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Urea-selective catalytic reduction (SCR) catalysts are the leading aftertreatment technology for diesel engines, but there are major challenges associated with meeting future NOx emission standards, especially under transient drive cycle conditions that include large swings in exhaust temperatures. Here we present a simplified, transient, one-dimensional integral model of NOx reduction by NH₃ on a commercial small-pore Cu-zeolite urea-SCR catalyst for which detailed kinetic parameters have not been published. The model was developed and validated using data acquired from bench reactor experiments on a monolith core, following a transient SCR reactor protocol. The protocol incorporates NH₃ storage, NH₃ oxidation, NO oxidation and three global SCR reactions under isothermal conditions, at three space velocities and at three NH₃/NOx ratios.

This paper describes a novel catalytic oxidation sensor which represents an attempt to realise a practical sensor for on vehicle detection of catalyst efficiency and misfire. Via experimental and modelling approaches, promising characteristics are established, which could mean that an application to the on-vehicle detection of catalyst efficiency and misfire is feasible.

A previously developed Stochastic Reactor Model (SRM) is used to simulate combustion in a four cylinder in-line four-stroke naturally aspirated direct injection Spark Ignition (SI) engine modified to run in Homogeneous Charge Compression Ignition (HCCI) mode with a Negative Valve Overlap (NVO). A portion of the fuel is injected during NVO to increase the cylinder temperature and enable HCCI combustion at a compression ratio of 12:1. The model is coupled with GT-Power, a one-dimensional engine simulation tool used for the open valve portion of the engine cycle. The SRM is used to model in-cylinder mixing, heat transfer and chemistry during the NVO and main combustion. Direct injection is simulated during NVO in order to predict heat release and internal Exhaust Gas Recycle (EGR) composition and mass. The NOx emissions and simulated pressure profiles match experimental data well, including the cyclic fluctuations.

A Stochastic Reactor Model (SRM) has been used to simulate the transition from Spark Ignition (SI) mode to Homogeneous Charge Compression Ignition (HCCI) mode in a four cylinder in-line four-stroke naturally aspirated direct injection SI engine with cam profile switching. The SRM is coupled with GT-Power, a one-dimensional engine simulation tool used for modelling engine breathing during the open valve portion of the engine cycle, enabling multi-cycle simulations. The model is initially calibrated in both modes using steady state data from SI and HCCI operation. The mode change is achieved by switching the cam profiles and phasing, resulting in a Negative Valve Overlap (NVO), opening the throttle, advancing the spark timing and reducing the fuel mass as well as utilising a pilot injection. Experimental data is presented along with the simulation results.

An established Stochastic Reactor Model (SRM) is used to simulate the transition from Spark Ignition (SI) to Homogeneous Charge Compression Ignition (HCCI) combustion mode in a four-cylinder in-line four-stroke naturally aspirated direct injection SI engine with cam profile switching. The SRM is coupled with GT-Power, a one-dimensional engine simulation tool used for modeling engine breathing during the open valve portion of the engine cycle, enabling multi-cycle simulations. The mode change is achieved by switching the cam profiles and phasing, resulting in a Negative Valve Overlap (NVO), opening the throttle, advancing the spark timing and reducing the fuel mass as well as using a pilot injection. A proven technique for tabulating the model is used to create look-up tables in both SI and HCCI modes. In HCCI mode several tables are required, including tables for the first NVO, transient valve timing NVO, transient valve timing HCCI and steady valve timing HCCI and NVO.

Particulate emissions from IC engines associated with transient engine conditions are very important (similar to the legislated gaseous emissions). This is true both during real-world and test cycle driving. This paper describes an instrument for measuring the number of particles, and their spectral weighting, in the 5nm to 1000nm size range, with a time response of 200ms. This is achieved via an electrostatic classification technique, consisting of a diffusion charger followed by a multi-element, constant voltage, classifier. Conversion of the data to other metrics, such as mass, is also described. Results are presented from artificial test aerosols and from light and heavy duty diesel engines on standard test cycles.

