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The Sabatier reactor is an exothermic, heterogeneous catalytic reactor that has the function of reducing carbon dioxide to methane and water vapor. Sabatier reactor operation is affected by gravity through the effects of buoyant forces. The buoyant forces affect the transfer of heat and can be significant in determining the temperatures of the various portions of the reactor. The temperatures then affect the fundamental processes such as the chemical reaction rate. This paper presents the results of zero “G” computer model simulations of Sabatier reactor operation. Groundbase experiments were made for various manned loadings under normal ambient and gravity (l-G) conditions and were correlated with normal gravity simulations. The zero “G” simulations show the reactor will run significantly hotter in a zero “G” environment if cooling air flow is not increased to compensate for the loss of natural convections.

An aqueous phase catalytic oxidation system (APCOS) was designed, tested and delivered to NASA/Johnson Space Center (JSC). The APCOS removes residual organic impurities in reclaimed water to a level acceptable for potable use and to provide disinfection. The reactor, which contains a heterogeneous catalyst consisting of a noble metal on an inert support medium, operates at 120 - 150 °C and at fluid pressures of several atmospheres to maintain an aqueous liquid phase. Pressurized gaseous oxygen, used as the oxidant, is directly injected into the liquid phase. A description of the subsystems process hardware is presented. The APCOS was demonstrated to mineralize organic impurities at concentrations of 100 mg/L total organic carbon (TOC) to < .5 mg/L (<500 μg/L TOC). In addition, disinfection features were demonstrated with microbial challenge tests.

The work presented in this paper summarizes the early results of an integrated advanced water recovery system test conducted by the Crew and Thermal Systems Division (CTSD) at NASA-Johnson Space Center (JSC). The system design and the results of the first two months of operation are presented. The overall objective of this test is to demonstrate the capability of an integrated advanced water recovery system to produce potable quality water for at least six months. Each subsystem is designed for operation in microgravity. The primary treatment system consists of a biological system for organic carbon and ammonia removal. Dissolved solids are removed by reverse osmosis and air evaporation systems. Finally, ion exchange technology in combination with photolysis or photocatalysis is used for polishing of the effluent water stream. The wastewater stream consists of urine and urine flush water, hygiene wastewater and a simulated humidity condensate.

This paper addresses the derivation of chemical ersatz recipes for use in the evaluation of development hardware designed for advanced spacecraft water recovery systems. The recipes simulate characteristics of wastewater generated on a transit mission and on an early planetary base (EPB). In addition, recipes are provided which simulate the water quality of the early planetary base wastewater as it moves through a combination biological and physical-chemical water recovery system. These ersatz are considered to be accurate representations of the wastewater as it passes through primary, secondary, and tertiary processing stages. The EPB ersatz formulas are based on chemical analyses of an integrated water recovery system performance test that was conducted over a period of one year. The major inorganic and organic chemical impurities in the raw wastewater, and in the effluent from the various subsystems, were identified and quantified.

The work presented in this paper summarizes the performance of subsystems used during an integrated advanced water recovery system test conducted by the Crew and Thermal Systems Division (CTSD) at NASA-Johnson Space Center (JSC). The overall objective of this test was to demonstrate the capability of an integrated advanced water recovery system to produce potable quality water for at least six months. Each subsystem was designed for operation in microgravity. The primary treatment system consisted of a biological system for organic carbon and ammonia removal. Dissolved solids were removed by reverse osmosis and air evaporation systems. Finally, ion exchange technology in combination with photolysis or photocatalysis was used for polishing of the effluent water stream. The wastewater stream consisted of urine and urine flush water, hygiene wastewater and a simulated humidity condensate.

This paper discusses the recent developments in water quality monitoring for Space Station reclaimed wastewaters. A preprototype unit that contains an ultraviolet absorbance organic carbon monitor integrated with pH and conductivity sensors is presented. The preprototype has provisions for automated operation and is a reagentless flow-through system without any gas/liquid interfaces. The organic carbon monitor detects by ultraviolet absorbance the organic impurities in reclaimed wastewater which may be correlated to the organic carbon content of the water. A comparison of the preprototype organic carbon detection values with actual total organic carbon measurements is presented. The electrolyte double junction concept for the pH sensor and fixed electrodes for both the pH and conductivity sensors are discussed. In addition, the development of a reagentless organic carbon analyzer that incorporates ultraviolet oxidation and infrared detection is presented.

A microgravity whole body shower (WBS) and a waste water recovery system (WWRS) were used in a closed loop test at the Johnson Space Center. The WWRS process involved chemical pretreatment, phase change distillation and post-treatment. A preprototype Thermoelectric Integrated Hollow Fiber Membrane Evaporation Subsystem (TIMES) was used for distillation after pretreatment and the post-treatment was accomplished with activated carbon, mixed ion exchange resin beds and microbial check valve (MCV) iodine bactericide dispensing units. The purposes of this test were to evaluate a NASA approved Shuttle soap for whole body showering comfort; evaluate the effects of the shower water on the WBS and the TIMES; and evaluate purification qualities of the recovered water in a closed loop operation.

A shower test was conducted recently at NASA-JSC in which waste water was reclaimed and reused. Test subjects showered in a prototype whole body shower following a protocol similar to that anticipated for Space Station. The waste water was purified using reverse osmosis followed by filtration through activated carbon and ion exchange resin beds. The reclaimed waste water was maintained free of microorganisms by using both heat and iodine. This paper discusses the test results, including the limited effectiveness of using iodine as a disinfectant and the evaluation of a Space Station candidate soap for showering. In addition, results are presented on chemical and microbial impurity content of water samples obtained from various locations in the water recovery process.

A microgravity whole body shower and waste water recovery system were evaluated in three separate closed loop tests at NASA/JSC. These tests covered a period from August 1985 to June 1987 in which shower waste water was reclaimed and reused for showering. Test persons showered in a preprototype whole body shower following a protocol similar to that anticipated for the Space Station. Each test was performed by using different water recovery system technologies which included phase change distillation and two separate reverse osmosis processes. These were integrated with post-treatment for the final purification of the reclaimed water. The phase change, a preprototype Thermoelectric Hollow Fiber Membrane Evaporation Subsystem was used for the initial test with chemical pretreatment of the shower waste water input. A reverse osmosis dynamic membrane system was used for the second test and a 2-stage ultrafiltration/reverse osmosis system for the third test.

Recovery of high quality water from urine is an essential part of life support on a Space Station to avoid costly launch and resupply penalties. Water can be effectively recovered from urine by distillation following pretreatment by a chemical agent to inhibit microorganism contamination and fix volatile ammonia constituents. This paper presents the results of laboratory investigations of several pretreatment chemicals which were tested at several concentration levels in combination with sulfuric acid in urine. The optimum pretreatment formulation was then evaluated with urine in the Hamilton Standard Thermoelectric Integrated Membrane Evaporation Subsystem (TIMES). Over 2,600 hours of test time was accumulated. Results of these laboratory and system tests are presented in this paper.