achieve low tail pipe emissions with satisfactory packagebility. The features of the method are; (1) consideration of the governing phenomena such as gas flow, heat transfer, and chemical reactions (2) capability of predicting warm-up characteristic for not only the catalytic converters but also the system as a whole during emission test modes such as the USA LA-4 mode. The description of the method is presented. The experimental verifications of the method were conducted to assure the accuracy of it. The effect of design parameters such as electrically heated catalyst (EHC), high loading of noble metal and thin honeycomb wall on warm-up characteristic of the catalyst are analyzed in the paper.

Methyl esters of saturated/unsaturated higher aliphatic acids (FAMEs) and a FAME of waste cooking oil (WCOME) were heated at 120°C in an air gas flow. The samples were analyzed before and after heating, using six different methods including electrospray ionization mass spectrometry. As a result, the samples after heating were found to contain low molecular weight aliphatic compounds and oligomers of the FAME. Based on the chemical structure of these oxidation products, reaction schemes were proposed for the deterioration of FAMEs. In addition, two unsaturated FAMEs containing 2,6-di-t-butyl-p-cresol (BHT) were similarly heated and analyzed to examine the effect of BHT on the oxidation of these FAME.

Filiform corrosion phenomenon and its prevention method for 5000 series aluminum alloy sheet have been investigated. The painted aluminum alloy sheets were subject significantly to filiform corrosion caused by formation of a mottled and coarse zinc phosphate film during chemical conversion process. On the other hand, galvanized aluminum alloy sheet showed an uniform and fine phosphate film in a brief time and the filiform corrosion resistance was improved markedly. The test results of press-forming and corrosion for the prototype engine hoods made of this newly developed galvanized sheets have revealed a good formability and an excellent filiform corrosion resistance.

Toyota Motor Corporation has mass-produced turbochager with sillicon nitride ceramic rotors. A moment of inertia was reduced by 60% using ceramic rotor which improved turbochager response. The ceramic rotor was joined to metal shaft by new method which compensated problems in both shrink fitting and active brazing methods. They are generals for mechanical and chemical techniques, respectively. There still exist the following disadvantages. It is quite severe to controll the clearance of shrink fitting to obtain the reliability of the joint. The shaft may be loosened at high temperature with a small shrink-fit interference. The large shrink-fit interference could result in a failure of ceramic shaft due to large stress. Those may require a machinig accuracy with micron meter order of surface roughness which, leads to high cost.

Recently, the plastic material is positively introducing for automotive parts due to the Needs of vehicle weight reduction and cost saving. On the other hand, the countermeasure for scrapped car is a big subject to need to consider as a car maker. Therefore, the development of recycling technology for plastic parts has been necessary. In this study, we tried to develop recycling technology for glass fiber reinforced Polyamide6(PA6) which is applied to various automotive parts like an air intake manifold. As a recycling technique, we focused on the chemical recycling which can reclaim raw material of PA6(ε- caprolactams) from the post-consumer automotive parts. The chemical recycling we selected can be put on a higher priority because it has possibility to utilize the limited resource repeatedly. As a result, we could retain high purity of ε- caprolactams using our following two techniques which make possible to recycle Polyamide 6 materials. One is to separate PA6 from glass fiber.

The use of ceramic insulation to reduce engine heat loss and thus improve fuel economy was examined but found to be detrimental rather than advantageous. This paper analyzes the reasons and presents an alternative approach, namely minimizing the heat transfer area. Experiments were conducted to determine the effects of surface smoothness on BSFC, output torque, heat release rate and piston temperature. It was found that with a mirror-finished combustion chamber, heat loss is decreased and consequently engine output is raised, while fuel consumption is lowered. The percentage reduction in heat loss was ascertained by numerically simulating combustion and was confirmed by FEM analysis of piston thermal distribution.

