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Urea-selective catalytic reduction (SCR) catalysts are the leading aftertreatment technology for diesel engines, but there are major challenges associated with meeting future NOx emission standards, especially under transient drive cycle conditions that include large swings in exhaust temperatures. Here we present a simplified, transient, one-dimensional integral model of NOx reduction by NH₃ on a commercial small-pore Cu-zeolite urea-SCR catalyst for which detailed kinetic parameters have not been published. The model was developed and validated using data acquired from bench reactor experiments on a monolith core, following a transient SCR reactor protocol. The protocol incorporates NH₃ storage, NH₃ oxidation, NO oxidation and three global SCR reactions under isothermal conditions, at three space velocities and at three NH₃/NOx ratios.

Because of the more hostile environment in the compression ignition engine compared to the spark ignition engine, development and application of CI engine in-cylinder diagnostic methods have lagged those for SI engines. However, with more stringent federally mandated particulate and NOx standards which will go into effect in 1991 and 1994, the need for detailed information on the combustion processes in the cylinder is vital to controlling tailpipe emissions. The present paper contains a summary of the state-of-the-art techniques for determining in-situ species concentrations and profiles; particle concentrations, profiles, and size distributions; and temperature fields. Optical and physical probing methods, total cylinder dumping methods, and optical diagnostics applied for use in CI engine combustion chambers are discussed.

Model-based control strategies are important for meeting the dual objective of maximizing NOx reduction and minimizing NH3 slip in urea-SCR catalysts. To be implementable on the vehicle, the models should capture the essential behavior of the system, while not being computationally intensive. This paper discusses the adequacy of two different reduced order SCR catalyst models and compares their performance with a higher order model. The higher order model assumes that the catalyst has both diffusion and reaction kinetics, whereas the reduced order models contain only reaction kinetics. After describing each model, its parameter identification and model validation based on experiments on a Navistar I6 7.6L engine are presented. The adequacy of reduced order models is demonstrated by comparing the NO, NO2 and NH3 concentrations predicted by the models to their concentrations from the test data.

Combustion characteristics of an L-head engine combustion chamber have been examined using ionization probes and piezioelectric pressure transducers. The method describes how pressure rise rates, peak pressures, mean effective pressures, and flame arrival times were recorded. The flame arrival times were then used to find the position and shape of the flame front as a function of time. The influence of spark plug location on the above parameters was then examined for two different combustion chamber shapes.

Automotive exhaust emissions of polynuclear aromatic (C16+) hydrocarbons (PNA) were reduced by 65-70% by current emissions control systems and by about 99% by two experimental advanced emission control systems. At a given level of emission control, PNA emission was primarily controlled by fuel PNA content through the transient storage of PNA in engine deposits and their later emission under more severe engine operating conditions. A relatively minor contribution to PNA emission was made by PNA synthesized from lower molecular weight fuel aromatics, particularly C10-C14 aromatics. Deposit-related PNA emissions were linearly correlated with the PNA content of the deposit formation fuel. In comparison with a fuel of field-average PNA content (0.5 ppm benzo(a)pyrene), a field-maximum fuel (3 ppm) contained 4 to 7 times as much of three major PNA species and caused 3 to 5 times higher emissions of these species.

The effect of the use of a manganese-copper fuel additive with a Corning EX-47 particulate trap on heavy-duty diesel emissions has been investigated; reductions in total particulate matter (70%), sulfates (65%), and the soluble organic fraction (SOF) (62%) were measured in the diluted (15:1) exhaust and solids were reduced by 94% as measured in the raw exhaust. The use of the additive plus the trap had the same effect on gaseous emissions (hydrocarbons and oxides of nitrogen) as did the trap alone. The use of the additive without the trap had no effect on measured gaseous emissions, although sulfate increased by 20%. Approximately 50% of the metals added to the fuel were calculated to be retained in the engine system. The metals emitted by the engine were collected very efficiently (>97%) by the trap even during regeneration, which occured 180°C lower when the additive was used.

Due to its high hydrogen storage capacity (up to 16% by weight for the release of 2.5 molar equivalents of hydrogen gas) and its stability under typical ambient conditions, ammonia borane (AB) is a promising material for chemical hydrogen storage for fuel cell applications in transportation sector. Several systems models for chemical hydride materials such as solid AB, solvated AB and alane were developed and evaluated at Pacific Northwest National Laboratory (PNNL) to determine an optimal configuration that would meet the 2010 and future DOE targets for hydrogen storage. This paper presents an overview of those systems models and discusses the simulation results for various transient drive cycle scenarios.

