Search Results

An overview is given on the state of the art of a new catalytic exhaust gas aftertreatment device for diesel engines. The function of a precious metal based, flow-through type diesel oxidation catalyst is explained. Much attention is paid to the durability of the diesel oxidation catalyst and especially to the influence of poisoning elements on the catalytic activity. Detailed data on the interaction of poisoning elements such as sulfur, zinc and phosphorus with the catalytic active sites are given. Finally it is demonstrated that it is possible to meet the stringent emission standards for diesel passenger cars in Europe with a new catalyst generation over 80.000 km AMA aging.

The study of oil emission is of essential interest for the engine development of modern cars, as well as for the understanding of hydrocarbon emissions especially during cold start conditions. A laser mass spectrometer has been used to measure single aromatic hydrocarbons in unconditioned exhaust gas of a H2-fueled engine at stationary and transient motor operation. These compounds represent unburned oil constituents. The measurements were accompanied by FID and GC-FID measurements of hydrocarbons which represent the burned oil constituents. The total oil consumption has been determined by measuring the oil sampled by freezing and weighing. It has been concluded that only 10 % of the oil consumption via exhaust gas has burned in the cylinders. A correlation of the emission of single oil-based components at ppb level detected with the laser mass spectrometer to the total motor oil emission has been found.

External Exhaust Gas Recirculation (EGR) provides an opportunity to increase the efficiency of turbocharged spark-ignition engines. Of the competing technologies and configurations, Low-Pressure EGR (LP-EGR) is the most challenging in terms of its dynamic behavior. Only some of the stationary feasible potential can be used during dynamic engine operation. To guarantee fuel consumption-optimized engine operation with no instabilities, a load point-dependent limitation of the EGR rate or alternatively an adaptation of the operating point to the actual EGR rate is crucial. For this purpose, a precise knowledge of efficiency and combustion variance is necessary. Since the operating state includes the actual EGR rate, it has an additional dimension, which usually results in an immense measuring effort.

In this paper a fast NOx model is presented which can be used for engine optimization, aftertreatment control or virtual mapping. A cylinder pressure trace is required as input data. High calculation speed is obtained by using table interpolation to calculate equilibrium temperatures and species concentrations. Test data from a single-cylinder engine and from a complete six-cylinder engine have been used for calibration and validation of the model. The model produces results of good agreement with emission measurements using approximately 50 combustion product zones and a calculation time of one second per engine cycle. Different compression ratios, EGR rates, injection timing, inlet pressures etc. were used in the validation tests.

The California LEV1 II program will be introduced in the year 2003 and requires a further reduction of the exhaust emissions of passenger cars. The cold start emissions represent the main part of the total emissions of the FTP2-Cycle. Cold start emissions can be efficiently reduced by injecting secondary air (SA) in the exhaust port making compliance with the most stringent standards possible. The thermochemical conditions (mixing rate and temperature of secondary air and exhaust gas, exhaust gas composition, etc) prevailing in the exhaust system are described in this paper. This provides knowledge of the conditions for auto ignition of the mixture within the exhaust manifold. The thus established exothermal reaction (exhaust gas post-combustion) results in a shorter time to light-off temperature of the catalyst. The mechanisms of this combustion are studied at different engine idle conditions.

The two major problems of diesel emission control are the reduction of nitrogen oxides and particulates. This paper describes experimental investigations to achieve both a separation of soot particles as well as a catalytic NOx reduction with hydrocarbons under lean diesel exhaust gas conditions. For that purpose a diesel particle trap is coated with a catalyst based on a Pt containing zeolite. Preliminary studies have been performed on the catalytic NOx reduction to evaluate the efficiency of a Pt/zeolite system as well as to establish the impact of operation conditions on the catalyst performance. The activity of the prepared samples (catalytic coating on particle trap) has been determined under model gas test conditions. Much attention has been focussed on the steady-state kinetics of the surface processes. Another aspect considered is the N2O formation which can be reduced, when alkali-earth or rare-earth oxides are added to the catalyst system.

Several different possibilities will be described and discussed on the processes of reducing NOx in lean-burn gasoline and diesel engines. In-company studies were conducted on zeolitic catalysts. With lean-burn spark-ignition engines, hydrocarbons in the exhaust gas act as a reducing agent. In stationary conditions at λ = 1.2, NOx conversion rates of approx. 45 % were achieved. With diesel engines, the only promising variant is SCR technology using urea as a reducing agent. The remaining problems are still the low space velocity and the narrow temperature window of the catalyst. The production of reaction products and secondary reactions of urea with other components in the diesel exhaust gas are still unclarified.