The cylinder pressure signal, as an instantaneous and direct measure of the engine operation, contains valuable information for closed loop engine control and offers very useful engine monitoring and control capabilities. The estimation technique for cylinder pressure has been investigated for many years. Based on the Frequency Analysis Method, a synthetic estimation method is proposed in this paper to estimate pressure. Methods that are successful in obtaining a more accurate estimated cylinder pressure over a wider range of crankshaft angle are reported. Quantitative results obtained from application of the method are also given.

Afterburning of a rich exhaust/air mixture ahead of the catalyst has been shown in earlier papers to offer an effective means of achieving catalyst light-off in very short times. Protection of the catalyst from overheating is an important aspect of systems using EGI, and on board diagnostics will be required to check for proper function of EGI. In this paper, some options for these requirements are discussed, using a high temperature linear thermistor.

A key challenge in achieving good transient performance of highly boosted engines is the difficulty of accelerating the turbocharger from low air flow conditions (“turbo lag”). Multi-stage turbocharging, electric turbocharger assistance, electric compressors and hybrid powertrains are helpful in the mitigation of this deficit, but these technologies add significant cost and integration effort. Air-assist systems have the potential to be more cost-effective. Injecting compressed air into the intake manifold has received considerable attention, but the performance improvement offered by this concept is severely constrained by the compressor surge limit. The literature describes many schemes for generating the compressed gas, often involving significant mechanical complexity and/or cost. In this paper we demonstrate a novel exhaust assist system in which a reservoir is charged during braking.

A novel technique for measuring the axial distribution of wall flow in diesel particle filters is described. It is based on measuring the dilution of a tracer gas (introduced at the upstream end of an outlet channel) as it passes along a filter channel, due to the wall flow. A relation is derived between the change in concentration and the flow per unit length of air entering the outlet channel from adjacent inlet channels. Typical data showing the axial variation in the wall flow for clean and loaded filters are presented and discussed. We find qualitatively plausible flow distributions, but note that independent verification of the method is required before the data can confidently be interpreted quantitatively. Some of the potential applications of the technique may include studying the regeneration process and measurement of ash deposition.

A novel mechanical method of achieving a rapid switch between stoichiometric and lean conditions for SI engines is explored. Two and three throttle configurations, a switch strategy which employs a standard intake manifold and an assembly of pipes and throttle(s), are investigated numerically by using a one-dimensional engine simulation program based on the method of characteristics. The results indicate that it is possible to achieve rapid AFR switch without a torque jump, i.e. unperceptible to the driver.

The paper presents a computer simulation of flow and heat transfer phenomena in the intake port of a spark ignition engine with port fuel injection. Engine cold starting conditions are studied including the effects of in-cylinder mixture back flow into the port. One dimensional air flow and wall fuel film flow models and a two dimensional fuel droplet flow model have been developed using a combination of finite difference approaches. As a result, predictions are obtained that provide detailed picture of the air-fuel mixture properties along the intake port. The model may be of special importance for exhaust gas ignition system simulation as it will provide data concerning mixture formation under conditions of excessive fuel injection during engine start-up. The calculations performed are shown to be phenomenologically correct.

Because of the more hostile environment in the compression ignition engine compared to the spark ignition engine, development and application of CI engine in-cylinder diagnostic methods have lagged those for SI engines. However, with more stringent federally mandated particulate and NOx standards which will go into effect in 1991 and 1994, the need for detailed information on the combustion processes in the cylinder is vital to controlling tailpipe emissions. The present paper contains a summary of the state-of-the-art techniques for determining in-situ species concentrations and profiles; particle concentrations, profiles, and size distributions; and temperature fields. Optical and physical probing methods, total cylinder dumping methods, and optical diagnostics applied for use in CI engine combustion chambers are discussed.

A semi-empirical model of fuel transport in the intake manifold of spark ignition engines, which assumes a fraction of injected fuel deposits onto the port walls and describes the detailed fuel film phenomena, is proposed. The model is applied in the throttle ramp transients during which both the air and the fuel flow change significantly. The predicted air fuel ratio excursions, engine torque etc, are in good agreement with the experimental data. Also simulated is another kind of transience, which has only an air flow jump, i.e. with fuelling rate constant, when the engine jumps between stoichiometric and lean running. The results are again in satisfactory agreement with experiment.