The relative oxidation stability of two fully formulated engine oils was compared in three testing methods by following the increase in kinematic viscosity of the oil. The purpose of the study was to determine the cause of the completely opposite ranking of the oxidation stability of the two oils that was observed in the ASTM Sequence IIIE engine test and the JASO M333 93 engine test and to determine the degree of correlation the two engine tests had with the field. The study consisted of laboratory oxidation testing, engine testing and taxi field testing to cover the range of conditions from controlled oxidation to actual driving conditions.

Engine friction reduction is an effective means to improve fuel consumption. Fluid friction reduction of main bearing is examined for engine friction reduction in cold condition. As one of the examinations, it was focused on low temperature of lubricating oil in the early stage during engine cold start. In hydrodynamic lubrication, the oil film temperature is maintained by balance between heat generation and heat transfer. The heat generation is generated by shear of lubricating oil. The factors of the heat transfer, the following elements are considered as follows, A) The heat transfer to a crank shaft, B) The heat transfer to a bearing, C) The heat transfer by convection. If the heat generation is constant, oil film temperature is increased by reduction of heat transfer. It is considered that the reduction of oil leakage and reduction of the heat transfer by convection is equivalent.

Multi-cylinder hydrogen-absorbing alloy tanks for fuel cell vehicles have 10 to 40 metallic cylinders that are bundled and filled with hydrogen-absorbing alloy. In this system, the cylinders themselves act as a heat exchanger and the working pressure is lowered to 10 to 20 MPa compared with high-pressure MH tanks. Moreover, both heat conduction and mass reduction can be achieved by reducing the wall thickness of the cylinders. A model verification experiment was conducted using a one-quarter-scale prototype of a full size tank, and a conduction simulation model verified in the experiment was used to predict the performance of the full size tank. Results showed that it is possible to fill the tank with hydrogen to 80% of its capacity in a five-minute filling time, although issues related to heat conductivity performance require improvement. Accordingly, it may be possible to adopt this tank as part of a system if the storage amount of the hydrogen-absorbing alloy can be increased.

On the basis of the investigation of the airflow and temperature distributions between the car underside and the wind tunnel floor, methods to improve, the differential gear lubricant cooling performance in high speed running have been studied. It has been clarified that the differential gear lubricant temperature is nearly dominated by the convective heat transfer coefficient and the air temperature around the differential gear carrier. Control of the heat transfer coefficient and the air temperature around the differential gear carrier through the modification of the car underside configuration was found to be the most efficient method to decrease the temperature of the differential gear lubricant.

The design of the newly developed Toyota AZ series 4 cylinder engine has been optimized through both simulations and experiments to improve heat transfer, cooling water flow, vibration noise and other characteristics. The AZ engine was developed to achieve good power performance and significantly reduced vibration noise. The new engine meets the LEV regulations due to the improved combustion and optimized exhaust gas flow. A major reduction in friction has resulted in a significant improvement in fuel economy compared with conventional models. It also pioneered a newly developed resin gear drive balance shaft.

To facilitate research and development of diesel engines, the universal numerical code for predicting diesel combustion has been favored for the past decade. In this paper, the finite-rate elementary chemical reactions, sometimes called the detailed chemical reactions, are introduced into the KIVA-3V code through the use of the Partially Stirred Reactor (PaSR) model with the KH-RT break-up, modified collision and velocity interpolation models. Outcomes were such that the predicted pressure histories have favorable agreements with the measurements of single and double injection cases in the diesel engine for use in passenger cars. Thus, it is demonstrated that the present model will be a useful tool for predicting ignition and combustion characteristics encountered in the cylinder.

This paper presents the numerical simulation method to predict the deactivation process of three-way catalytic converters. Three-way catalytic converter's deactivation typically results from thermal and chemical mechanisms. The major factor of thermal deactivation is the sintering of noble metal particles, which is known to depend on the ageing temperature and the oxygen concentration in the exhaust gas. The chemical deactivation is mainly caused by the poisoning, which has two effects on the catalyst deactivation. One effect is the loss of the catalyst activity, which is expressed by reduced frequency factors of reaction rates. Another effect is the suppression of the noble metal sintering. Poison deposits prevent the noble metal particles from moving in the washcoat, assisted by the reduced thermal loading of reaction heats, which is caused by the loss of the catalyst activity. Modeling these deactivation factors, we propose the rate expression of noble metal sintering.

