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Urea-selective catalytic reduction (SCR) catalysts are the leading aftertreatment technology for diesel engines, but there are major challenges associated with meeting future NOx emission standards, especially under transient drive cycle conditions that include large swings in exhaust temperatures. Here we present a simplified, transient, one-dimensional integral model of NOx reduction by NH₃ on a commercial small-pore Cu-zeolite urea-SCR catalyst for which detailed kinetic parameters have not been published. The model was developed and validated using data acquired from bench reactor experiments on a monolith core, following a transient SCR reactor protocol. The protocol incorporates NH₃ storage, NH₃ oxidation, NO oxidation and three global SCR reactions under isothermal conditions, at three space velocities and at three NH₃/NOx ratios.

Because of the more hostile environment in the compression ignition engine compared to the spark ignition engine, development and application of CI engine in-cylinder diagnostic methods have lagged those for SI engines. However, with more stringent federally mandated particulate and NOx standards which will go into effect in 1991 and 1994, the need for detailed information on the combustion processes in the cylinder is vital to controlling tailpipe emissions. The present paper contains a summary of the state-of-the-art techniques for determining in-situ species concentrations and profiles; particle concentrations, profiles, and size distributions; and temperature fields. Optical and physical probing methods, total cylinder dumping methods, and optical diagnostics applied for use in CI engine combustion chambers are discussed.

Model-based control strategies are important for meeting the dual objective of maximizing NOx reduction and minimizing NH3 slip in urea-SCR catalysts. To be implementable on the vehicle, the models should capture the essential behavior of the system, while not being computationally intensive. This paper discusses the adequacy of two different reduced order SCR catalyst models and compares their performance with a higher order model. The higher order model assumes that the catalyst has both diffusion and reaction kinetics, whereas the reduced order models contain only reaction kinetics. After describing each model, its parameter identification and model validation based on experiments on a Navistar I6 7.6L engine are presented. The adequacy of reduced order models is demonstrated by comparing the NO, NO2 and NH3 concentrations predicted by the models to their concentrations from the test data.

Combustion characteristics of an L-head engine combustion chamber have been examined using ionization probes and piezioelectric pressure transducers. The method describes how pressure rise rates, peak pressures, mean effective pressures, and flame arrival times were recorded. The flame arrival times were then used to find the position and shape of the flame front as a function of time. The influence of spark plug location on the above parameters was then examined for two different combustion chamber shapes.

With new legislation and federal regulation for vehicle emission levels, automotive and truck manufacturers have been prompted to focus on emission control technologies that limit the level of exhaust pollutants. One of the primary pollutants, especially from diesel engines, is oxides of nitrogen (NOx). One possible solution to this pollution challenge is to design a more efficient internal combustion engine, which would require better engine operating parameter controls. However, there are limitations associated with such tight engine management. This need has led researchers and engineers to focus on the development of exhaust aftertreatment devices that will reduce NOx emissions with current diesel engines. An optimum aftertreatment device must be unaffected by exhaust-gas impurity poisoning such as sulfur products, and must have minimal impact on vehicle operations and fuel economy.

Automotive exhaust emissions of polynuclear aromatic (C16+) hydrocarbons (PNA) were reduced by 65-70% by current emissions control systems and by about 99% by two experimental advanced emission control systems. At a given level of emission control, PNA emission was primarily controlled by fuel PNA content through the transient storage of PNA in engine deposits and their later emission under more severe engine operating conditions. A relatively minor contribution to PNA emission was made by PNA synthesized from lower molecular weight fuel aromatics, particularly C10-C14 aromatics. Deposit-related PNA emissions were linearly correlated with the PNA content of the deposit formation fuel. In comparison with a fuel of field-average PNA content (0.5 ppm benzo(a)pyrene), a field-maximum fuel (3 ppm) contained 4 to 7 times as much of three major PNA species and caused 3 to 5 times higher emissions of these species.

The effect of the use of a manganese-copper fuel additive with a Corning EX-47 particulate trap on heavy-duty diesel emissions has been investigated; reductions in total particulate matter (70%), sulfates (65%), and the soluble organic fraction (SOF) (62%) were measured in the diluted (15:1) exhaust and solids were reduced by 94% as measured in the raw exhaust. The use of the additive plus the trap had the same effect on gaseous emissions (hydrocarbons and oxides of nitrogen) as did the trap alone. The use of the additive without the trap had no effect on measured gaseous emissions, although sulfate increased by 20%. Approximately 50% of the metals added to the fuel were calculated to be retained in the engine system. The metals emitted by the engine were collected very efficiently (>97%) by the trap even during regeneration, which occured 180°C lower when the additive was used.

