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The development and validation of detailed simulation models of in-cylinder combustion, emission formation mechanisms and reaction kinetics in the exhaust system are of crucial importance for the design of future low-emission powertrain concepts. To investigate emission formation mechanisms on one side and to create a solid basis for the validation of simulation methodologies (e.g. 3D-CFD, multi-dimensional in-cylinder models, etc.) on the other side, specific detailed measurements in the exhaust system are required. In particular, the hydrocarbon (HC) emissions are difficult to be investigated in simulation and experimentally, due to their complex composition and their post-oxidation in the exhaust system. In this work, different emission measurement devices were used to track the emission level and composition at different distances from the cylinder along the exhaust manifold, from the exhaust valve onwards.

Liquefied Petroleum Gas direct injection (LPG DI) is believed to be the key enabler for the adaption of modern downsized gasoline engines to the usage of LPG, since LPG DI avoids the significant low end torque drop, which goes along with the application of conventional LPG port fuel injection systems to downsized gasoline DI engines, and provides higher combustion efficiencies. However, especially the high vapor pressure of C3 hydrocarbons can result in hot fuel handling issues as evaporation or even in reaching the supercritical state of LPG upstream or inside the high pressure pump (HPP). This is particularly critical under hot soak conditions. As a result of a rapid fuel density drop close to the supercritical point, the HPP is not able to keep the rail pressure constant and the engine stalls.

Downsizing of highly-boosted spark-ignition (SI) engines is limited by pre-ignition, which may lead to extremely strong knocking and severe engine damage. Unfortunately, the concerning mechanisms are generally not yet fully understood, although several possible reasons have been suggested in previous research. The primary objective of the present paper is to investigate the influence of molecular bio-fuel structure on the locations of pre-ignition in a realistic, highly-charged SI engine at low speed by state-of-the-art optical measurements. The latter are conducted by using a high-sensitivity UV endoscope and an intensified high-speed camera. Two recently tested bio-fuels, namely tetrahydro-2-methylfuran (2-MTHF) and 2-methylfuran (2-MF), are investigated. Compared to conventional fuels, they have potential advantages in the well-to-tank balance. In addition, both neat ethanol and conventional gasoline are used as fuels.