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Currently, states that are out of compliance with the National Ambient Air Quality Standards must, according to the Clean Air Act Amendments of 1990 (CAAA), develop and implement control strategies that demonstrate specific degrees of reduction in emissions-with the degree of reduction depending upon the severity of the problem. One tool that has been developed to aid regulators in both deciding an appropriate course of action and to demonstrate the desired reductions in mobile emissions is EPA's Mobile 5a emission estimation model. In our study, Mobile 5a has been used to examine the effects of regulatory strategies, as applied to the Northeast United States, on vehicle emissions under worst-case ozone-forming conditions.

A set of experiments was performed to investigate the effects of relative air-fuel ratio, inlet boost pressure, and compression ratio on engine knock behavior. Selected operating conditions were also examined with simulated hydrogen rich fuel reformate added to the gasoline-air intake mixture. For each operating condition knock limited spark advance was found for a range of octane numbers (ON) for two fuel types: primary reference fuels (PRFs), and toluene reference fuels (TRFs). A smaller set of experiments was also performed with unleaded test gasolines. A combustion phasing parameter based on the timing of 50% mass fraction burned, termed “combustion retard”, was used as it correlates well to engine performance. The combustion retard required to just avoid knock increases with relative air-fuel ratio for PRFs and decreases with air-fuel ratio for TRFs.

This paper provides an overview of spark-ignition engine unburned hydrocarbon emissions mechanisms, and then uses this framework to relate measured engine-out hydrocarbon emission levels to the processes within the engine from which they result. Typically, spark-ignition engine-out HC levels are 1.5 to 2 percent of the gasoline fuel flow into the engine; about half this amount is unburned fuel and half is partially reacted fuel components. The different mechanisms by which hydrocarbons in the gasoline escape burning during the normal engine combustion process are described and approximately quantified. The in-cylinder oxidation of these HC during the expansion and exhaust processes, the fraction which exit the cylinder, and the fraction oxidized in the exhaust port and manifold are also estimated.

The autoignition characteristics of methanol, ethanol and MTBE (methyl tert-butyl ether) have been investigated in a rapid compression machine at pressures in the range 20-40 atm and temperatures within 750-1000 K. All three oxygenated fuels tested show higher autoignition temperatures than paraffins, a trend consistent with the high octane number of these fuels. The autoignition delay time for methanol was slightly lower than predicted values using reported reaction mechanisms. However, the experimental and measured values for the activation energy are in very good agreement around 44 kcal/mol. The measured activation energy for ethanol autoignition is in good agreement with previous shock tube results (31 kcal/mol), although ignition times predicted by the shock tube correlation are a factor of three lower than the measured values. The measured activation energy for MTBE, 41.4 kcal/mol, was significantly higher than the value previously observed in shock tubes (28.1 kcal/mol).

This paper explores the benefits that would be achieved if gasoline marketers produced and offered a higher-octane gasoline to the U.S. consumer market as the standard grade. By raising octane, engine knock constraints are reduced, so that new spark-ignition engines can be designed with higher compression ratios and boost levels. Consequently, engine and vehicle efficiencies are improved thus reducing fuel consumption and greenhouse gas (GHG) emissions for the light-duty vehicle (LDV) fleet over time. The main objective of this paper is to quantify the reduction in fuel consumption and GHG emissions that would result for a given increase in octane number if new vehicles designed to use this higher-octane gasoline are deployed. GT-Power simulations and a literature review are used to determine the relative brake efficiency gain that is possible as compression ratio is increased.

Spark-ignition engine knock was characterized in terms of when during the engine cycle and combustion process knock occurred and its magnitude or intensity. Cylinder pressure data from a large number of successive individual cycles were generated from a single-cylinder engine of hemispherical chamber design over a range of operating conditions where knock occurred in some or all of these cycles. Mean values and distributions of following parameters were quantified: knock occurrence crank angle, knock intensity, combustion rate and the end-gas thermodynamic state. These parameters were determined from the cylinder pressure data on an individual cycle basis using a mass-burn-rate analysis. The effects of engine operating variables on these parameters were studied, and correlations between these parameters were examined.

Gasoline/ethanol fuel blends have significant synergies with Spark Ignited Direct Injected (SI DI) engines. The higher latent heat of vaporization of ethanol increases charge cooling due to fuel evaporation and thus improves knock onset limits and efficiency. Realizing these benefits, however, can be challenging due to the finite time available for fuel evaporation and mixing. A methodology was developed to quantify how much in-cylinder charge cooling takes place in an engine for different gasoline/ethanol blends. Using a turbocharged SI engine with both Port Fuel Injection (PFI) and Direct Injection (DI), knock onset limits were measured for different intake air temperatures for both types of injection and five gasoline/ethanol blends. The superior charge cooling in DI compared to PFI for the same fuel resulted in pushing knock onset limits to higher in-cylinder maximum pressures. Knock onset is used as a diagnostic of charge cooling.

