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A 2-D simulation of fluid dynamic and chemistry interaction following end gas autoignition has demonstrated three distinct modes of reaction, dependent upon the temperature gradient about an exothermic centre. All three modes (deflagration, developing detonation and thermal explosion) can contribute to knock; the developing detonation case, associated with intermediate temperature gradient, has been identified as the more damaging. The simulation code (LUMAD) has been used in a systematic parametric study designed to separate the complex interacting events which can lead to mixed modes in real engines. A most significant finding related to the sequential autoignition of multiple exothermic centres.

Numerical investigations are reported on the location of sites at which autoignition first develops in the end-gas ahead of a spark-ignited flame in a combustion chamber following rapid compression of an alkane + air mixture to high pressures and temperatures. Attention is drawn to the part played by the reactions that give rise to a negative temperature coefficient of reaction rate in an inhomogeneous temperature field. A ‘reduced’ kinetic mechanism was employed to model the spontaneous oxidation of n-alkanes. Flame propagation was described in terms of the ‘eddy dissipation concept’ and coupled to the more detailed mechanism by means of a switching algorithm. The CFD calculations were performed by use of KIVA II.

Reported in the current paper is a study of the effects of Nitric Oxide (NO) within a simulated Exhaust Gas Residual (sEGR) on Spark Ignition (SI) engine end gas autoignition. A modified version of the single cylinder Leeds University Ported Optical Engine Version 2 (LUPOE-2) engine was designed to completely eliminate retained residual gas and so allow unambiguous definition of the composition of the in-cylinder charge. The engine was alternately operated on stoichiometric mixtures of iso-octane, two Primary Reference Fuels (PRF), a Toluene Reference Fuel (TRF), and a commercially available Unleaded Gasoline (ULG) and air. These mixtures were diluted with sEGR (products of the complete stoichiometric combustion of the given fuel/air mixture) in mass fractions ranging from 0-15%; with and without 5000ppm NO (0.52% by mass) within that sEGR.

Modern engine developments result in very different gas pressure-temperature histories to those in RON/MON determination tests and strain the usefulness of those knock scales and their applicability in SI engine knock and HCCI autoignition onset models. In practice, autoignition times are complex functions of fuel chemistry and burning velocity (which affects pressure-temperature history), residual gas concentration and content of species such as NO. As a result, autoignition expressions prove inadequate for engine conditions straying far from those under which they were derived. The currently reported study was designed to separate some of these effects. Experimental pressure crank-angle histories were derived for an engine operated in skip-fire mode to eliminate residuals. The unburned temperature history was derived for each cycle and was used with a number of autoignition/knock models.