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A laboratory scale simulation test method was developed to evaluate deterioration of radial lip seals of fluoroelastomer (FKM) compounds for engine crankshafts. The investigation of the collected radial lip seals of FKM compounds from the field with service up to 450,000km indicated that the only symptom of deterioration is a decrease of lip interference. This deterioration was not duplicated under conventional test conditions using an oil seal test machine because sludge build up at the seal lip caused oil leakage. However, revised test conditions make it possible to duplicate the deterioration experienced in the field. An immersion test using a radial lip seal assembled with the mating shaft was newly developed. This test method was found to be useful to evaluate deterioration of radial lip seals using FKM compounds. Oil additives affect the deterioration of lip seal materials significantly. Therefore, immersion tests of four different oils were conducted to evaluate this effect.

Methyl esters of saturated/unsaturated higher aliphatic acids (FAMEs) and a FAME of waste cooking oil (WCOME) were heated at 120°C in an air gas flow. The samples were analyzed before and after heating, using six different methods including electrospray ionization mass spectrometry. As a result, the samples after heating were found to contain low molecular weight aliphatic compounds and oligomers of the FAME. Based on the chemical structure of these oxidation products, reaction schemes were proposed for the deterioration of FAMEs. In addition, two unsaturated FAMEs containing 2,6-di-t-butyl-p-cresol (BHT) were similarly heated and analyzed to examine the effect of BHT on the oxidation of these FAME.

Sintered silicon nitride, particularly in structural ceramics, has superior properties such as low weight, heat resistance, wear resistance, etc. It is already being applied to automobile engine parts such as the swirl chamber and the turbine rotor. In recent years, the strength of silicon nitride has shown to be above 1000MPa. This has been achieved through advances in manufacturing technology such as materials powder, forming, sintering and so on. But the silicon nitride is easily damaged during grinding because it has less fracture toughness than metal. Consequently, the inherent strength of the material is not demonstrated in the actual products presently produced. It is assumed that the main cause of strength reduction is microcrack. In ordinary grinding methods, the length of microcrack has been estimated at approximately twenty micrometers by fracture mechanics analysis.

The effect of GTL diesel fuel on organic materials used in fuel delivery systems of vehicles was investigated. Specimens made from 16 kinds of organic materials were immersed in GTL diesel fuels synthesized at Refinery-A and Refinery-B (referred to as GTL-A and GTL-B, respectively) and then subjected to tensile testing. The tensile test results revealed that elongation of the nylon sample immersed in GTL-A was extremely small, about 4% of that of untreated nylon. In the light of this finding, the GTL diesel fuels and nylons before and after immersion test were analyzed in detail using about 20 analysis methods to determine the cause for poor elongation. The following points were found. (1) GTL-A consisted of low molecular-weight paraffins. (2) GTL-A had low molecular-weight i-paraffins. (3) The nylon immersed in GTL-A contained low molecular-weight paraffins. (4) The paraffins in the nylon immersed in GTL-A were richer in i-paraffins than the original GTL-A.

In a previous paper (Part 1 of this series), nylon-66 specimens were immersed in two GTL diesel fuels (GTL-A and GTL-B) and then subjected to tensile testing. The tensile test results revealed that the elongation of the specimen immersed in GTL-A was dramatically reduced. The GTL diesel fuels and nylon specimens before and after immersion were analyzed to determine the cause of the decline in elongation. It was found that the poor elongation was caused by penetration and oxidation of low molecular-weight paraffins and that the ease of penetration and oxidation of paraffin depended on the structure of paraffin. In this paper, the low molecular-weight paraffins detected in GTL-A were mixed to produce model fuels. Then, pieces of nylon cut from the tensile test specimen, were immersed in the model fuels. In addition, partial oxidation products of the paraffin (alcohol, aldehyde or ketone and acid) were used in immersion tests of the nylon pieces.

Toyota participated in Formula One1 (F1) Racing from 2002 to 2009. As a result of the downturn in the world economy, various engine developments within F1 were restricted in order to reduce the cost of competing in F1. The limit on the maximum number of engines allowed has decreased year by year. Toyota focused on the engine performance deterioration due to the combustion chamber deposits. In 2009, Toyota was successful in reducing around 40% of the deterioration by making combustion chamber cleaner in cooperation with ExxonMobil. This contributed to good result of 2009 F1 season for Toyota, including two second place finishes.

