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An overview is given on the state of the art of a new catalytic exhaust gas aftertreatment device for diesel engines. The function of a precious metal based, flow-through type diesel oxidation catalyst is explained. Much attention is paid to the durability of the diesel oxidation catalyst and especially to the influence of poisoning elements on the catalytic activity. Detailed data on the interaction of poisoning elements such as sulfur, zinc and phosphorus with the catalytic active sites are given. Finally it is demonstrated that it is possible to meet the stringent emission standards for diesel passenger cars in Europe with a new catalyst generation over 80.000 km AMA aging.

The California LEV1 II program will be introduced in the year 2003 and requires a further reduction of the exhaust emissions of passenger cars. The cold start emissions represent the main part of the total emissions of the FTP2-Cycle. Cold start emissions can be efficiently reduced by injecting secondary air (SA) in the exhaust port making compliance with the most stringent standards possible. The thermochemical conditions (mixing rate and temperature of secondary air and exhaust gas, exhaust gas composition, etc) prevailing in the exhaust system are described in this paper. This provides knowledge of the conditions for auto ignition of the mixture within the exhaust manifold. The thus established exothermal reaction (exhaust gas post-combustion) results in a shorter time to light-off temperature of the catalyst. The mechanisms of this combustion are studied at different engine idle conditions.

Under city driving conditions, the powertrain represents one of the major vehicle exterior noise sources. Especially at idle and during full load acceleration, the oil pan contributes significantly to the overall powertrain sound emission. The engine oilpan can be a significant contributor to the powertrain radiated sound levels. Passive optimization measures, such as structural optimization and acoustic shielding, can be limited by e.g. light-weight design, package and thermal constraints. Therefore, the potential of the Active Structure Acoustic Control (ASAC) method for noise reduction was investigated within the EU-sponsored project InMAR. The method has proven to have significant noise reduction potential with respect to oil pan vibration induced noise. The paper reports on activities within the InMAR project with regard to a passenger car oil pan application of an ASAC system based on piezo-ceramic foil technology.

The overall perception of a vehicle's quality is significantly influenced by its interior noise characteristics. Therefore, it is important to strike a balance between “pleasant” and “dynamic” sound that fits the customer requirements with respect to vehicle brand and class [1]. Typically, a significant share of the interior vehicle noise is transferred through structure-borne paths. Hence, the powertrain mounting system plays an important role in designing the interior noise. This paper describes an application of the method of vehicle interior noise simulation (VINS) to achieve a characteristic interior sound. This approach is based on separate measurements (or calculations) of excitations and transfer functions and subsequent calculation of the interior noise in the time domain.

The prevention of any brake noise or brake-induced body vibrations is a key development target firmly integrated in the car development process. Emphasis is placed here on disc brake judder that is attributable to thickness variations in the disc. These deviations from the ideal plane surface can be caused either by wear and corrosion or by thermal stresses (changes within the microstructure of the disc material). They are termed “cold judder” and “thermal judder” respectively. During braking, possible vibration excitation passes through a wide frequency band due to the coupling between the judder frequency and the wheel rotational speed, and thus, resonant frequencies of many vehicle components can be excited. This includes wheel suspension components and the steering column. In this paper, it is reported on extensive investigations into the topic of “cold judder”.

Several different possibilities will be described and discussed on the processes of reducing NOx in lean-burn gasoline and diesel engines. In-company studies were conducted on zeolitic catalysts. With lean-burn spark-ignition engines, hydrocarbons in the exhaust gas act as a reducing agent. In stationary conditions at λ = 1.2, NOx conversion rates of approx. 45 % were achieved. With diesel engines, the only promising variant is SCR technology using urea as a reducing agent. The remaining problems are still the low space velocity and the narrow temperature window of the catalyst. The production of reaction products and secondary reactions of urea with other components in the diesel exhaust gas are still unclarified.

