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Color-ratio pyrometry (CRP) is a technique for estimating the temperature and loading of soot, based on its thermal emission spectrum. This technique is contrasted with conventional two-color pyrometry which requires absolute measurements of the radiation intensity, either at two specific wavelengths or ranges of wavelengths. CRP uses two ratios, obtained by measuring the radiation intensity for three wavelengths or wavelength bands. CRP has been implemented here by using a digital CCD camera, and full details of the calibration are reported. Because of uncertainties in the emissivity of reference sources (such as tungsten ribbon lamps, in which the emissivity depends on temperature and wavelength), then a spectroscopic calibration of the CCD camera has been used. Use of a CCD camera is not straightforward because of internal digital signal processing (DSP), so full details are given of the calibration and technique implementation.