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Forthcoming worldwide emissions regulations will start regulating ammonia emissions from light duty vehicles. At present, most light duty vehicles are powered by gasoline spark ignition engines. Sources of ammonia emission from such engines can be in-cylinder reactions (i.e. combustion) or downstream reactions across aftertreatment devices, particularly three-way catalysts. The latter has been known to be a major source of ammonia emissions from gasoline vehicles and has been extensively investigated. The former (combustion), less so, and thus is the subject of this work. A two-zone thermodynamic spark ignition engine model with a comprehensive chemical kinetics framework (C3MechV3.3 mechanism), after being validated against experimental ammonia emissions data, is used to study ammonia formation during combustion.

Models for the convective heat transfer from the combustion gases to the walls inside a spark ignition engine are an important keystone in the simulation tools which are being developed to aid engine optimization. The existing models have, however, been cited to be inaccurate for hydrogen, one of the alternative fuels currently investigated. One possible explanation for this inaccuracy is that the models do not adequately capture the effect of the gas properties. These have never been varied in a wide range because air and ‘classical’ fossil fuels have similar values, but they are significantly different in the case of hydrogen. As a first step towards a fuel independent heat transfer model, we have investigated the effect of the gas properties on the heat flux in a spark ignition engine.

The burn rate and the instantaneous in-cylinder heat transfer have been studied experimentally in a spray-guided direct-injection spark-ignition engine with three different fuels: gasoline, iso-octane and toluene. The effects of the ignition timing, air fuel ratio, fuel injection timing and injection strategy (direct injection or port injection) on the burn rate and the in-cylinder heat transfer have been experimentally investigated at a standard mapping point (1500 rpm and 0.521 bar MAP) with the three different fuels. The burn rate analysis was deduced from the in-cylinder pressure measurement. A two-dimensional heat conduction model of the thermocouple was used to calculate the heat flux from the measured surface temperature. An engine thermodynamic simulation code was used to predict the gas-to-wall heat transfer.

Tax concessions promote the use of Liquefied Petroleum Gas (LPG) fuel for automotive use in Europe. Modelling of the LPG evaporation process shows the importance of drawing the liquid from the tank rather than the gas, otherwise the most volatile component (propane) is used more quickly and the composition of the remaining fuel changes. It is shown that the LPG components have similar calorific values to gasoline, however injecting the LPG as a gas into the inlet port causes a loss of volumetric efficiency and peak power. The experimental results showed: The LPG fuels have similar burn rates and optimum ignition timing to gasoline. The Lean Mixture Limit (LML) of the gaseous fuels was weaker than that for gasoline.

Exhaust gas temperatures in a 1.4 L, sparked ignition engine have been measured using fine wire thermocouples at different loads and speeds. However the thermocouples are not fast enough to resolve the rapid change in exhaust temperature. This paper discusses a new thermocouple compensation technique to resolve the cycle-by-cycle variations in exhaust temperature by segmentation. Simulation results show that the technique can find the lower time constants during blowdown, reducing the bias from 28 to 4%. Several estimators and model structures have been compared. The best one is the difference equation-least squares technique, which has the combined error between -4.4 to 7.6% at 60 dB signal-to-noise ratio. The compensated temperatures have been compared against combustion parameters on a cycle-by-cycle basis. The results show that the cycle-by-cycle variations of the exhaust temperatures and combustion are correlated.

In-cylinder temperatures and their cyclic variations strongly influence many aspects of internal combustion engine operation, from chemical reaction rates determining the production of NOx and particulate matter to the tendency for auto-ignition leading to knock in spark ignition engines. Spatially resolved measurements of temperature can provide insights into such processes and enable validation of Computational Fluid Dynamics simulations used to model engine performance and guide engine design. This work uses a combination of Two-Colour Planar Laser Induced Fluorescence (TC-PLIF) and Laser Induced Grating Spectroscopy (LIGS) to measure the in-cylinder temperature distributions of a firing optically accessible spark ignition engine. TC-PLIF performs 2-D temperature measurements using fluorescence emission in two different wavelength bands but requires calibration under conditions of known temperature, pressure and composition.

The first part of the paper is a brief review of the techniques needed for measuring the voltage and current during the ignition process. These techniques have been used in test rigs and an engine to gain insights into the breakdown and subsequent discharge development. New correlations are presented for breakdown voltage as functions of spark plug gap, gas composition, temperature and pressure. The discharge voltage is affected by the flow, so an elevated pressure flow rig was used to look at the effect of flow and pressure on the discharge voltage history, with different stored energies in the ignition coil. This study led to a model for the discharge voltage history, from which it was possible to deduce the flow velocity through the spark plug gap. Finally, these techniques were applied to a single cylinder, 4-valve, pent-roof combustion chamber SI engine, for determining the cycle-by-cycle variations in velocity through the spark plug at the time of ignition.

Color-ratio pyrometry (CRP) is a technique for estimating the temperature and loading of soot, based on its thermal emission spectrum. This technique is contrasted with conventional two-color pyrometry which requires absolute measurements of the radiation intensity, either at two specific wavelengths or ranges of wavelengths. CRP uses two ratios, obtained by measuring the radiation intensity for three wavelengths or wavelength bands. CRP has been implemented here by using a digital CCD camera, and full details of the calibration are reported. Because of uncertainties in the emissivity of reference sources (such as tungsten ribbon lamps, in which the emissivity depends on temperature and wavelength), then a spectroscopic calibration of the CCD camera has been used. Use of a CCD camera is not straightforward because of internal digital signal processing (DSP), so full details are given of the calibration and technique implementation.