Simple air-path models for modern (VGT/EGR equipped) diesel engines are in common use, and have been reported in the literature. This paper addresses some of the shortcomings of control-oriented models to allow better prediction of the cylinder charge properties. A fast response CO2 analyzer is used to validate the model by comparing the recorded and predicted CO2 concentrations in both the intake port and exhaust manifold of one of the cylinders. Data showing the recorded NOx emissions and exhaust gas opacity during a step change in engine load illustrate the spikes in both NOx and smoke seen during transient conditions. The predicted cylinder charge properties from the model are examined and compared with the measured NOx and opacity. Together, the emissions data and charge properties paint a consistent picture of the phenomena occurring during the transient. Alternative strategies for the fueling and cylinder charge during these load transients are investigated and discussed.

Model-based control strategies are important for meeting the dual objective of maximizing NOx reduction and minimizing NH3 slip in urea-SCR catalysts. To be implementable on the vehicle, the models should capture the essential behavior of the system, while not being computationally intensive. This paper discusses the adequacy of two different reduced order SCR catalyst models and compares their performance with a higher order model. The higher order model assumes that the catalyst has both diffusion and reaction kinetics, whereas the reduced order models contain only reaction kinetics. After describing each model, its parameter identification and model validation based on experiments on a Navistar I6 7.6L engine are presented. The adequacy of reduced order models is demonstrated by comparing the NO, NO2 and NH3 concentrations predicted by the models to their concentrations from the test data.

The benefits of deliberately modulating air-to-fuel ratio over a three-way catalyst are disputed. In this work, engine test cell experiments were carried out to assess the performance of a warmed-up Pd/Rh three-way catalyst. The objectives were threefold: first, to determine the best mode of operation; second, to determine if air-to-fuel ratio modulation enhances robustness to transient air-to-fuel ratio disturbances; third, to determine if the conversion efficiency can be manipulated by controlling the shape of the air-to-fuel ratio oscillation. It was observed that the highest conversion efficiency is obtained using a steady air-to-fuel ratio just rich of stoichiometric; however, this mode of operation lacks robustness with respect to transient disturbances and UEGO sensor errors. Robustness can be improved using an oscillating air-to-fuel ratio, but with a sacrifice in peak conversion efficiency.

The transport of fuel during cold start in the intake of a port-injected engine has been investigated using a standard engine with very little modification. A fast response FID sampling from the intake manifold is used to measure the instantaneous vapor concentration during the start. At short times after the start, the engine is stopped, and the port under investigation isolated. The engine is then warmed up by passing hot water through it and at the same time is flushed with hot air, in the port and the cylinder. This evaporates the liquid fuel, and by integrating the vapor concentration multiplied by mass flow of the displaced gas, the fuel mass in the isolated port and cylinder is measured. It is shown how the mass of liquid in the port at the time at which the engine is stopped can reliably be related to the concentration measurement. By stopping the engine at different times after the start, detailed accounting of the fuel transport as a function of time since start can be made.

The information provided by the in-cylinder pressure signal is of great importance for modern engine management systems. The obtained information is implemented to improve the control and diagnostics of the combustion process in order to meet the stringent emission regulations and to improve vehicle reliability and drivability. The work presented in this paper covers the experimental study and proposes a comprehensive and practical solution for the estimation of the in-cylinder pressure from the crankshaft speed fluctuation. Also, the paper emphasizes the feasibility and practicality aspects of the estimation techniques, for the real-time online application. In this study an engine dynamics model based estimation method is proposed. A discrete-time transformed form of a rigid-body crankshaft dynamics model is constructed based on the kinetic energy theorem, as the basis expression for total torque estimation.

Experiments to cyclically resolve the HC concentration emitted by an I.C. engine with improved sampling techniques are described. The results suggest that the technique is easy to use, and gives results which are comparable with those obtained by other methods.