The performance of a closed-loop electronic fuel injection timing control system for diesel engines has been investigated, both experimentally and analytically. The Electronic Control System (ECS) studied is a version of the “Optimizer,” a peak seeking control which can find the maximum of one variable with respect to another. In this case, it was used to find the timing for maximum brake torque (MBT). The ECS can also be operated in a “biased” mode in which it will hold the timing either advanced or retarded of MBT, but in a fixed relationship to it. Performance and emissions of a medium duty engine equipped with the ECS were measured on an engine dynamometer. The results clearly demonstrate that, for a variety of operating conditions and for two fuels, the ECS can find and hold the timing at MBT or in fixed relationship to it.

The development of the DDC methanol engine has been an evolutionary process, with each subsequent configuration showing significant durability and/or emission improvement over its predecessor. Sixty demonstration engines are now in service in the field, including fifty-four (54) urban bus engines, five (5) truck engines, and one (1) generator set engine. While nitrogen oxide (NOx) and particulate emissions from the methanol engine are inherently low, a durable solution to the effective control of hydrocarbon (HC) emissions has been an especially challenging area. The 1991 Federal urban bus transient emission standards (including 0.10 gm/bhp-hr particulate) have been met with several combinations of compression ratio, intake port height, exhaust valve cam profile, injector tip design, and electronic control strategies, and without exhaust aftertreatment devices or fuel ignition improvers.

Concept feasibility of a burner-bypass particulate trap system for a heavy-duty diesel engine has been demonstrated. The success of this demonstration resulted from the development of a new method of controlling the thermal regeneration process which avoids melting, thermal cracking, and thermal fatigue of the cordierite ceramic trap element. Over 300 load and regeneration cycles, simulating more than 100,000 vehicle miles, were accumulated on a single trap element in engine dynamometer tests with no signs of trap deterioration. In vehicle tests with this trap system, vehicle performance was unaffected, exhaust noise was comparable to that of a production muffler, and the fuel economy penalty was less than one percent. Although this system shows promise for providing the durability required for the heavy-duty application, concerns about its cost and complexity remain.

Particle mass and size distribution measurements have been made on the exhaust of an Onan prechamber diesel engine. Seven fuels were examined: no. 1 and no. 2 diesel fuel, 40 and 50 cetane number secondary reference fuels, and no. 2 diesel fuel doped with three different concentrations of Lubrizol 565, a barium-based smoke suppressant. The no. 1 and no. 2 diesel fuels and the 50 cetane number reference fuels produced very similar emissions with emission indices in the range 0.3-1.3 mg (gm-fuel)-1 and volume mean diameters between .09 and 0.15 μm. The 40 cetane number reference fuel produced both smaller emission indices, 0.2 to 0.8 mg (gm-fuel)-1, and particle diameters, 0.03 to 0.09 μm. These reductions were apparently related to the longer ignition delay period of the 40 cetane number fuel, which allowed better mixing of the fuel and air prior to combustion.

Particle concentrations and size distributions were measured in the exhaust of a turbocharged, aftercooled, direct-injection, Diesel engine equipped with a ceramic filter (trap). Measurements were performed both upstream and downstream of the filter using a two-stage, variable residence time, micro-dilution system, a condensation particle counter and a scanning mobility particle sizer set up to count and size particles in the 7-320 nm diameter range. Engine operating conditions of the ISO 11 Mode test were used. The engine out (upstream of filter) size distribution has a bimodal, log normal structure, consisting of a nuclei mode with a geometric number mean diameter, DGN, in the 10-30 nm range and an accumulation mode with DGN in the 50-80 nm range. The modal structure of the size distribution is less distinct downstream of the filter. Nearly all the particle number emissions come from the nuclei mode, are nanoparticles (Dp < 50nm), and are volatile.

An adaptive control system which determines the optimum system parameters based on the engine response to changes in those parameters, has been tested as an ignition timing control system on several gaseous fueled engines. The changes in the MBT timing for speed, load, air-fuel ratio, and fuel type were explored. The ability of the control system to correct the timing for these parameters was demonstrated. An air-fuel ratio control based on the same technique is also discussed.

Diesel particles carry charges ranging from 1-5 units of elementary charge per particle. The charge is bipolar, i.e., there are approximately equal numbers of positively and negatively charged particles. The charge distribution with respect to size follows a high temperature, Boltzmann equilibrium relationship. The first part of this paper describes charge measurements made on diesel particles emitted by three different diesel engines, and postulates a charging mechanism. The second part of the paper is an examination of how this natural charge may be used to collect particles from the exhaust. The charge level produced by combustion is only slightly lower than the charge level produced by the corona discharge in a conventional electrostatic precipitator. Thus, a simple electrostatic precipitator without a corona section will collect diesel particles affectively.

