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Technical Paper

42 Catalytic Reduction of Marine Sterndrive Engine Emissions

2002-10-29
2002-32-1811
A 2001 General Motors 4.3 liter V-6 marine engine was baseline emissions tested and then equipped with catalysts. Emission reduction effects of exhaust gas recirculation (EGR) were also explored. Because of a U.S. Coast Guard requirement that inboard engine surface temperatures be kept below 200°F, the engine's exhaust system, including the catalysts, was water-cooled. Engine emissions were measured using the ISO-8178-E4 5-mode steady-state test for recreational marine engines. In baseline configuration, the engine produced 16.6 g HC+NOx/kW-hr, and 111 g CO/kW-hr. In closed-loop control with catalysts, HC+NOx emissions were reduced by 75 percent to 4.1 g/kW-hr, and CO emissions were reduced by 36 percent to 70 g/kW-hr of CO. The catalyzed engine was then installed in a Sea Ray 190 boat, and tested for water reversion on both fresh and salt water using National Marine Manufacturers Association procedures.
Technical Paper

A Study of the Potential Impact of Some Unregulated Motor Vehicle Emissions

1983-06-06
830987
Studies of emissions from vehicles equipped with catalysts have shown that some unregulated emissions can increase when a catalyst is used. One example of this is sulfuric acid, which has been studied extensively. Other unregulated emissions include ammonia and hydrogen cyanide. In a number of studies, these unregulated pollutant emissions have been measured from light-duty vehicles and heavy-duty engines. These emission levels were used in air quality dispersion models to predict the resultant air quality levels. The ambient concentrations predicted for each pollutant were then compared to suggested concentrations at which adverse health effects may be found to determine if additional monitoring or control would be indicated for these pollutants. It was determined that mobile source emissions of sulfuric acid, hydrogen cyanide, and ammonia do not in general result in ambient levels of concern for the air quality situations studied.
Technical Paper

Automotive Hydrocarbon Emission Patterns in the Measurement of Nonmethane Hydrocarbon Emission Rates

1977-02-01
770144
The advent of emission control technology has resulted in significant changes in both the total mass and detailed patterns of hydrocarbons emitted from automobiles. Emission rates of 56 hydrocarbons from 22 motor vehicles, including catalyst and noncatalyst configurations, were determined for the Federal Urban Driving Cycle. An increased relative abundance of methane is indicated for vehicles equipped with oxidation catalysts. In view of the photochemically non-reactive nature of methane, simple and economic procedures for determination of vehicle nonmethane hydrocarbon emission rates are evaluated. In general the procedures evaluated require independent total hydrocarbon and methane analysis, with the nonmethane hydrocarbon level calculated by difference. The procedures are evaluated by comparison of indicated nonmethane hydrocarbon emission rates with rates obtained by summation of individual compound rates determined by advanced gas chromatographic procedures.
Technical Paper

Catalysts for Methanol Vehicles

1987-11-01
872052
A Methanol catalyst test program has been conducted in two phases. The purpose of Phase I was to determine whether a base metal or lightly-loaded noble metal catalyst could reduce Methanol engine exhaust emissions with an efficiency comparable to conventional gasoline engine catalytic converters. The goal of Phase II was the reduction of aldehyde and unburned fuel emissions to very low levels by the use of noble metal catalysts with catalyst loadings higher than those in Phase I. Catalysts tested in Phase I were evaluated as three-way converters as well as under simulated oxidation catalyst conditions. Phase II catalysts were tested as three-way converters only. For Phase I, the most consistently efficient catalysts over the range of pollutants measured were platinum/rhodium configurations. None of the catalysts tested in Phase I were able to meet a NOx level of 1 gram per mile when operated in the oxidation mode.
Technical Paper

Detection of Catalyst Failure On-Vehicle Using the Dual Oxygen Sensor Method

1991-02-01
910561
On-vehicle proof-of-concept testing was conducted to evaluate the ability of the dual oxygen sensor catalyst evaluation method to identify serious losses in catalyst efficiency under actual vehicle operating conditions. The dual oxygen sensor method, which utilizes a comparison between an upstream oxygen sensor and an oxygen sensor placed downstream of the catalyst, was initially studied by the Environmental Protection Agency (EPA) under steady-state operating conditions on an engine dynamometer and reported in Clemmens, et al. (1).* At the time that study was released, questions were raised as to whether the technological concepts developed on a test fixture could be transferred to a vehicle operating under normal transient conditions.
Technical Paper

Development of Adjustment Factors for the EPA City and Highway MPG Values

1984-02-01
840496
This paper describes the development of adjustment factors applicable to the EPA City and Highway MPG values. The paper discusses the data bases used, and the analytical methods employed to arrive at adjustment factors of 0.90 for the EPA City MPG value and 0.78 for the EPA Highway MPG value.
Technical Paper