Recently, there has been a tendency of high power and high speed in automotive engines. In addition they have been also required high reliability. And engine bearings have been required to be advanced in wear resistance as well as seizure resistance. Therefore, copper-lead alloy bearings with overlay, which have better seizure resistance, have been widely used for high speed engines up to the present. But it becomes very important for them to advance the overlay wear resistance. In this paper, the composite overlay is mainly researched to improve wear resistance regarding kind of hard particles and their amounts in the overlay.

The muffler layout in the exhaust system has been optimized for the attenuation of exhaust noise which has not been studied much to this date. As a result, “Exhaust Manifold Muffler” has been developed. This unit is capable of efficiently muffling the primary and secondary componemts of the engine explosion stroke noise. Such task is achieved without deterioration of engine performance by allocating the volume at the junction of the exhaust manifold branch pipes. Acoustic characteristics of “Exhaust Manifold Muffler” have been analyzed by FEM and experimental methods, which have shown that not only does the volume placed at the junction of the exhaust manifold branch pipes work as a conventional muffler, but also prevents the exhaust manifold branch pipes from amplifying exhaust noise. This is the reason why “Exhaust Manifold Muffler” can muffle more efficiently than the conventional muffler.

The new intelligent VVT (Variable Valve Timing) -i, is one of the systems developed to improve engine performance. The pulley unit is one of the most important mechanical components of the system. We developed a suitable process for the four main parts of the VVT-i pulley in order to achieve the target performance at a minimal cost. The requirements for the mechanical component, the pulley unit, include light weight and compact design as well as a quick response time. To satisfy these requirements, we developed three helical gears having unique profiles and high accuracy, and a timing pulley which must prevent pressurized oil from leaking. The inner gear is a helical gear with external teeth,and a key way on its inside diameter. The piston gear is a helical gear of which the inside and outside teeth have opposite helix angles. We developed a unique powder compacting technology for these two gears. The timing pulley is also made of sintered metal alloy.

We have developed a new torsional damper spring which lowers the torsional rigidity of the clutch disc while retaining its conventional size. The following two items have been adopted in the newly developed spring: 1) A new steel wire which suppresses any core-softening of the element wire through nitriding. 2) A dual-stage shot peening method which uses harder steel shots (rather than conventional shots) in order to obtain an optimal residual stress profile. As a result of evaluating the fatigue characteristics of this spring, it was discovered that its fatigue strength is approximately 35% higher than that of the conventional spring. A clutch disc using this spring was able to absorb rattling noises which conventional clutch discs could not.

In conventional gasoline engine vehicles, three-way catalysts are used to simultaneously remove HC, CO and NOx from the exhaust gas. The effectiveness of the catalyst to remove these harmful species depends strongly on the oxygen concentration in the exhaust gas. Deterioration of three-way catalyst results in a reduction in its purification activity and OSC (oxygen storage capacity). In this investigation, additive elements were used to enhance the durability and OSC of the catalyst support material. An optimized formulation of a CeO2-ZrO2 and a ZrO2 material was developed to have excellent durability, improved OSC, enhanced interaction between precious metals and support materials, and increase thermal stability. Using these newly developed support materials, catalysts with increased performance was designed.

A high strength and high toughness new bainitic steel has been developed which shows comparable mechanical properties, fatigue property, and machinability to those of quenched and tempered SAE 5140. The heat treatment of the bainitic steel is aging after hot forging in order to improve ratio of 0.2% proof stress and tensile strength (i.e. yield ratio) and to avoid warpage associated with quenching. The new bainitic steel has been applied to the slender and lightweight lower arms for automotive suspension. As a result, the total production costs in the lower arms have been reduced by nearly 15 percent.

It is important to reduce the viscosity of automatic transmission fluid (ATF) in order to improve fuel economy. However, in general, low viscosity fluid can cause metal fatigue, wear, and seizure. It is necessary to increase the viscosity of the fluid at higher temperatures to maintain the durability of the automatic transmission (AT). The key point is the selection of the base oil and the viscosity index improver (VII) with both a high viscosity index (VI) and excellent shear stability. On the basis of this concept, a new generation high performance ATF named WS was developed. WS can achieve the highest level of fuel economy, while maintaining the durability of the AT.