Spark Ignited Direct Injection (SI DI) of fuel extends engine knock limits compared to Port Fuel Injection (PFI) by utilizing the large in-cylinder charge cooling effect due to fuel evaporation. The use of gasoline/ethanol blends in direct injection (DI) is therefore especially advantageous due to the high heat of vaporization of ethanol. In addition to the thermal benefit due to charge cooling, ethanol blends also display superior chemical resistance to autoignition, therefore allowing the further extension of knock limits. Unlike the charge cooling benefit which is realized mostly in SI DI engines, the chemical benefit of ethanol blends exists in Port Fuel Injected (PFI) engines as well. The aim of this study is to separate and quantify the effect of fuel chemistry and charge cooling on knock. Using a turbocharged SI engine with both PFI and DI, knock limits were measured for both injection types and five gasoline-ethanol blends.

This paper assesses the potential improvement of automotive powertrain technologies 25 years into the future. The powertrain types assessed include naturally-aspirated gasoline engines, turbocharged gasoline engines, diesel engines, gasoline-electric hybrids, and various advanced transmissions. Advancements in aerodynamics, vehicle weight reduction and tire rolling friction are also taken into account. The objective of the comparison is the potential of anticipated improvements in these powertrain technologies for reducing petroleum consumption and greenhouse gas emissions at the same level of performance as current vehicles in the U.S.A. The fuel consumption and performance of future vehicles was estimated using a combination of scaling laws and detailed vehicle simulations. The results indicate that there is significant potential for reduction of fuel consumption for all the powertrains examined.

The goal of this paper is to quantitatively assess the implications of congressionally mandated biofuel targets on requirements for ethanol blending, distribution, and usage in spark ignition engines in the U.S. light-duty vehicle fleet. The “blend wall” is a term that refers to the maximum amount of ethanol that can be blended into the gasoline pool without exceeding the legal volumetric blend limit of 10%. Beyond the blend wall, the additional ethanol fuel must be used in higher blends of ethanol like E85. Once the blend wall is reached, the existing fleet of flex fuel vehicles (FFVs) will be required to use E85 for some percentage of vehicle miles traveled (VMT) in order to achieve the Renewable Fuel Standard (RFS) targets.

CARS temperature measurements were carried out both in a constant volume combustion chamber and in a spark-ignition engine. The CARS temperature measurement under engine-like condition was validated by comparing the unburned gas temperatures for premixed propane-air flame in a constant volume combustion chamber obtained by CARS with predicted temperatures of 2-zone flame propagation simulation model. There was good agreement between the predicted temperatures and the mean values of 10 CARS measurements. The standard deviation of 10 measurements at each measuring timing was about ±40 K. End-gas temperatures were measured by CARS technique in a conventional 4-cylinder DOHC spark-ignition engine with the engine motoring and firing. The measured motoring temperature matched well with the adiabatic core temperature calculated from the measured cylinder pressure. The engine was fueled with primary reference fuel (PRF80) of 80% iso-octane and 20% n-heptane by volume.

The effects of combustion chamber and intake valve deposit build-up on the knocking characteristics of a spark ignition engine were studied. A Chrysler 2.2 liter engine was run continuously for 180 hours to build up intake valve and combustion chamber deposits. In the tests reported here, the gasoline used contained a deposit controlling fuel additive. The engines's octane requirement increased by 10 research octane numbers during this extended engine operating period. At approximately 24 hour intervals during these tests, the engine was audibly knock rated to determine its octane requirement. Cylinder pressure data was collected during knocking conditions to investigate the knocking characteristics of each cylinder, and deposit build-up effects on those statistics. Cylinder-to-cylinder variations in knock statistics were studied. Analysis of the data indicated that some 20 to 40 percent of cycles knock before the knock is audibly detected.

In this research, an optical system for the detection of the flame propagation under the non-knocking and knocking conditions is developed and applied to a mass produced four cylinder SI engine. The normal flames are measured and analyzed under the steady state operating conditions at various engine speeds. For knocking cycles, the flame front propagations before and after knock occurrence are simultaneously taken with cylinder pressure data. In non-knocking and knocking cycles, flame propagation shows cycle-by-cycle variations, which are quite severe especially in the knocking cycles. The normal flame propagations are analyzed at various engine speeds, and show that the flame front on the exhaust valve side becomes faster as the engine speed increases. According to the statistical analysis, knock occurence location and flame propagation process after knock can be categorized into five different types.