A 1.9 liter Volkswagen TDI engine has been modified to accomodate the addition of hydrogen into the intake manifold via timed port fuel injection. Engine out particulate matter and the emissions of oxides of nitrogen were investigated. Two fuels,low sulfur diesel fuel (BP50) and soy methyl ester (SME) biodiesel (B99), were tested with supplemental hydrogen fueling. Three test conditions were selected to represent a range of engine operating modes. The tests were executed at 20, 40, and 60 % rated load with a constant engine speed o 1700 RPM. At each test condition the percentage of power from hydrogen energy was varied from 0 to 40 %. This corresponds to hydrogen flow rates ranging from 7 to 85 liters per minute. Particulate matter (PM) emissions were measured using a scaning mobility particle sizer (SMPS) and a two stage micro dilution system. Oxides of nitrogen were also monitored.

Supplementing the gasoline-air intake mixture of an internal combustion engine with a hydrogen-rich fuel is one means of achieving very lean operation and low NOx levels that promise to meet the 0.4 g/mi standard. Steady-state engine dynamometer tests were conducted with a specially modified multicylinder engine to determine if the improved lean operating ability of this engine would enhance the hydrogen-supplemented fuel approach. For these tests the hydrogen enrichment was accomplished with both bottled hydrogen and simulated hydrogen-generator products. The hydrogen requirement of this engine was comparable to that of a 1973 Chevrolet engine tested at the Jet Propulsion Laboratory of the California Institute of Technology. Thus, the experimental engine did not benefit the hydrogen-supplemented fuel approach.

Diesel exhaust particle number concentrations and size distributions, as well as gaseous and particulate mass emissions, were measured during steady-state tests on a US heavy-duty engine and a European passenger car engine. Two fuels were compared, namely a Fischer-Tropsch diesel fuel manufactured from natural gas, and a US D2 on-highway diesel fuel. With both engines, the Fischer-Tropsch fuel showed a considerable reduction in the number of particles formed by nucleation, when compared with the D2 fuel. At most test modes, particle number emissions were dominated by nucleation mode particles. Consequently, there were generally large reductions (up to 93%) in the total particle number emissions with the Fischer-Tropsch fuel. It is thought that the most probable cause for the reduction in nucleation mode particles is the negligible sulphur content of the Fischer-Tropsch fuel. In general, there were also reductions in all the regulated emissions with the Fischer-Tropsch fuel.

A test apparatus containing two raw-gas particulate sampling systems was designed and developed to determine accurately the performance of various materials as diesel exhaust particulate filters. This apparatus was used in conjunction with a single-cylinder diesel engine and a series of fibrous filters to quantify experimentally the effects of filter face area, filter thickness, packing density and fiber diameter on filter performance. Time-dependent efficiency measurements made with this system were smooth and consistent for all of the filters tested and correctly reflected the changes made in these key trap parameters. In all cases, the collection efficiency of the filters increased during the first hour of operation and then reached a relatively constant level. The pressure drop across the filters increased continuously as particulate material accumulated on the filters.

The use of a corona-less electrostatic precipitator as a collection and agglomeration device for diesel soot has been investigated. It collects and grows diesel particles which are emitted in the submicron diameter range and grow into much larger particles. These larger particles may then be collected with a relatively simple inertial device. Previous testing of a full scale precipitator designed for a Caterpillar 3304 engine showed that the reduction in sub-micron sized mass from the engine was roughly 30 to 40%. Greater reductions were desired. A sub-scale electrostatic agglomerator was built to analyze in greater detail the behavior of an existing full scale device. Tests were designed to determine; the charged fraction of the particles from the engine used, the collection efficiency of the electrostatic agglomerator, the effect of geometry on collection efficiency, and the size distribution of the particles reentrained after electrostatic collection.

This paper describes the performance and emissions of a hydrogen-fueled, spark-ignited engine. An electronic control device, designed to provide the engine with a timed injection of the fuel, is shown to give high mean effective pressures and high efficiencies. The oxides of nitrogen from the exhaust gases have been analyzed and the mechanism for their formation is reviewed. The paper further describes an experiment with traces of hydrocarbons added to the hydrogen in an attempt to explain any additional phenomena that may be taking place during the combustion, such as “prompt NO” which is known to occur in hydrocarbon flames only. As it turns out, such additions have a negligible effect on the NOx formation in the region investigated.