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To explore the production and oxidation characteristics of soot in the flame of diesel jet under the condition equivalent to the direct injection diesel engine condition, the effect of three different important parameters (including injection pressure, injection duration, and oxygen concentration) are experimentally examined. For these purposes, a small CVCC (constant volume combustion chamber) with the volume of 60cc equivalent to the volume of combustion chamber of automotive diesel engine is used. To obtain the experimental data of soot production and oxidation, in experiments, the ambient condition of temperature, pressure and oxygen concentration before injection timing are prepared by the combustion of lean hydrogen mixture (with help of 8 spark plugs) at a high temperature and pressure condition around 1000K and 4.5MPa. The common rail type injector with 8 injection holes for modern diesel engine is attached to this vessel.

The effects of CO2 and N2 mixing and the effect of O2 concentration on intermittent spray combustion were examined experimentally under the same condition of ambient temperature and pressure, and the same injection pressure. Through the systematic experiments, it was confirmed that the O2 concentration is the dominant factor affecting ignition delay and combustion duration. The flame temperature becomes lower with the decrease of O2 concentration mainly due to the dilution effect. The decrease of flame temperature due to the dilution effect and that due to the thermal/chemical effect of CO2 was quantified. Concerning the soot production, with the decrease of O2 concentration, it is suppressed during the early stage of combustion, however it becomes higher in the middle to later stage of combustion.

Effect of the ambient O2 concentration and pressure on the spray combustion characteristics of diesel fuel was experimentally examined using a high-temperature, high-pressure combustion vessel. The sequential images were captured by using a high-speed color video camera and were analyzed using the two color method to quantify the temporal variation of the soot temperature and KL factor. Based on a series of systematic experiments, it is confirmed that O2 concentration is the dominant factor affecting both the ignition delay and combustion period. The volumetric fraction of O2 in ambient air has great effect on flame temperature and NOx emission, however ambient pressure has little effect on both values. On the contrary both of the volumetric fraction of O2 in ambient air and the ambient pressure have large effect on soot production.

The effects of fuel injection rate shaping and injection pressure on flame temperature and soot production in intermittent spray combustion were investigated. Two-color technique was applied to the luminous image of free spray flame captured by an ICCD camera to evaluate the 2-D temperature and soot distributions in flame. In addition to the experiments, CFD calculations using KIVA-3V code were carried out and compared with the experimental data. The experimental and computational results showed that fuel injection rate shaping affected the temporal change of flame temperature and the emission of NOx. The optimal mode of injection rate shaping, in terms of NOx reduction, varied according to injection pressure. Concerning the soot production, fuel injection rate shaping affected the regions of soot production and the injection pressure affected soot oxidation especially in the latter stage of combustion.