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Use of ethanol as gasoline replacement can contribute to the reduction of nitrogen oxide (NOx) and carbon oxide (CO) emissions. Depending on ethanol production, significant reduction of greenhouse-gas emissions is possible. Concentration of certain species, such as unburned ethanol and acetaldehyde in the engine-out emissions are known to rise when ratio of ethanol to gasoline increases in the fuel. This research explores on hydrous ethanol fueled port-fuel injection (PFI) spark ignition (SI) engine emissions that contribute to photochemical formation of ozone, or so-called ozone precursors and the precursor of peroxyacetyl nitrates (PANs). The results are compared to engine operation on gasoline. Concentration obtained by FTIR gas analyzer, and mass-specific emissions of formaldehyde (HCHO), acetaldehyde (MeCHO) and methane (CH4) under two engine speed, four load and two spark advance settings are analyzed and presented.

Due to the single fuel concept implemented by the US military, the soot production of diesel engines fueled with JP-8 has important implications for military vehicle visual signature and survivability. This work compares in-cylinder soot formation and oxidation of JP-8 and ULSD in a small-bore, optical diesel engine. Experimental engine-out soot emission measurements are compared to crank-angle resolved two-color measurements of soot temperature and optical thickness, KL. A 3-D chemical kinetic-coupled CFD model with line of sight integration is employed in order to investigate the soot distribution in a 2-D projection associated with the imaging plane, as well as to aid in interpreting the third dimension along the optical depth which is not available within the experimental work. The study also examines the effect of volatility on soot emission characteristics by CFD simulation.

The presence of OH radicals as a marker of the high temperature reaction region usually has been used to determine the lift-off length (LOL) in diesel engines. Both OH Laser Induced Fluorescence (LIF) and OH* chemiluminescence diagnostics have been widely used in optical engines for measuring the LOL. OH* chemiluminescence is radiation from OH being formed in the exited states (OH*). As a consequence OH* chemiluminescence imaging provides line-of-sight information across the imaged volume. In contrast, OH-LIF provides information on the distribution of radicals present in the energy ground state. The OH-LIF images only show OH distribution in the thin cross-section illuminated by the laser. When both these techniques have been applied in earlier work, it has often been reported that the chemiluminescence measurements result in shorter lift-off lengths than the LIF approach.

This paper presents an experimental investigation conducted to determine the parameters that control the behavior of autoignition in a small-bore, single-cylinder, optically-accessible diesel engine. Depending on operating conditions, three types of autoignition are observed: a single ignition, a two-stage process where a low temperature heat release (LTHR) or cool flame precedes the main premixed combustion, and a two-stage process where the LTHR or cool flame is separated from the main heat release by an apparent negative temperature coefficient (NTC) region. Experiments were conducted using commercial grade low-sulfur diesel fuel with a common-rail injection system. An intensified CCD camera was used for ultraviolet imaging and spectroscopy of chemiluminescent autoignition reactions under various operating conditions including fuel injection pressures, engine temperatures and equivalence ratios.

Three jet fuel surrogates were compared against their target fuels in a compression ignited optical engine under a range of start-of-injection temperatures and densities. The jet fuel surrogates are representative of petroleum-based Jet-A POSF-4658, natural gas-derived S-8 POSF-4734 and coal-derived Sasol IPK POSF-5642, and were prepared from a palette of n-dodecane, n-decane, decalin, toluene, iso-octane and iso-cetane. Optical chemiluminescence and liquid penetration length measurements as well as cylinder pressure-based combustion analyses were applied to examine fuel behavior during the injection and combustion process. HCHO* emissions obtained from broadband UV imaging were used as a marker for low temperature reactivity, while 309 nm narrow band filtered imaging was applied to identify the occurrence of OH*, autoignition and high temperature reactivity.

With increasing interest to reduce the dependency on gasoline and diesel, alternative energy source like compressed natural gas (CNG) is a viable option for internal combustion engines. Spark-ignited (SI) CNG engine is the simplest way to utilize CNG in engines, but direct injection (DI) Diesel-CNG dual-fuel engine is known to offer improvement in combustion efficiency and reduction in exhaust gases. Dual-fuel engine has characteristics similar to both SI engine and diesel engine which makes the combustion process more complex. This paper reports the computational fluid dynamics simulation of both DI dual-fuel compression ignition (CI) and SI CNG engines. In diesel-CNG dual-fuel engine simulations and comparison to experiments, attention was on ignition delay, transition from auto-ignition to flame propagation and heat released from the combustion of diesel and gaseous fuel, as well as relevant pollutants emissions.

Under the borderline autoignition conditions experienced during cold-starting of diesel engines, the amount and composition of residual gases may play a deterministic role. Among the intermediate species produced by misfiring and partially firing cycles, formaldehyde (HCHO) is produced in significant enough amounts and is sufficiently stable to persist through the exhaust and intake strokes to kinetically affect autoignition of the following engine cycle. In this work, the effect of HCHO addition at various phases of autoignition of n-heptane-air mixtures is kinetically modeled. Results show that HCHO has a retarding effect on the earliest low-temperature heat release (LTHR) phase, largely by competition for hydroxyl (OH) radicals which inhibits fuel decomposition. Conversely, post-LTHR, the presence of HCHO accelerates the occurrence of high-temperature ignition.