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The octane appetite of an engine is frequently characterised by the so-called K value. It is usually assumed that K is dependent only on the thermodynamic conditions in the engine when knock occurs. In this work we test this hypothesis: further analysis was conducted on experimental results from SAE 2019-01-0035 in which a matrix of fuels was tested in a single cylinder engine. The fuels consisted of a relatively small number of components, thereby simplifying the analysis of the chemical kinetic proprieties. Through dividing the original fuel matrix into subsets, it was possible to explore the variation of K value with fuel properties. It was found that K value tends to increase slightly with RON. The explanation for this finding is that higher RON leads to advanced ignition timing (i.e. closer to MBT conditions) and advanced ignition timing results in faster combustion because of the higher pressures and temperatures reached in the thermodynamic trajectory.

Increasingly stringent regulations and rising fuel costs require that automotive manufacturers reduce their fleet CO2 emissions. Gasoline engine downsizing is one such technology at the forefront of improvements in fuel economy. As engine downsizing becomes more aggressive, normal engine operating points are moving into higher load regions, typically requiring over-fuelling to maintain exhaust gas temperatures within component protection limits and retarded ignition timings in order to mitigate knock and pre-ignition events. These two mechanisms are counterproductive, since the retarded ignition timing delays combustion, in turn raising exhaust gas temperature. A key process being used to inhibit the occurrence of these knock and pre-ignition phenomena is cooled exhaust gas recirculation (EGR). Cooled EGR lowers temperatures during the combustion process, reducing the possibility of knock, and can thus reduce or eliminate the need for over-fuelling.

Stringent regulations on fuel economy have driven major innovative changes in the internal combustion engine design. (E.g. CAFE fuel economy standards of 54.5 mpg by 2025 in the U.S) Vehicle manufacturers have implemented engine infrastructure changes such as downsizing, direct injection, higher compression ratios and turbo-charging/super-charging to achieve higher engine efficiencies. Fuel properties therefore, have to align with these engine changes in order to fully exploit the possible benefits. Fuel octane number is a key metric that enables high fuel efficiency in an engine. Greater resistance to auto-ignition (knock) of the fuel/air mixture allows engines to be operated at a higher compression ratio for a given quantity of intake charge without severely retarding the spark timing resulting in a greater torque per mass of fuel burnt. This attribute makes a high octane fuel a favorable hydrocarbon choice for modern high efficiency engines that aim for higher fuel economy.