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A wider use of biofuels in internal combustion engines could reduce the emissions of pollutants and greenhouse gases from the transport sector. In particular, due to stringent emission regulatory programs, compression ignition engine requires interventions aimed at reducing their polluting emissions. Ethanol, a low carbon fuel generally produced from biomass, is a promising alternative fuel applicable in compression ignition engines to reduce CO2 and soot emissions. In this paper, the application of a dual fuel diesel-ethanol configuration in a light-duty compression ignition engine has been numerically investigated. Ethanol is injected into the intake port, while diesel fuel is directly injected into the combustion chamber of the analyzed engine. CFD simulations have been carried out by means of the AVL Fire 3-D code. The operation at given engine load and speed has been simulated considering different diesel injection timings.