We developed a new Manual Transmission Gear Oil (MTF) named LV for improved fuel economy and CO2 reduction. MTF LV is a low viscosity fluid to reduce stir losses at lower temperatures. In general, low viscosity fluids can cause metal fatigue, wear and seizure. The MTF LV was designed to overcome these problems by maintaining the oil film thickness after it is deteriorated and improving the wear characteristics with additives. As a result, the MTF LV provides equal or better durability than the current MTF. In addition, it also has good performance at low temperatures, better shift feeling characteristics, and improved oxidation stability.

In October 1998, a new mass-produced car with titanium engine-valves was released from TOYOTA Motor Corporation. Both intake and exhaust valves were manufactured via a newly developed cost-effective P/M forging process. Furthermore, the material which was specially designed for the exhaust one is a unique titanium metal matrix composite (MMC). This paper discusses the materials and manufacturing methods used. The tensile, fatigue strength and creep resistance of the MMC are always superior to those for the typical heat-resistant steel of 21-4N. Both valves have achieved sufficient durability and reliability with a manufacturing cost acceptable for mass-produced automobile parts.

In preparation for compliance with California's SULEV standard and Euro STAGE 4 standard, which will take effect in 2002 and 2005, respectively, we have developed a laminated planar oxygen sensor. The developed sensor has the following characteristics: high thermal conductivity and superior dielectric characteristic, due to direct joining of the heater element alumina substrate and the sensor element zirconia electrolyte; low heat stress at temperature rise, due to optimized heater design; superior sensor protection from water droplets, and improved sensor response, due to optimized arrangement of intake holes in the sensor cover. With these characteristics, the developed oxygen sensor can be activated in 10 seconds after cold start. This report describes the technologies we used to develop the early-activation oxygen sensor.

In comparison with conventional hot forging process, powder forging process has much advantage such as good dimensional accuracy, minimum scattering of weight, etc. In spite of much advantage, the powder forged parts have not been mass-produced except for relatively simple shape parts because of technical and economic problems such as low productivity. Solving these problems, powder forging process was applied to connecting rods which required fatigue strength and minimum scattering of weight, and which were complex in shape. As a result, for the first time in the world, mass-production of powder forged connecting rods was carried out, and its properties are as follows; (1) Sufficient fatigue strength (2) Minimum scattering of weight (3) Good dimensional accuracy

The camshaft for an automobile engine is generally made of chilled cast iron. Due to increasing demand for higher performance, lawer maintenance and better fuel economy, it is difficult to make the cast iron camshaft lighter and/or more durable. In order to overcome these problems, development of an integral camshaft comprised of a sintered alloy cam piece for better wear resistance and steel tube for weight saving has been accomplished. In 1981 Toyota Motor Corporation successively started the mass-production of the sintered intergral camshaft for the new 1.8 liter ls engine. The significant advantages are as follows; (1) Weight saving (2) Excellent wear resistance (3) Improvement of lubrication system (4) Saving machining cost

This newly developed helical spring can be used at a stress level up to 1300 MPa. The material is composed of Fe-C-Si-Mn-Ni-Cr-Mo-V alloy. Its strength-toughness balance was greatly superior to that of other spring steels. To improve the fatigue strength at a higher stress level, decarburization at the surface upon austenitizing was severely controlled, applying induction heating. Then, a special shot peening process, introduced for the first time, was applied to obtain a surface residual stress at the surface of over 1000 MPa. The spring was first applied to a 1992 TOYOTA model car. Plans are to increase the use since the spring material achieves a weight reduction of at least 30 % and, possibly, 35 to 40 %.

According to the principle of pH measurement, an on-board type engine oil deterioration sensor has been developed. The developed sensor is composed of a Pb and oxidized stainless steel electrodes. The sensor signal shows a good linear relationship to the quasi-pH value of the oil. Especially in the region where the oil deterioration proceeds, the remaining basic additives in the oil is easily estimated from the sensor signal.