Low temperature heat release (LTHR) has been of interest to researchers for its potential to mitigate knock in spark ignition (SI) engines and control auto-ignition in advanced compression ignition (ACI) engines. Previous studies have identified and investigated LTHR in both ACI and SI engines before the main high temperature heat release (HTHR) event by appropriately curating the in-cylinder thermal state during compression, or in the case of SI engines, timing the spark discharge late to reveal LTHR (sometimes referred to as pre-spark heat release). In this work, LTHR is demonstrated in isolation from HTHR events. Tests were run on motored single-cylinder engines and inlet air temperatures and pressures were adjusted to realise LTHR from n-heptane and iso-octane (2,2,4-trimethylpentane) without entering the HTHR regime. LTHR was observed for a lean n-heptane-air mixture at inlet temperatures ranging from 60°C to 100°C and inlet pressures of 0.9 bar (absolute).

Extending the planar Particle Image Velocimetry (PIV) technique to enable measurements on multiple planes simultaneously allows for some of the 3 dimensional nature of unsteady flow fields to be investigated. This requires less hardware and retains the typically higher spatial resolution of planar PIV compared to fully 3-dimensional PIV techniques. Performing multi-plane PIV measurements requires the light scattered from the different measurement planes to be distinguishable. This may be achieved by using different laser wavelengths which adds significantly to the expense and complexity of the system, by using different light sheet polarisations which is challenging for engine measurements through windows due to stress-induced birefringence, or by making alternating measurements of each plane which sacrifices the simultaneity of the flow measurement across multiple planes.

The blending of oxygenated compounds with gasoline is projected to increase because oxygenate fuels can be produced renewably, and because their high octane rating allows them to be used in substitution of the aromatic fraction in gasoline. Blending oxygenates with gasoline changes the fuels' properties and can have a profound affect on the distillation curve, both of which are known to affect engine-out emissions. In this work, the effect of blending methanol and ethanol with gasoline on unburned hydrocarbon and particulate emissions is experimentally determined in a spray guided direct injection engine. Particulate number concentration and size distribution were measured using a Cambustion DMS500. These data are presented for different air fuel ratios, loads, ignition timings and injection timings. In addition, the ASTM D86 distillation curve was modeled using the binary activity coefficients method for the fuel blends used in the experiments.

A thermodynamic model of spark ignition engine combustion, with multiple burned gas zones, has been extended to permit the different burned gas zones to have different mixture strengths. The NO formation is predicted in each burned gas zone using the extended Zeldovich mechanism. The model has been used to study stratified charge spark ignition engine combustion, in order to investigate the influence of overall equivalence ratio and degree of stratification on the NO emissions and the engine brake specific fuel consumption. For fixed throttle operation, it is concluded that the best trade-off is with an overall weak mixture that is close to homogeneous. For maximum power output using a slightly rich of stoichiometric mixture, then the mixture should also be close to homogeneous.

This paper has two parts. The first compares the measured burned gas temperature using Coherent Anti-Stokes Raman Scattering (CARS) with the predictions of a multiple zone computer simulation of combustion. The second part describes a system that is capable of determining the heat flux into the combustion chamber by means of measuring the chamber surface temperature. It is shown that the multi-zone computer simulation can accurately predict the burned gas temperature once the fuel burn rate has been analyzed and the model tuned correctly. The effect of different fuels (methane and iso-octane) on the burned gas temperature is reported. A high burn rate or more advanced ignition timing gave a lower burned gas temperature towards the end of the engine cycle. The surface heat flux was deduced from measurements of the surface temperature by using a finite difference method.

Knocking combustion places a major limit on the performance and efficiency of spark ignition engines. Spontaneous ignition of the unburned air-fuel mixture ahead of the flame front leads to a rapid release of energy, which produces pressure waves that cause the engine structure to vibrate at its natural frequencies and produce an audible ‘pinging’ sound. In extreme cases of knock, increased temperatures and pressures in the cylinder can cause severe engine damage. Damage is thought to be caused by thermal strain effects that are directly related to the heat flux. Since it will be the maximum values that are potentially the most damaging, then the heat flux needs to be measured on a cycle-by-cycle basis. Previous work has correlated heat flux with the pressure fluctuations on an average basis, but the work here shows a correlation on a cycle-by-cycle basis. The in-cylinder pressure and surface temperature were measured using a pressure transducer and eroding-type thermocouple.

Particulate Matter (PM) legislation for gasoline engines and the introduction of gasoline/ethanol blends, make it important to know the effect of fuel composition on PM emissions. Tests have been conducted with fuels of known composition in both a single-cylinder engine and V8 engine with a three-way catalyst. The V8 engine used an unleaded gasoline (PURA) with known composition and distillation characteristics as a base fuel and with 10% by volume ethanol. The single-cylinder engine used a 65% iso-octane - 35% toluene mixture as its base fuel. The engines had essentially the same combustion system, with a centrally mounted 6-hole spray-guided direct injection system. Particle size distributions were recorded and these have also been converted to mass distributions. Filter samples were taken for thermo-gravimetric analysis (TGA) to give composition information. Both engines were operated at 1500 rpm under part load.