The regulations for mobile applications will become stricter in Euro 6 and further emission levels and require the use of active aftertreatment methods for NOX and particulate matter. SCR and LNT have been both used commercially for mobile NOX removal. An alternative system is based on the combination of these two technologies. Developments of catalysts and whole systems as well as final vehicle demonstrations are discussed in this study. The small and full-size catalyst development experiments resulted in PtRh/LNT with optimized noble metal loadings and Cu-SCR catalyst having a high durability and ammonia adsorption capacity. For this study, an aftertreatment system consisting of LNT plus exhaust bypass, passive SCR and engine independent reductant supply by on-board exhaust fuel reforming was developed and investigated. The concept definition considers NOX conversion, CO2 drawback and system complexity.

Meeting current exhaust emission standards requires rapid catalyst light-off. Closed-coupled catalysts are commonly used to reduce light-off time by minimizing exhaust heat loss between the engine and catalyst. However, this exhaust gas system design leads to a coupling of catalyst heating and engine operation. An engine-independent exhaust gas aftertreatment can be realized by combining a burner heated catalyst system (BHC) with an underfloor catalyst located far away from the engine. This paper describes some basic characteristics of such a BHC system and the results of fitting this system into a Volkswagen Touareg where a single catalyst was located about 1.8 m downstream of the engine. Nevertheless, it was possible to reach about 50% of the current European emission standard EU 4 without additional fuel consumption caused by the BHC system.

For substantial reduction of fuel consumption of their vehicle fleet, Volkswagen AG has decided to develop spark-ignition engines with direct fuel injection. To launch this new engine concept with stratified lean operation mode while at the same time meeting the stringent EU IV emission standards, it was necessary to develop a suitable exhaust gas aftertreatment system. This was achieved as part of an intensive co-operation between Volkswagen AG and OMG, formerly dmc2 Degussa Metals Catalysts Cerdec AG. The paper describes the demands for exhaust gas aftertreatment due to lean burn operation. In addition the main development steps of the exhaust gas aftertreatment system for Volkswagen FSI engines and catalyst durability over vehicle lifetime are discussed. Focus is laid on the catalyst system design and coating variations. Volkswagen developed a new closed-loop emission control management system which uses NOx-sensor signals for the first time worldwide.

A uniform flow distribution at converter inlet is one of the fundamental requirements to meet high catalytic efficiency. Commonly used tools for optimization of the inlet flow distribution are flow measurements as well as CFD analysis. This paper puts emphasis on the experimental procedures and results. The interaction of flow measurements and CFD is outlined. The exhaust gas flow is transient, compressible and hot, making in-situ flow measurements very complex. On the other hand, to utilize the advantages of flow testing at steady-state and cold conditions the significance of these results has to be verified first. CFD analysis under different boundary conditions prove that - in a first approach - the flow situation can be regarded as a sequence of successive, steady-state situations. Using the Reynolds analogy a formula for the steady-state, cold test mass flow is derived, taking into account the cylinder displacement and the rated speed.

The EPEFE study (European Programme on Emissions, Fuels and Engine Technologies), /1/ and other programmes have identified an increase in tailpipe NOx emissions with reduced gasoline aromatics content for modern 3-way controlled catalyst vehicles. This effect occurs with fully warmed-up catalyst under closed-loop operation. In order to understand the reasons for this effect VW and Shell have mechanistically investigated the effects of fuel properties on EMS (engine management system) and catalyst performance. Fuels with independent variation of oxygen, aromatics and mid-range volatility were tested in different VW engines. λ was monitored using sensors located both pre and post catalyst. The results confirmed that reducing gasoline aromatics content reduced engine-out emissions but increased tailpipe NOx emissions. It could be shown that differences in H/C ratio led to differences in the hydrogen content of engine-out emissions which affected the reading of the λ sensor.

Dust testing of vehicles on unpaved roads is crucial in the development process for automotive manufacturers. These tests aim to ensure the functionality of locking systems in dusty conditions, minimize dust concentration inside the vehicle, and enhance customer comfort by preventing dust accumulation on the car body. Additionally, deposition on safety-critical parts, such as windshields and sensors, can pose threats to driver vision and autonomous driving capabilities. Currently, dust tests are primarily conducted experimentally at proving grounds. In order to gain early insights and reduce the need for costly physical tests, numerical simulations are becoming a promising alternative. Although simulations of vehicle contamination by dry dust have been studied in the past, they have often lacked detailed models for tire dust resuspension. In addition, few publications address the specifics of dust deposition on vehicles, especially in areas such as door gaps and locks.

