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This work was concerned with evaluation of the performance and emissions of potential future biofuels during advanced spark ignition engine operation. The fuels prepared included three variants of gasoline, three gasoline-ethanol blends and a gasoline-butanol fuel altogether covering a range of oxygen mass concentrations and octane numbers to identify key influencing parameters. The combustion of the fuels was evaluated in a turbocharged multi-cylinder direct fuel injection research engine equipped with a standard three-way catalyst and an external EGR circuit that allowed use of either cooled or non-cooled EGR. The engine operating effects studied at both part and boosted high load conditions included fuel injection timing and pressure, excess air tolerance, EGR tolerance and spark retard limits. A number of blends were also mapped at suitable sites across the European drive cycle under downsized engine conditions.

The work was concerned with experimental study of the turbulent flame development process of ethanol fuels in an optically accessed spark ignition research engine. The fuels were evaluated in a single cylinder engine equipped with full-bore overhead optical access and operated at typical stoichiometric part-load conditions. High-speed natural light (or chemiluminescence) imaging and simultaneous in-cylinder pressure data measurement and analysis were used to understand the fundamental influence of both low and high ethanol content on turbulent flame propagation and subsequent mass burning. Causes for the difference in cyclic variations were evaluated in detail, with comparisons made to existing burning velocity correlations where available.

Natural Gas (NG) is currently a cost effective substitute for diesel fuel in the Heavy-Duty (HD) diesel transportation sector. Dual-Fuel engines substitute NG in place of diesel for decreased NOx and soot emissions, but suffer from high engine-out methane (CH4) emissions. Premixed Dual-Fuel Combustion (PDFC) is one method of decreasing methane emissions and simultaneously improving engine efficiency while maintaining low NOx and soot levels. PDFC utilizes an early diesel injection to adjust the flammability of the premixed charge, promoting more uniform burning of methane. Engine experiments were carried out using a NG and diesel HD single cylinder research engine. Key speeds and loads were explored in order to determine where PDFC is effective at reducing engine-out methane emissions over Conventional Dual-Fuel which uses a single diesel injection for ignition.

This experimental work was concerned with the combination of internal EGR with an early inlet valve closure strategy for improved part-load fuel economy. The experiments were performed in a new spark-ignited thermodynamic single cylinder research engine, equipped with a mechanical fully variable valvetrain on both the inlet and exhaust. During unthrottled operation at constant engine speed and load, increasing the mass of trapped residual allowed increased valve duration and lift to be used. In turn, this enabled further small improvements in gas exchange efficiency, thermal efficiency and hence indicated fuel consumption. Such effects were quantified under both port and homogeneous central direct fuel injection conditions. Shrouding of the inlet ports as a potential method to increase in-cylinder gas velocities has also been considered.

This work was concerned with study of the in-cylinder flow field and flame development in a spark ignition research engine equipped with Bowditch piston optical access. High-speed natural light (chemiluminescence) imaging and simultaneous in-cylinder pressure data measurement and analysis were used to understand the fundamentals of flame propagation for a variety of ethanol fuels blended with either gasoline or iso-octane. PIV was undertaken on the same engine in a motoring operation at a horizontal imaging plane close to TDC (10 mm below the fire face) throughout the compression stroke (30°,40°,90° and 180°bTDC) for a low load engine operating condition at 1500rpm/0.5 bar inlet plenum pressure. Up to 1500 cycles were considered to determine the ensemble average flow-field and turbulent kinetic energy. Finally, comparisons were made between the flame and flow experiments to understand the apparent interactions.

Ammonia (NH3) is emerging as a potential fuel for longer range decarbonised heavy transport, predominantly due to favourable characteristics as an effective hydrogen carrier. This is despite generally unfavourable combustion and toxicity attributes, restricting end use to applications where robust health and safety protocols can always be upheld. In the currently reported work, a spark ignited thermodynamic single cylinder research engine was upgraded to include gaseous ammonia and hydrogen port injection fueling, with the aim of understanding maximum viable ammonia substitution ratios across the speed-load operating map. The work was conducted under stoichiometric conditions with the spark timing re-optimised for maximum brake torque at all stable logged sites. The experiments included industry standard measurements of combustion, performance and engine-out emissions.

This work was concerned with study of lubricant introduced directly into the combustion chamber and its effect on pre-ignition and combustion in an optically accessed single-cylinder spark ignition engine. The research engine had been designed to incorporate full bore overhead optical access capable of withstanding peak in-cylinder pressures of up to 150bar. An experiment was designed where a fully formulated synthetic lubricant was deliberately introduced through a specially modified direct fuel injector to target the exhaust area of the bore. Optical imaging was performed via natural light emission, with the events recorded at 6000 frames per second. Two port injected fuels were evaluated including a baseline commercial grade gasoline and low octane gasoline/n-heptane blend. The images revealed the location of deflagration sites consistently initiating from the lubricant itself.

Characterization of soot nanoparticle morphology can be used to develop understanding of nanoparticle interaction with engine lubricant oil and its additives. It can be used to help direct modelling of soot-induced thickening, and in a more general sense for combatting reductions in engine efficiency that occur with soot-laden oils. Traditional 2D transmission electron microscopy (TEM) characterization possesses several important shortcomings related to accuracy that have prompted development of an alternative 3D characterization technique utilizing electron tomography, known as 3D-TEM. This work details progress made towards facilitating semi-automated image acquisition and processing for location of structures of interest on the TEM grid. Samples were taken from a four cylinder 1.4 L gasoline turbocharged direct injection (GTDI) engine operated in typically extra-urban driving conditions for 20,284 km, with automatic cylinder deactivation enabled.

The experimental work was concerned with improving understanding of the competing effects of the latent heat of vaporization and auto-ignition delay times of different ethanol blended fuels during heaving knocking combustion. The unique single cylinder SI engine employed included full bore overhead optical access capable of withstanding unusually high in-cylinder pressures. Heavy knock was deliberately induced under moderate loads using inlet air heating and a primary reference fuel blend of reduced octane rating. High-speed chemiluminescence imaging and simultaneous in-cylinder pressure data measurement were used to evaluate the combustion events. Under normal operation the engine was operated under port fuel injection with a stoichiometric air-fuel mixture. Multiple centered auto-ignition events were regularly observed, with knock intensities of up to ~40bar. Additional excess fuel of varied blend was then introduced directly into the end-gas in short transient bursts.

The work was concerned with visualisation of the charge homogeneity and cyclic variations within the planar fuel field near the spark plug in an optical spark ignition engine fitted with an outwardly opening central direct fuel injector. Specifically, the project examined the effects of fuel type and injection settings, with the overall view to understanding some of the key mechanisms previously identified as leading to particulate formation in such engines. The three fuels studied included a baseline iso-octane, which was directly compared to two gasoline fuels containing 10% and 85% volume of ethanol respectively. The engine was a bespoke single cylinder with Bowditch style optical access through a flat piston crown. Charge stratification was studied over a wide spectrum of injection timings using the Planar Laser Induced Fluorescence (PLIF) technique, with additional variation in charge temperature due to injection also estimated when viable using a two-line PLIF approach.