Emission Patterns of Diesel-Powered Passenger Cars - Part II

1977-02-01
770168
An experimental program was conducted to characterize the gaseous and particulate emissions from a 1975 Peugeot 504D light duty diesel-powered vehicle. The vehicle was tested over the 1975 Federal Test Procedure, Highway Fuel Economy Test, and Sulfate Emissions Test driving cycles using four different fuels covering a fair range of composition, density, and sulfur content. In addition to fuel economy and regulated gaseous emission measurements of hydrocarbons, carbon monoxide, and oxides of nitrogen, emission measurements were also obtained for non-regulated pollutants including sulfur dioxide, sulfates, aldehydes, benzo[a]pyrene, carbonyl sulfide, hydrogen cyanide, nonreactive hydrocarbons, and particulate matter. The results are discussed in terms of emission trends due to either fuel type or driving cycle influence.
Technical Paper

Emissions from Catalyst Cars Beyond 50 000 Miles and the Implications for the Federal Motor Vehicle Control Program

1978-02-01
780027
High mileage vehicles (in excess of 50,000 miles) contribute more than half of all vehicular emissions. With the new catalytic converter equipped cars, the proportional contribution of these vehicles may be even higher than for pre-catalyst vehicles. Thus a substantial portion of motor vehicle related air pollution may be caused by vehicles not subject to the manufacturer directed provisions of the Clean Air Act. This paper presents a modeling effort based on hypotheses and some preliminary data, and suggests some alternatives to combat this potential problem.
Technical Paper

Evaluation of Emission Control Technology Approaches for Heavy-Duty Gasoline Engines

1978-02-01
780646
This paper summarizes a laboratory effort toward reducing nine-mode cycle composite emissions and fuel consumption in a heavy-duty gasoline engine, while retaining current durability performance. Evaluations involved standard carburetors, a Dresserator inductor, a Bendix electronic fuel injection system, exhaust manifold thermal reactors, and exhaust gas recirculation, along with other components and engine operating parameters. A system consisting of electronic fuel injection, thermal reactors with air injection and exhaust gas recirculation, was assembled which met specified project goals. An oxidation catalyst was included as an add-on during the service accumulation demonstration. In addition, the driveability of this engine configuration was demonstrated.
Technical Paper

Evaluation of Heat Storage Technology for Quick Engine Warm-Up

1992-10-01
922244
The Schatz Heat Battery stores excess heat energy from the engine cooling system during vehicle operation. This excess energy may be returned to the coolant upon the ensuing cold start, shortening the engine warm-up period and decreasing cold start related emissions of unburned fuel and carbon monoxide (CO). A Heat Battery was evaluated on a test vehicle to determine its effect on unburned fuel emissions, CO emissions, and fuel economy over the cold start portion (Bag 1) of the Federal Test Procedure (FTP) at 24°C and -7°C ambient conditions. The Heat Battery was mounted in a vehicle fueled alternately with indolene clear (unleaded gasoline) and M85 high methanol blend fuels. Several Heat Battery/coolant flow configurations were evaluated to determine which would result in lowest cold start emissions.
Technical Paper

Evaluation of a Passenger Car Equipped with a Direct Injection Neat Methanol Engine

1992-02-01
920196
The cyclic and steady-state vehicle emissions, fuel economy, performance, and cold start behavior of an automobile equipped with a direct injection methanol engine are compared with those of three other comparable vehicles. One of the comparable vehicles was powered by a gasoline-fueled engine, and the other two were Diesels. One of the Diesel-powered vehicles was naturally aspirated and the other was turbocharged. All evaluations were made using the same road load horsepower and equivalent test weight. All the evaluations were conducted at low mileage. The emissions of the methanol vehicle are compared to California low emission vehicle standards, and to the emissions of another methanol vehicle.
Technical Paper

Exhaust Emissions from In-Use Passenger Cars Equipped with Three-Way Catalysts

1980-06-01
800823
This paper presents the results of an exhaust emission testing program conducted by the U.S. Environmental Protection Agency. The test vehicles were 1978–1980 passenger cars of various makes and models. Each of the 686 vehicles tested was equipped with a three-way catalyst system and was certified to California standards. The purpose of the program was to gather information on current systems in customer use for projections on the ability of the three-way system to meet emission standards of the future. The results indicate that these systems are capable of achieving low emission levels although high levels are also possible due to defects, deterioration, or tampering.
Technical Paper