This paper describes experimental and theoritical studies of a turbulent combustion bomb. We find a correlation between heat transfer to the wall and the Initial turbulence intensity. Wall temperature and pressure measurements were made for three levels of initial turbulence. All tests were performed with an equivalence ratio of 1.0, and the turbulence intensity was controlled by varying the time delay between mixture intake and spark ignition. Assuming one-dimensional conduction, the surface heat flux was computed from the wall temperature data. Gas temperatures were computed from the pressure data assuming isentropic compression. Based on turbulent velocity measurements made in previous studies, these results permitted a correlation of Nusselt number with turbulent Reynolds number. Using this correlation, we estimate the heat transfer in the end gas and its effect on the gas temperature.

Experiments were performed to identify the knock trends of lean hydrocarbon-air mixtures, and such mixtures enhanced with hydrogen (H2) and carbon monoxide (CO). These enhanced mixtures simulated 15% and 30% of the engine's gasoline being reformed in a plasmatron fuel reformer [1]. Knock trends were determined by measuring the octane number (ON) of the primary reference fuel (mixture of isooctane and n-heptane) supplied to the engine that just produced audible knock. Experimental results show that leaner operation does not decrease the knock tendency of an engine under conditions where a fixed output torque is maintained; rather it slightly increases the octane requirement. The knock tendency does decrease with lean operation when the intake pressure is held constant, but engine torque is then reduced.

The laminar burning speeds of two practical multi-component hydrocarbon fuels similar to automotive gasoline were measured using a spherical combustion bomb with central ignition. Mixtures with equivalence ratios between 0.7 and 1.6, and volume fractions of simulated residual gas between 0 and 0.3 were tested at pressures from 0.4 atm to 12 atm and unburned gas temperatures from 350 K to 550 K. The laminar burning speeds were fitted to a power function expression involving the unburned gas pressure and temperature, and the diluent fraction. The pressure and temperature dependences of the laminar burning speed for undiluted mixtures agreed well with values reported by other investigators for various fuels, indicating that these dependences are independent of fuel type. The percentage reduction in laminar burning speed due to the addition of simulated residual gas was found to be a function only of the amount added, independent of the properties of the mixture.

When hydrogen is added to a gasoline fueled spark ignition engine the lean limit of the engine can be extended. Lean running engines are inherently more efficient and have the potential for significantly lower NOx emissions. In the engine concept examined here, supplemental hydrogen is generated on-board the vehicle by diverting a fraction of the gasoline to a plasmatron where a partial oxidation reaction is initiated with an electrical discharge, producing a plasmatron gas containing primarily hydrogen, carbon monoxide, and nitrogen. Two different gas mixtures were used to simulate the plasmatron output. An ideal plasmatron gas (H2, CO, and N2) was used to represent the output of the theoretically best plasmatron. A typical plasmatron gas (H2, CO, N2, and CO2) was used to represent the current output of the plasmatron. A series of hydrogen addition experiments were also performed to quantify the impact of the non-hydrogen components in the plasmatron gas.

In this study, spark-ignition engine knock was studied experimentally. Cylinder pressure and cylinder block vibration of a four cylinder SI engine were measured. Knock characteristics, such as knock intensity, knock cycle percentage, knock occurrence crank angle, were determined from pressure and vibration signals using different analysis methods. Methods using band-pass filter, third derivative and step method, which was developed in this study, were shown to be the most suitable. The step method only used signals above threshold value during knocking and, as a result, both pressure and vibration signal analysis results with this method showed good signal-to-noise ratio. The knock intensities calculated from cylinder pressure and block vibration were proportional to each other over a wide range. It was confirmed in this study that vibration signals were useful in knock detection.

A method to collect and speciate the components of gasoline absorbed in the lubricant oil using gas chromatography has been developed. Samples were collected continuously from the piston skirt, baffle and sump in a Saturn engine. A long (18 hours) test was performed to determine the build up of hydrocarbons in the sump, and a shorter (25 min) test was performed to determine the build up of hydrocarbons in the piston skirt and baffle during engine warm-up. The first experiment showed that the total hydrocarbon concentration in the sump oil reached a steady state of about 1.35% mass fraction after 11 hours of engine operation. The relative concentration of individual fuel hydrocarbon species absorbed in the oil increases exponentially with boiling point. Most of the identified species in the oil consist of the heavy end aromatics. Similar compositions but lower concentrations were found for samples collected from the piston skirt during engine warm-up.

1 Downsizing and turbocharging a spark-ignited engine is becoming an important strategy in the engine industry for improving the efficiency of gasoline engines. Through boosting the air flow, the torque is increased, the engine can thus be downsized, engine friction is reduced in both absolute and relative terms, and engine efficiency is increased. However knock onset with a given octane rating fuel limits both compression ratio and boost levels. This paper explores the operating limits of a turbocharged engine, with various gasoline-ethanol blends, and the interaction between compression ratio, boost levels, and spark retard, to achieve significant increases in maximum engine mean effective pressure and efficiency.