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Due to the high power and energy density and also relative safety, lithium ion batteries are receiving increasing acceptability in industrial applications especially in transportation systems with electric traction such as electric vehicles and hybrid electric vehicles. In this regard, to ensure performance reliability, accurate modeling of calendar life of such batteries is a necessity. In fact, potential failure of Li-ion battery packs remains a barrier to commercialization. Battery pack life is a critical feature to warranty and maintenance planning for hybrid vehicles, and will require adaptive control systems to account for the loss in vehicle range, and loss in battery charge and discharge efficiency. Failure not only results in large replacement costs, but also potential safety concerns such as overheating or short circuiting which may lead to fires.

A major challenge in the development of the next generation electric and hybrid electric vehicle (EV and HEV) technology is the control and management of heat generation and operating temperatures. Vehicle performance, reliability and ultimately consumer market adoption are integrally dependent on successful battery thermal management designs. In addition to this, crucial to thermal modeling is accurate thermo-physical property input. Therefore, to design a thermal management system and for thermal modeling, a designer must study the thermal characteristics of batteries. This work presents a purely experimental thermal characterization of thermo-physical properties of a lithium-ion battery utilizing a promising electrode material, LiFePO4, in a prismatic pouch configuration. In this research, the thermal resistance and corresponding thermal conductivity of prismatic battery materials is evaluated.