Due to its high hydrogen storage capacity (up to 16% by weight for the release of 2.5 molar equivalents of hydrogen gas) and its stability under typical ambient conditions, ammonia borane (AB) is a promising material for chemical hydrogen storage for fuel cell applications in transportation sector. Several systems models for chemical hydride materials such as solid AB, solvated AB and alane were developed and evaluated at Pacific Northwest National Laboratory (PNNL) to determine an optimal configuration that would meet the 2010 and future DOE targets for hydrogen storage. This paper presents an overview of those systems models and discusses the simulation results for various transient drive cycle scenarios.

The performance of a closed-loop electronic fuel injection timing control system for diesel engines has been investigated, both experimentally and analytically. The Electronic Control System (ECS) studied is a version of the “Optimizer,” a peak seeking control which can find the maximum of one variable with respect to another. In this case, it was used to find the timing for maximum brake torque (MBT). The ECS can also be operated in a “biased” mode in which it will hold the timing either advanced or retarded of MBT, but in a fixed relationship to it. Performance and emissions of a medium duty engine equipped with the ECS were measured on an engine dynamometer. The results clearly demonstrate that, for a variety of operating conditions and for two fuels, the ECS can find and hold the timing at MBT or in fixed relationship to it.

The development of the DDC methanol engine has been an evolutionary process, with each subsequent configuration showing significant durability and/or emission improvement over its predecessor. Sixty demonstration engines are now in service in the field, including fifty-four (54) urban bus engines, five (5) truck engines, and one (1) generator set engine. While nitrogen oxide (NOx) and particulate emissions from the methanol engine are inherently low, a durable solution to the effective control of hydrocarbon (HC) emissions has been an especially challenging area. The 1991 Federal urban bus transient emission standards (including 0.10 gm/bhp-hr particulate) have been met with several combinations of compression ratio, intake port height, exhaust valve cam profile, injector tip design, and electronic control strategies, and without exhaust aftertreatment devices or fuel ignition improvers.

Particle mass and size distribution measurements have been made on the exhaust of an Onan prechamber diesel engine. Seven fuels were examined: no. 1 and no. 2 diesel fuel, 40 and 50 cetane number secondary reference fuels, and no. 2 diesel fuel doped with three different concentrations of Lubrizol 565, a barium-based smoke suppressant. The no. 1 and no. 2 diesel fuels and the 50 cetane number reference fuels produced very similar emissions with emission indices in the range 0.3-1.3 mg (gm-fuel)-1 and volume mean diameters between .09 and 0.15 μm. The 40 cetane number reference fuel produced both smaller emission indices, 0.2 to 0.8 mg (gm-fuel)-1, and particle diameters, 0.03 to 0.09 μm. These reductions were apparently related to the longer ignition delay period of the 40 cetane number fuel, which allowed better mixing of the fuel and air prior to combustion.

Particle concentrations and size distributions were measured in the exhaust of a turbocharged, aftercooled, direct-injection, Diesel engine equipped with a ceramic filter (trap). Measurements were performed both upstream and downstream of the filter using a two-stage, variable residence time, micro-dilution system, a condensation particle counter and a scanning mobility particle sizer set up to count and size particles in the 7-320 nm diameter range. Engine operating conditions of the ISO 11 Mode test were used. The engine out (upstream of filter) size distribution has a bimodal, log normal structure, consisting of a nuclei mode with a geometric number mean diameter, DGN, in the 10-30 nm range and an accumulation mode with DGN in the 50-80 nm range. The modal structure of the size distribution is less distinct downstream of the filter. Nearly all the particle number emissions come from the nuclei mode, are nanoparticles (Dp < 50nm), and are volatile.

An adaptive control system which determines the optimum system parameters based on the engine response to changes in those parameters, has been tested as an ignition timing control system on several gaseous fueled engines. The changes in the MBT timing for speed, load, air-fuel ratio, and fuel type were explored. The ability of the control system to correct the timing for these parameters was demonstrated. An air-fuel ratio control based on the same technique is also discussed.

Diesel particles carry charges ranging from 1-5 units of elementary charge per particle. The charge is bipolar, i.e., there are approximately equal numbers of positively and negatively charged particles. The charge distribution with respect to size follows a high temperature, Boltzmann equilibrium relationship. The first part of this paper describes charge measurements made on diesel particles emitted by three different diesel engines, and postulates a charging mechanism. The second part of the paper is an examination of how this natural charge may be used to collect particles from the exhaust. The charge level produced by combustion is only slightly lower than the charge level produced by the corona discharge in a conventional electrostatic precipitator. Thus, a simple electrostatic precipitator without a corona section will collect diesel particles affectively.