In direct-injection gasoline (GDI) engines with charge stratification, minimizing engine-out nitrogen oxide (NOx) emission is crucial since exhaust-gas aftertreatment tolerates only limited amounts of NOx. Reduced NOx production directly lowers the frequency of energy-inefficient catalyst regeneration cycles. In this paper we investigate NO formation in a realistic GDI engine. Quantitative in-cylinder measurements of NO concentrations are carried out via laser-induced fluorescence imaging with excitation of NO (A-X(0,2) band at 248 nm), and subsequent fluorescence detection at 220-240 nm. Engine modifications were kept to a minimum in order to provide results that are representative of practical operating conditions. Optical access via a sapphire ring enabled identical engine geometry as a production line engine. The engine is operated with commercial gasoline (“Super-Plus”, RON 98).

Dry dust testing of vehicles on unpaved dust roads plays a crucial role in the development process of automotive manufacturers. One of the central aspects of the test procedure is ensuring the functionality of locking systems in the case of dust ingress and keeping the dust below a certain concentration level inside the vehicle. Another aspect is the customer comfort because of dust deposited on the surface of the car body. This also poses a safety risk to customers when the dust settles on safety-critical parts such as windshields and obstructs the driver’s view. Dust deposition on sensors is also safety critical and is becoming more important because of the increasing amount of sensors for autonomous driving. Nowadays, dust tests are conducted experimentally at dust proving grounds. To gain early insights and avoid costly physical testing, numerical simulations are considered a promising approach. Simulations of vehicle contamination by dry dust have been studied in the past.

In a consortium of European industrial partners and research institutes, a combination of industrial development and scientific research was organised. The objective was to improve the catalytic NOx conversion for lean burn cars and heavy-duty trucks, taking into account boundary conditions for the fuel consumption. The project lasted for three years. During this period parallel research was conducted in research areas ranging from basic research based on a theoretical approach to full scale emission system development. NOx storage catalysts became a central part of the project. Catalysts were evaluated with respect to resistance towards sulphur poisoning. It was concluded that very low sulphur fuel is a necessity for efficient use of NOx trap technology. Additionally, attempts were made to develop methods for reactivating poisoned catalysts. Methods for short distance mixing were developed for the addition of reducing agent.

In a joint research project between industrial companies and a number of research institutes, nitrogen oxide conversion in oxygen containing exhaust gas has been investigated according to the following procedure Basic investigations of elementary steps of the chemical reaction Production and prescreening of different catalytic material on laboratory scale Application oriented screening of industrial catalyst material Catalyst testing on a lean bum gasoline engine, passenger car diesel engines (swirl chamber and DI) and on a DI truck engine Although a number of solid body structures show nitrogen oxide reduction by hydrocarbons, only noble metal containing catalysts and transition metal exchanged zeolites gave catalytic efficiencies of industrial relevance. A maximum of 25 % NOx reduction was found in the European driving cycle for passenger cars, about 40 % for truck engines in the respective European test.

Strategic Materials at Reaction Temperatures (SMART) is an approach used to design washcoat systems for passive 4-way emission control catalysts. Light duty diesel vehicles need to meet the European Motor Vehicle Emissions Group (MVEG) cycle or U. S. Federal test procedure (FTP 75). Emissions that are monitored include hydrocarbon (HC), nitrogen oxides (NOx), carbon monoxide (CO) and total particulate matter (TPM). Low engine-exhaust temperatures (< 200°C during city driving) and high temperatures (> 500-800°C under full load and wide-open throttle) make emission control a formidable task for the catalyst designer Gas phase HC, CO and NOx reactions must be balanced with the removal of the soluble organic fraction for the vehicle to be in compliance with regulations. The SMART approach uses model gases under typical operating conditions in the laboratory to better understand the function of individual washcoat components.

The acoustics insulation on the car body is ones of the more important target in the NVH (Noise Vibration and Harshness) vehicle development process. The method of SEA is a validated statistical approach to solve airborne noise transmission problems. In the vehicle analysis above 300 Hz where material trim and leakage paths makes a important contribution in the vehicle interior acoustics shows the methodology its advantages over deterministic methods.