ϵ-caprolactam was polymerized in the interlayer space of montmorillonite, the clay mineral yielding a nylon-clay hybrid (NCH). X-ray and TEM measurements revealed that each template of the silicate, which was 1 nm thick, was dispersed in the nylon 6 matrix, and that the interlayer distance of clay increased continuously from 1.2 nm for the unintercalated material to 21.4 nm for the intercalated material. Thus, NCH is a polymer-based molecular composite or a nano-composite. NCH contains 1-15 vol% of monolayer clay. Injection-molded NCH showed excellent mechanical properties compared with nylon 6 in terms of tensile strength, tensile modulus and heat resistance. The tensile modulus of NCH was twice that of Nylon 6, and the heat distortion temperature increased from 65°C for nylon 6 to 145°C for the NCH containing only 1.6 vol% of a clay mineral. It was found that such excellent properties of an NCH system was due to the strong ionic interaction between nylon 6 and the silicate layer.

Methanol steam reforming, which is an endothermic reaction, needs some heating. Both methanol conversion ratio and carbon monoxide (CO) concentration increase when temperature is elevated. As CO poisons a typical polymer electrolyte of a fuel cell, the relationship between methanol conversion ratio and CO concentration is a trade-off one. It was found from preliminary researches that the reforming reaction speed is controlled by heat transfer rate at large methanol flow rate, where methanol conversion ratio becomes lower and CO concentration becomes higher. Therefore it is necessary to develop a new methanol reforming concept that provides stable combustion for heating and enhanced heat transfer for improving the trade-off relationship and making a compact reformer. Reforming catalyst using metal honeycomb support and a new catalytic combustion were applied to a new concept plate type methanol steam reformer, which is used in a fuel cell of 3 kW-class electric generation.

A prediction technique for the lubricating oil temperature in a manual transaxle was developed. Using this technique, the effects of heat transfer enhancement and heat generation decrease, etc., on the oil temperature reduction can be estimated. The heat generation in a manual transaxle is caused by lubricating oil stirring, friction and gear meshing. The heat transfer and flow characteristics are thus very complicated under the two-phase flow of the oil and air induced by rotating gears. It is necessary for the development of the prediction technique to model the heat transfer process in a manual transaxle. The experiments measuring of heat generation, heat flux and the air flow velocity distribution around the manual transaxle were conducted to get information for modeling the heat transfer process. A flow visualization of two-phase flow in the manual transaxle was also conducted.

At the engine restart, when the temperature of the catalytic converter is low, additional fuel consumption would be required to warm up the catalyst for controlling exhaust emission.The aim of this study is to find a thermally optimal way to reduce fuel consumption for the catalyst warm up at the engine restart, by improving the thermal retention of the catalytic converter in the cool down process after the previous trip. To make analysis of the thermal flow around the catalytic converter, a 2-D thermal flow model was constructed using the thermal network method. This model simulates the following processes: 1) heat conduction between the substrate and the stainless steel case, 2) heat convection between the stainless steel case and the ambient air, 3) heat convection between the substrate and the gas inside the substrate, 4) heat generation due to chemical reactions.

In order to develop the valve rocker arm material for the new type engine, we investigated various materials whose chemical compositions were selected using 30% chromium cast iron, which had shown good results in screening evaluation tests, as the basis. High chromium cast irons are well known for their abrasive wear resistance, but it has been very difficult to apply them for use as rocker arm material because their machinability is very poor, and because it is difficult for them to have a regular microstructure. In this paper, both the manufacturing method for the rocker arm which decreases the disadvantages that high chromium cast iron have and the rocker arm material best suited for this method are described.