Fuel Economy of In-Use Passenger Cars: Laboratory and Road

1981-06-01
810780
This report describes an evaluation of fuel economy of in-use passenger cars conducted by the U.S. Environmental Protection Agency during 1980. A total of 440 vehicles from the 1975-1980 model years were obtained from private owners in several cities. Each vehicle was tested according to the Federal Test Procedure and the Highway Fuel Economy Test. After the laboratory testing, the owners were asked to record their next four fuel purchases on a reply postcard. The results from the survey were analyzed and compared with the test results, estimates by the owner, and the values published in EPA's Gas Mileage Guide.
Technical Paper

In-Use Emissions of 1980 and 1981 Passenger Cars: Results of EPA Testing

1982-02-01
820975
This paper presents the results of several emission testing programs conducted by the U.S. Environmental Protection Agency. The test vehicles were primarily 1980 and 1981 passenger cars which were obtained at random from private owners. Some 1982 models were also tested. The 1328 vehicles were selected from the Los Angeles area as well as from a number of other low-altitude locations. The test sequence included the Federal Test Procedure, the Highway Fuel Economy Test and several short cycle tests. The primary purpose of the program was to gather information on current vehicles which could be used in calculations and projections of air quality and aid development of programs to improve it. The results of the program indicate that these vehicles are capable of maintaining low emission levels although high levels are also possible due to defects, deterioration, or tampering. Inspection/Maintenance programs are a feasible and effective means for correcting high levels when they occur.
Technical Paper

Investigation into the Vehicle Exhaust Emissions of High Percentage Ethanol Blends

1995-02-01
950777
Six in-use vehicles were tested on a baseline gasoline and nine gasoline/ethanol blends to determine the effect of ethanol content in fuels on automotive exhaust emissions and fuel economy. The baseline gasoline was representative of average summer gasoline and served as the base from which the other fuels were blended. For the majority of the vehicles, total hydrocarbon, and carbon monoxide exhaust emissions as well as fuel economy decreased while NOx and acetaldehyde exhaust emissions increased as the ethanol content in the test fuel increased. Formaldehyde and carbon dioxide emissions were relatively unaffected by the addition of ethanol. The emission responses to the increased fuel oxygen levels were consistent with what would be expected from leaning-out the air/fuel ratio for a spark ignition engine. The results are shown graphically and a linear regression is performed utilizing the method of least squares to investigate statistically significant trends in the data.
Technical Paper

Light Duty Automotive Fuel Economy … Trends through 1982

1982-02-01
820300
EPA Fuel economy figures are presented for model year 1982 cars and light duty trucks. Comparisons with the MPG figures of prior years are included. Sales penetrations of various vehicle, engine, and emission control design features are given, and domestic cars' MPG characteristics are compared to that of imports', gasoline vehicle MPG is compared to Diesel MPG, and 49-states MPG is compared to California MPG. Usage of newer vehicle technologies is continuing to increase, leading to continued growth in fuel economy capability in spite of stringent emission standards.
Technical Paper

Light Duty Automotive Fuel Economy … Trends thru 1985

1985-05-01
850550
This, the thirteenth in a series of papers on trends in EPA fuel economy, covers both passenger cars and light trucks and concentrates on the current model year, 1985. It differs from previous papers in two ways: 1) Model years 1975, 1980 and 1985 are highlighted, with the model years in between these rarely discussed; 2) The progress of the industry, as a whole, in improving fuel economy since 1975 is emphasized, and individual manufacturer data are de-emphasized. Conclusions are presented on the trends in fuel economy of the car and light truck fleets; the Domestic, European and Japanese market sectors; and various vehicle classes.
Technical Paper

Light Duty Automotive Fuel Economy …Trends through 1981

1981-02-01
810386
EPA new-model fuel economy figures are presented for passenger vehicles and light duty trucks (those with GVW ratings up to 8500 lbs). The 1981 models are emphasized, with some comparisons to prior years included. Reader familiarity with the EPA tests, data bases, and analytical methods is assumed. Principal two-way analyses include comparisons of domestic vs. import, gasoline vs. Diesel, and Federal (49-state) vs. California vehicles. Sales fractions for a number of vehicle and engine emission control design features are included. The principal finding is that increased use of newer vehicle and emission control technologies in 1981 has accompanied significant fuel economy gains in spite of the tougher 1981 emission standards.
Technical Paper

Light Duty Automotive Fuel Economy… Trends thru 1983

1983-02-01
830544
This, the eleventh in a series of Papers on EPA fuel economy trends, emphasizes the current Model Year (1983) as usual, but also gives increased emphasis to trends in vehicle technology, including catalyst and transmission subclasses. Final “CAFE”* production volumes and MPG figures have been used to update the data bases through the 1980 Model Year, and an analytic method used in the past to allocate year-to-year fleet MPG changes to specific causes, such as weight mix shifts, has been reinstituted. Conclusions are presented on the relation between fuel economy and emission standards, catalyst types, and transmission types.
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