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The control of nitrogen oxide and smoke emissions in diesel engines has been one of the key researches in both the academia and industry. Nitrogen oxides can be effectively suppressed by the use of exhaust gas recirculation (EGR). However, the introduction of inert exhaust gas into the engine intake is often associated with high smoke emissions. To overcome these issues there have been a number of proposed strategies, one of the more promising being the use of low temperature combustion enabled with heavy EGR. This has the potential to achieve simultaneously low emissions of nitrogen oxide and smoke. However, a quantitative way to identify the transition zone between high temperature combustion and low temperature combustion has still not been fully explored. The combustion becomes even more complicated when ethanol fuel is used as a partial substitution for diesel fuel.