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This paper presents a new approach for the development of six different JP-8 surrogates for application in diesel cycle simulation. The approach involves a step-wise formulation of 2-, 3-, and 4-component surrogates from a list of pure compounds which are selected based on several criteria. A MATLAB code is developed and is used in conjunction with the Ignition Quality Tester (IQT) and HYSYS software in order to formulate optimal surrogates. The first part of the results shows a comparison between the calculated and the measured DCNs for six surrogates. The differences in the properties such as the density, volatility, lower heating value, H/C ratio, molecular weight, and threshold sooting index of the surrogates and the JP-8 are also highlighted. This is followed by the evaluation of the surrogates with respect to the target JP-8 fuel. The evaluation is made in terms of ignition delays and the rate of heat release at three different IQT test temperatures.

All previous correlations of the ignition delay (ID) period in diesel combustion show a positive activation energy, which means that shorter ID periods are achieved at higher charge temperatures. This is not the case in the autoignition of most homogeneous hydrocarbons-air mixtures where they experience the NTC (Negative Temperature Coefficient ) regime in the intermediate temperature range, from about 800 K to 1000 K). Here, the autoignition reactions slow down and longer ID periods are experienced at higher temperatures. Accordingly the global activation energy for the autoignition reactions of homogeneous mixtures should vary from positive to negative values.