A new method for the analysis of the gas flow in an internal combustion engine has been developed. It is based on the interactive coupling between commercially available three (STAR-CD) and one dimensional (PROMO) fluid dynamics codes. With this method the detailed transient flow distribution for any engine component of interest can be calculated taking into account the overall gas dynamic interaction with other engine components. The underlying physics and numerics are outlined. A description of the coupling procedure ensuring proper communication between the two computer codes is given. Also addressed is the averaging procedure adopted at the 3D boundaries, including the influence of the 1D/3D interface placement. A first application of this new method is presented, in which the gas flow in a turbo-charged DI-diesel-engine is simulated.

This paper compares 4 different EGR systems by means of simulation in GT-Power. The demands of optimum massive EGR and fresh air rates were based on experimental results. The experimental data were used to calibrate the model and ROHR, in particular. The main aim was to investigate the influence of pumping work on engine and vehicle fuel consumption (thus CO2 production) in different EGR layouts using optimum VG turbine control. These EGR systems differ in the source of pressure drop between the exhaust and intake pipes. Firstly, the engine settings were optimized under steady operation - BSFC was minimized while taking into account both the required EGR rate and fresh air mass flow. Secondly, transient simulations (NEDC cycle) were carried out - a full engine model was used to obtain detailed information on important parameters. The study shows the necessity to use natural pressure differences or renewable pressure losses if reasonable fuel consumption is to be achieved.

The regulations for mobile applications will become stricter in Euro 6 and further emission levels and require the use of active aftertreatment methods for NOX and particulate matter. SCR and LNT have been both used commercially for mobile NOX removal. An alternative system is based on the combination of these two technologies. Developments of catalysts and whole systems as well as final vehicle demonstrations are discussed in this study. The small and full-size catalyst development experiments resulted in PtRh/LNT with optimized noble metal loadings and Cu-SCR catalyst having a high durability and ammonia adsorption capacity. For this study, an aftertreatment system consisting of LNT plus exhaust bypass, passive SCR and engine independent reductant supply by on-board exhaust fuel reforming was developed and investigated. The concept definition considers NOX conversion, CO2 drawback and system complexity.

The spray development, combustion and emissions in a 1.9L optical, four-cylinder, direct-injection diesel engine were investigated by means of pressure analysis, high-speed cinematography, the two-colour method and exhaust gas analysis for various levels of exhaust gas recirculation (EGR), three EGR temperatures (uncontrolled, hot and cold) and three fuels (diesel, n-heptane and a two-component fuel 7D3N). Engine operating conditions included 1000 rpm/idle and 2000 rpm/2bar with EGR-rates ranging from 0 to 70%. Independent of rate, EGR was found to have a very small effect on spray angle and spray tip penetration but the auto-ignition sites seemed to increase in size and number at higher EGR-rates with associated reduction in the flame luminosity and flame temperature, by, say, 100K at 50% EGR.

The production of the BMW ALPINA B12 5.7 with Switch-Tronic transmission provides the markets of Europe and Japan with an exclusive, luxury-orientated, high performance limited series limousine. This is the first vehicle worldwide to be fitted with the progressive exhaust gas aftertreatment technology known as the Electrically Heated Catalyst (EHC), in which the effectiveness of the power utilized is increased significantly by an alternating heating process for both catalytic converters. Only since this achievement has the implementation of the EHC been viable without extensive modification to the battery and alternator. With this exhaust gas aftertreatment concept, the emissions of this high performance vehicle will fall to less than half the maximum permissible for compliance with 1996 emission standards.

Meeting current exhaust emission standards requires rapid catalyst light-off. Closed-coupled catalysts are commonly used to reduce light-off time by minimizing exhaust heat loss between the engine and catalyst. However, this exhaust gas system design leads to a coupling of catalyst heating and engine operation. An engine-independent exhaust gas aftertreatment can be realized by combining a burner heated catalyst system (BHC) with an underfloor catalyst located far away from the engine. This paper describes some basic characteristics of such a BHC system and the results of fitting this system into a Volkswagen Touareg where a single catalyst was located about 1.8 m downstream of the engine. Nevertheless, it was possible to reach about 50% of the current European emission standard EU 4 without additional fuel consumption caused by the BHC system.