A 1.9 liter Volkswagen TDI engine has been modified to accomodate the addition of hydrogen into the intake manifold via timed port fuel injection. Engine out particulate matter and the emissions of oxides of nitrogen were investigated. Two fuels,low sulfur diesel fuel (BP50) and soy methyl ester (SME) biodiesel (B99), were tested with supplemental hydrogen fueling. Three test conditions were selected to represent a range of engine operating modes. The tests were executed at 20, 40, and 60 % rated load with a constant engine speed o 1700 RPM. At each test condition the percentage of power from hydrogen energy was varied from 0 to 40 %. This corresponds to hydrogen flow rates ranging from 7 to 85 liters per minute. Particulate matter (PM) emissions were measured using a scaning mobility particle sizer (SMPS) and a two stage micro dilution system. Oxides of nitrogen were also monitored.

Proposed vehicle emissions regulations for the near future have prompted automotive manufactures and component suppliers to focus heavily on developing more efficient exhaust aftertreatment devices to lower emissions from spark and compression ignition engines. One of the primary pollutants from lean-burn engines, especially from diesels, are oxides of nitrogen (NOx). Current three-way catalytic converters will not have adequate performance to meet future emission reduction requirements. Therefore, there is a need for researchers and engineers to develop efficient exhaust aftertreatment devices that will reduce NOx emissions from lean-burn engines. These devices must have very high conversion of NOx gases, be unaffected by exhaust-gas impurity such as sulfur, and have minimal impact on vehicle operations and fuel economy. An effective technology for NOx control that is currently receiving a lot of attention is a non-thermal plasma system.

With ever more stringent CO2 emissions mandates, many automobile manufacturers are seeking the fuel economy benefits of diesel and lean-burn gasoline engines. At the same time the emissions standards that diesel and gasoline engines will have to meet in the next decade continue to reduce. Proposed solutions for meeting the stringent emissions standards all appear to have limitations, such as propensities to poisoning from sulfur, narrow operating temperature windows, and requirements for controls that give rapid rich excursions. Non-thermal plasma-catalyst systems have shown good performance in bench testing while being largely unaffected by these same issues. A two-stage system with a unique non-thermal plasma reactor combined with a zeolite-based catalyst has been constructed and shown to work over a wide temperature range.

Diesel exhaust particle number concentrations and size distributions, as well as gaseous and particulate mass emissions, were measured during steady-state tests on a US heavy-duty engine and a European passenger car engine. Two fuels were compared, namely a Fischer-Tropsch diesel fuel manufactured from natural gas, and a US D2 on-highway diesel fuel. With both engines, the Fischer-Tropsch fuel showed a considerable reduction in the number of particles formed by nucleation, when compared with the D2 fuel. At most test modes, particle number emissions were dominated by nucleation mode particles. Consequently, there were generally large reductions (up to 93%) in the total particle number emissions with the Fischer-Tropsch fuel. It is thought that the most probable cause for the reduction in nucleation mode particles is the negligible sulphur content of the Fischer-Tropsch fuel. In general, there were also reductions in all the regulated emissions with the Fischer-Tropsch fuel.

The transportation industry is finding an ever-increasing number of applications for products manufactured using the tubular hydroforming process. Most of the current hydroforming applications use steel tubes. However, with the mounting regulatory pressure to reduce vehicle emissions, aluminum alloys appear attractive as an alternative material to reduce vehicle weight. The introduction of aluminum alloys to tubular hydroforming requires knowledge of their forming limits. The current work investigates the forming limits of AA6061 in both the T4 and T6 tempers under laboratory conditions. These experimental results are compared to theoretical forming limit diagrams calculated via the M-K method. Free hydroforming results and forming limit diagrams are also compared to components produced under commercial hydroforming conditions.

The use of a corona-less electrostatic precipitator as a collection and agglomeration device for diesel soot has been investigated. It collects and grows diesel particles which are emitted in the submicron diameter range and grow into much larger particles. These larger particles may then be collected with a relatively simple inertial device. Previous testing of a full scale precipitator designed for a Caterpillar 3304 engine showed that the reduction in sub-micron sized mass from the engine was roughly 30 to 40%. Greater reductions were desired. A sub-scale electrostatic agglomerator was built to analyze in greater detail the behavior of an existing full scale device. Tests were designed to determine; the charged fraction of the particles from the engine used, the collection efficiency of the electrostatic agglomerator, the effect of geometry on collection efficiency, and the size distribution of the particles reentrained after electrostatic collection.