For substantial reduction of fuel consumption of their vehicle fleet, Volkswagen AG has decided to develop spark-ignition engines with direct fuel injection. To launch this new engine concept with stratified lean operation mode while at the same time meeting the stringent EU IV emission standards, it was necessary to develop a suitable exhaust gas aftertreatment system. This was achieved as part of an intensive co-operation between Volkswagen AG and OMG, formerly dmc2 Degussa Metals Catalysts Cerdec AG. The paper describes the demands for exhaust gas aftertreatment due to lean burn operation. In addition the main development steps of the exhaust gas aftertreatment system for Volkswagen FSI engines and catalyst durability over vehicle lifetime are discussed. Focus is laid on the catalyst system design and coating variations. Volkswagen developed a new closed-loop emission control management system which uses NOx-sensor signals for the first time worldwide.

A uniform flow distribution at converter inlet is one of the fundamental requirements to meet high catalytic efficiency. Commonly used tools for optimization of the inlet flow distribution are flow measurements as well as CFD analysis. This paper puts emphasis on the experimental procedures and results. The interaction of flow measurements and CFD is outlined. The exhaust gas flow is transient, compressible and hot, making in-situ flow measurements very complex. On the other hand, to utilize the advantages of flow testing at steady-state and cold conditions the significance of these results has to be verified first. CFD analysis under different boundary conditions prove that - in a first approach - the flow situation can be regarded as a sequence of successive, steady-state situations. Using the Reynolds analogy a formula for the steady-state, cold test mass flow is derived, taking into account the cylinder displacement and the rated speed.

Removing toxic impurities from gaseous flows by electrical gas discharges has been investigated for almost two decades. Cold discharges, i.e. plasmas in which the electrons are not in thermal equilibrium with neutrals and ions, are a potential method for the conversion of NOx (NO, NO2) and hydrocarbons (HC) in exhaust gases of cars. In this work we present experimental results of removing nitric oxides in synthetic and real diesel exhaust and compare these results with modelling results using a spatially homogeneous, time-dependent model. We also compare results obtained by a two-dimensional, time-dependent model with experimental data measured with the LIF-method to test the accuracy of our numerical simulation results for the discharge behaviour.

One dimensional Spontaneous Raman Scattering measurements (RS) have been performed in a spray (standard gasoline, one-component and multi-component model fuels) which was operated in a high-temperature, high-pressure chamber, so that realistic engine conditions have been simulated. The present work investigates under what conditions 1D-RS can be employed for fuel/air-ratio measurements in realistic DI gasoline sprays. The distance from the spray axis has been determined, til that, coming from the outside, quantitative Raman measurement are possible. The equivalence ratio has been quantified for the one component fuel close to the spray. It turns out that the measurement error depends strongly on the type of fuel. These problems are caused by the PAH (polycyclic aromatic hydrocarbon) content of the fuel, which leads to interfering laser-induced fluorescence signals.

Internal combustion engines with lean homogeneous charge and auto-ignition combustion of gasoline fuels have the capability to significantly reduce fuel consumption and realize ultra-low engine-out NOx emissions. Group research of Volkswagen AG has therefore defined the Gasoline Compression Ignition combustion (GCI®) concept. A detailed investigation of this novel combustion process has been carried out on test bench engines and test vehicles by group research of Volkswagen AG and IAV GmbH Gifhorn. Experimental results confirm the theoretically expected potential for improved efficiency and emissions behavior. Volkswagen AG and IAV GmbH will utilize a highly flexible externally supercharged variable valve train (VVT) engine for future investigations to extend the understanding of gas exchange and EGR strategy as well as the boost demands of gasoline auto-ignition combustion processes.

Flame Ionization Detectors (FID) can be used to detect organic hydrocarbons that occur in plastics, lacquers, adhesives, solvents and gasoline. These substances are ionized in the hydrogen flame of the FID. The ionization current that is produced depends on the amount of hydrocarbon in the sample. With the lowering of emissions limits, measuring instruments, including the FID, have to be able to detect very low values. For SULEV (Super-Ultra Low Emissions Vehicle) measurements the accuracy and also the general applicability of the CVS (Constant Volume Sampling) measuring technique are now questioned. Basic understanding is necessary to ask the right questions. One important issue is the science behind the measurement principle of the FID. And in this case especially the influence of contamination of the operating gases, cross sensitivity and data processing on the Limit of Detection (LOD).

Apart from the reduction of engine-out emissions from the powerplant, the development of an efficient and reliable catalytic converter heating system is an important task of automotive engineering in the future to meet standards that will require reduction of cold start emissions. Carrying out a comprehensive study in this field, BMW has tested and evaluated possible solutions to this challenge. In additon to the electrically heated catalytic converter (E-cat) and the afterburner chamber, an incorporated burner system would meet the requirement for fast catalyst light-off in the future, particularly in the case of larger engines.